Hydroxyl modified hypercrosslinked polymers: targeting high efficient adsorption separation toward aniline

2021 ◽  
Author(s):  
Zishuai Wei ◽  
Qibin Chen ◽  
Honglai Liu

The removal of aniline from aqueous solution can have a major environmental impact and hence has attracted increasing attention in last years. In this work, four hypercrosslinked polymers (HCPs) bearing...

Author(s):  
Xiaofeng Huang ◽  
Qiulin Deng ◽  
Xingzhang Wang ◽  
Hongquan Deng ◽  
Tinghong Zhang ◽  
...  

2018 ◽  
Vol 42 (10) ◽  
pp. 7640-7648 ◽  
Author(s):  
Salvatore Cataldo ◽  
Gabriele Lando ◽  
Demetrio Milea ◽  
Santino Orecchio ◽  
Alberto Pettignano ◽  
...  

The leachate humic fraction is a good sequestering agent towards toxic metal ions, influencing their aqueous solution behaviour and their environmental impact.


2013 ◽  
Vol 273 ◽  
pp. 68-74 ◽  
Author(s):  
Yun-Hai Liu ◽  
You-Qun Wang ◽  
Zhi-Bin Zhang ◽  
Xiao-Hong Cao ◽  
Wen-Bin Nie ◽  
...  

2014 ◽  
Vol 496-500 ◽  
pp. 183-186
Author(s):  
Zhen Xu ◽  
Wei Liu ◽  
Fan Gong Kong ◽  
Shou Juan Wang ◽  
Hong Lei Chen

The removal of Cr (VI) from aqueous solution is paying more and more attention due to the higher concern of environmental influence of this ion. In this paper, the biodegradable cellulosic fibers were modified with the grafting reaction to introduce the amide groups onto the fibers. In the grafting reaction, the toluene diisocyanate was firstly grafted on the surface of natural fibers, and then the 3-Chloro-2-hydroxypropyltrimethylammonium chloride (HPTMAC), as a high efficiency trapping agent of Cr (VI), was introduced through the condensation reaction. The modified fibers was characterized by infrared spectroscopy (IR) and elemental analysis. The modified fibers were applied to adsorb chromium (VI) ion from aqueous solution. The adsorption capability of the modified fibers was evaluated under different pH, time and temperature. The optimal adsorption conditions were obtained. The results showed that the grafted fibers had high efficient adsorption of chromium (VI) ion.


2021 ◽  
Author(s):  
Jia Lin ◽  
Yude Zhang ◽  
Qian Zhang ◽  
Jinli Shang ◽  
Fuyao Deng

Abstract A benzene sulfonate modified hydrotalcite (SO3-LDH) was synthesized by a facile one-pot hydrothermal technique, which can efficiently remove methyl orange (MO), Congo red (CR) and orange II (OII) from aqueous solution. After modified by benzene sulfonate, the microstructure of hydrotalcite changes obviously, from the cellular structure to the stacking structure formed by the face-face contact of hydrotalcite nanosheets, which resulted in much more exchangeable nitrate ions to remain in the interlayer space. The pre-insertion of benzene sulfonate as a pillar expanded the interlayer gallery, which facilitated the pollutant anions (MO, CR and OII) into the interlayer of LDH in the subsequent adsorption process. The maximum adsorption capacity of SO3-LDH for MO, CR and OII was 4200.8 mg/g, 1252.0 mg/g and 1670.6 mg/g respectively, which is approximately 1.86 times, 1.8 times and 2.32 times that of the pristine NO3-LDH, respectively. The removal mechanism of anionic dyes was determined as anion exchange between NO3− ions and dye molecules. The adsorption behavior for MO and OII is multilayer adsorption, while the adsorption behavior for CR is monolayer adsorption. The adsorption process mainly was controlled by the chemical bonding between the dye molecules and adsorbent active sites. The benzene sulfonate modified LDH has a great potential to be used as a high-efficient adsorbent to remove anionic dyes from aqueous solution.


2020 ◽  
Vol 18 ◽  
pp. 100401 ◽  
Author(s):  
Hasna Ouassif ◽  
El Mostafa Moujahid ◽  
Redouane Lahkale ◽  
Rachid Sadik ◽  
Fatima Zahra Bouragba ◽  
...  

ChemCatChem ◽  
2018 ◽  
Vol 10 (21) ◽  
pp. 4781-4781
Author(s):  
Jianhui Li ◽  
Shaopo He ◽  
Kuan Zhang ◽  
Ziyi Quan ◽  
Qiheng Shan ◽  
...  

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