Early instability of MIL-125-NH2 in aqueous solution and mediation of the visible photogeneration of NADH cofactor

2021 ◽  
Author(s):  
Matias Ezequiel Aguirre ◽  
Rocio Isla Naveira ◽  
Pablo Botta ◽  
Tamara Antonela Altieri ◽  
Alejandro Wolosiuk ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Carboxylic Acid ◽  
Metal Organic Frameworks ◽  
Semiconductor Materials ◽  
Metal Organic ◽  
Photoinduced Processes

Metal organic frameworks (MOFs) based on titanium and carboxylic acid derivatives have been recently proposed as mediators of multiple photoinduced processes in substitution of traditional semiconductor materials. In the case...

Two water-stable lanthanide metal–organic frameworks with oxygen-rich channels for fluorescence sensing of Fe(iii) ions in aqueous solution

2018 ◽  
Vol 47 (45) ◽  
pp. 16190-16196 ◽  
Author(s):  
Lizhen Liu ◽  
Yu Wang ◽  
Rongyan Lin ◽  
Zizhu Yao ◽  
Quanjie Lin ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Carboxylic Acid ◽  
Metal Organic Frameworks ◽  
Fluorescence Sensing ◽  
Metal Organic ◽  
Lanthanide Metal

A strategy is proposed to construct oxygen-rich channel MOFs as chemosensors for sensing Fe3+ ions using oxygen-enriched multi-carboxylic acid ligands.

scholarly journals Highly sensitive detection of nitrobenzene by a series of fluorescent 2D zinc(ii) metal–organic frameworks with a flexible triangular ligand

RSC Advances ◽  
2021 ◽  
Vol 11 (39) ◽  
pp. 23975-23984
Author(s):  
Xue Yang ◽  
Yixia Ren ◽  
Hongmei Chai ◽  
Xiufang Hou ◽  
Zhixiang Wang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Frameworks ◽  
High Sensitivity ◽  
Fluorescent Sensors ◽  
Sensitive Detection ◽  
Donor Ligands ◽  
Highly Sensitive ◽  
Metal Organic ◽  
Highly Sensitive Detection

Four fluorescent 2D Zn-MOFs based on a flexible triangular ligand and linear N-donor ligands are hydrothermally prepared and used to detect nitrobenzene in aqueous solution with high sensitivity, demonstrating their potential as fluorescent sensors.

scholarly journals Synthesis of metal–organic frameworks (MOFs) MIL-100(Fe) functionalized with thioglycolic acid and ethylenediamine for removal of eosin B dye from aqueous solution

2021 ◽  
Vol 3 (1) ◽  
Author(s):  
Adedibu C. Tella ◽  
Janet T. Bamgbose ◽  
Vincent O. Adimula ◽  
Mary Omotoso ◽  
Sunday E. Elaigwu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Thioglycolic Acid ◽  
Metal Organic Frameworks ◽  
Thiol Group ◽  
Spectroscopic Techniques ◽  
Base Interaction ◽  
Adsorption Capacities ◽  
Melting Point Analysis ◽  
Eosin B ◽  
Metal Organic

AbstractThe interaction of eosin B dye from aqueous solution with MIL-100(Fe) and functionalized MIL-100(Fe) metal–organic frameworks (MOFs) is reported in this study. MIL-100(Fe) was prepared and functionalized with thioglycolic acid (TH) and ethylenediammine (ED) separately by incorporating the thiol (–SH) and the amine (–NH2) group of the functionalizing agents into the open metal sites of the MIL-100(Fe) to obtain the acidic (TH-MIL-100) and basic (ED-MIL-100) forms of the MOF respectively. Characterization of the MOFs was done by melting point analysis, elemental analysis, spectroscopic techniques, scanning electron microscopy (SEM), and powdered X-ray diffraction (PXRD) analysis. The adsorption experiments were carried out at different conditions such as pH, adsorbent dosage, contact time, temperature, and initial concentration of the dye to estimate the optimum conditions and the maximum adsorption capacities. Adsorption capacities were observed to increase in the order of ED-MIL-100 < MIL-100 < TH-MIL-100, while the TH-MIL-100 was the most effective in the removal process due to acid–base interaction between the acidic thiol group (–SH) and the alkaline medium of eosin B dye solution. The Langmuir Isotherm was seen to fit well to adsorption data obtained for all three adsorbent materials studied, and adsorption processes followed the pseudo-second order kinetics. This study, therefore, indicates the suitability of functionalization of MIL-100(Fe) towards improving its adsorption capacity.

3D Ln-MOFs as multi-responsive luminescent probe for efficient sensing of Fe3+, Cr2O72‒, and antibiotics in aqueous solution

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yuanshan Xue ◽  
Ji Ding ◽  
Dan-Ling Sun ◽  
Weiwei Cheng ◽  
Xuanrong Chen ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Frameworks ◽  
Luminescent Probe ◽  
Metal Organic ◽  
Lanthanide Metal

Two families of lanthanide metal-organic frameworks (Ln-MOFs), namely {[Ln2L2(DMF)4]·xDMF·yH2O}n (Ln = Ce(1), Pr(2), Sm(3), Eu(4), Gd(5); x = 0,1; y = 0,1), and {[Ln2L2(H2O)2.5]}n (Ln = Dy(6), Ho(7)), have been...

Removal of Co(II) from aqueous solution with functionalized metal–organic frameworks (MOFs) composite

2019 ◽  
Vol 322 (2) ◽  
pp. 827-838 ◽  
Author(s):  
Guoyuan Yuan ◽  
Yin Tian ◽  
Min Li ◽  
Yang Zeng ◽  
Hong Tu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Frameworks ◽  
Metal Organic

Metal–organic frameworks for radionuclide sequestration from aqueous solution: a brief overview and outlook

2017 ◽  
Vol 46 (47) ◽  
pp. 16381-16386 ◽  
Author(s):  
Chengliang Xiao ◽  
Mark A. Silver ◽  
Shuao Wang
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

137Cs, 90Sr, 238U, 79Se, and 99Tc sequestrations from aqueous solution by metal–organic framework materials are summarized in this Frontier article.

Electrochemical oxidation of 5-hydroxymethylfurfural on ternary metal-organic frameworks nanoarrays: enhancement from electronic structure modulation

2021 ◽  
Author(s):  
Xiaojue Bai ◽  
Wenxiu He ◽  
Xingyu Lu ◽  
Yu Fu ◽  
Wei Qi
Keyword(s):  
Electronic Structure ◽  
Carboxylic Acid ◽  
Electrochemical Oxidation ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Highly Active ◽  
Ternary Metal ◽  
Metal Organic ◽  
Structure Modulation

The rational design and exploitation of highly active and stable catalysts for the electrochemical oxidation of biomass-derived 5-hydroxymethylfurfural (HMF) to valuable chemical 2,5-furandi-carboxylic acid (FDCA), is of great significance. Herein,...

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