The fabrication composite material of bimetallic micro/nanostructured palladium–platinum alloy and graphene on nickel foam for the enhancement of electrocatalytic activity

2021 ◽  
Vol 45 (14) ◽  
pp. 6550-6559
Author(s):  
Xiuqi Dong ◽  
Shixiang Lu ◽  
Wenguo Xu ◽  
Shuguang Li
Keyword(s):  
Composite Material ◽  
Graphene Oxide ◽  
Electrocatalytic Activity ◽  
Ethanol Oxidation ◽  
Nickel Foam ◽  
Catalytic Efficiency ◽  
Immersion Method ◽  
Platinum Alloy ◽  
Reduced Graphene ◽  
Palladium Platinum

A composite of micro/nanostructured palladium–platinum alloy, reduced graphene oxide and polydopamine on nickel foam was obtained by a chemical immersion method and anneal method with high catalytic efficiency for the ethanol oxidation.

Fabrication of dog-bone shaped Au NRcore–Pt/Pdshell trimetallic nanoparticle-decorated reduced graphene oxide nanosheets for excellent electrocatalysis

2016 ◽  
Vol 4 (10) ◽  
pp. 3765-3776 ◽  
Author(s):  
Soumen Dutta ◽  
Chaiti Ray ◽  
Anup Kumar Sasmal ◽  
Yuichi Negishi ◽  
Tarasankar Pal
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Electrocatalytic Activity ◽  
Oxidation Reaction ◽  
Ethanol Oxidation ◽  
Graphene Oxide Nanosheets ◽  
Ethanol Oxidation Reaction ◽  
Dog Bone ◽  
Reduced Graphene

Dog-bone shaped Au NRcore–Pt/Pdshell decorated reduced graphene oxide nanocomposites (GMTs) exhibit outstanding electrocatalytic activity and durability towards ethanol oxidation reaction.

scholarly journals Synthesis of Fe3O4-Reduced Graphene Oxide Modified Tissue-Paper and Application in the Treatment of Methylene Blue

2019 ◽  
Vol 35 (3) ◽  
Author(s):  
Le Thanh Huyen ◽  
Dao Sy Duc ◽  
Nguyen Xuan Hoan ◽  
Nguyen Huu Tho ◽  
Nguyen Xuan Viet
Keyword(s):  
Methylene Blue ◽  
Composite Material ◽  
Wastewater Treatment ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Dye Removal ◽  
Catalytic Efficiency ◽  
Hazardous Materials ◽  
Tissue Paper ◽  
Reduced Graphene

Graphene-based composites have received a great deal of attention in recent year because the presence of graphene can enhance the conductivity, strength of bulk materials and help create composites with superior qualities. Moreover, the incorporation of metal oxide nanoparticles such as Fe3O4 can improve the catalytic efficiency of composite material. In this work, we have synthesized a composite material with the combination of reduced graphene oxide (rGO), and Fe3O4 modified tissue-paper (mGO-PP) via a simple hydrothermal method, which improved the removal efficiency of the of methylene blue (MB) in water. MB blue is used as the model of contaminant to evaluate the catalytic efficiency of synthesized material by using a Fenton-like reaction. The obtained materials were characterized by SEM, XRD. The removal of materials with methylene blue is investigated by UV-VIS spectroscopy, and the result shows that mGO-PP composite is the potential composite for the color removed which has the removal efficiency reaching 65% in acetate buffer pH = 3 with the optimal time is 7 h. Keywords Graphene-based composite, methylene blue, Fenton-like reaction. References [1] Ma Joshi, Rue Bansal, Reng Purwar, Colour removal from textile effluents, Indian Journal of Fibre & Textile Research, 29 (2004) 239-259 http://nopr.niscair.res.in/handle/123456789/24631.[2] Kannan Nagar, Sundaram Mariappan, Kinetics and mechanism of removal of methylene blue by adsorption on various carbons-a comparative study, Dyes and pigments, 51 (2001) 25-40 https://doi.org/10.1016/S0143-7208(01)00056-0.[3] K Rastogi, J. N Sahu, B. C Meikap, M. N Biswas, Removal of methylene blue from wastewater using fly ash as an adsorbent by hydrocyclone, Journal of hazardous materials, 158 (2008) 531-540.https://doi.org/10.1016/j.jhazmat.2008.01. 105.[4] Qin Qingdong, Ma Jun, Liu Ke, Adsorption of anionic dyes on ammonium-functionalized MCM-41, Journal of Hazardous Materials, 162 (2009) 133-139 https://doi.org/10.1016/j.jhazmat. 2008.05.016.[5] Mui Muruganandham, Rps Suri, Sh Jafari, Mao Sillanpää, Lee Gang-Juan, Jaj Wu, Muo Swaminathan, Recent developments in homogeneous advanced oxidation processes for water and wastewater treatment, International Journal of Photoenergy, 2014 (2014). http://dx. doi.org/10.1155/2014/821674.[6] Herney Ramirez, Vicente Miguel , Madeira Luis Heterogeneous photo-Fenton oxidation with pillared clay-based catalysts for wastewater treatment: a review, Applied Catalysis B: Environmental, 98 (2010) 10-26 https://doi.org/ 10.1016/j.apcatb.2010.05.004.[7] Guo Rong, Jiao Tifeng, Li Ruifei, Chen Yan, Guo Wanchun, Zhang Lexin, Zhou Jingxin, Zhang Qingrui, Peng Qiuming, Sandwiched Fe3O4/carboxylate graphene oxide nanostructures constructed by layer-by-layer assembly for highly efficient and magnetically recyclable dye removal, ACS Sustainable Chemistry & Engineering, 6 (2017) 1279-1288 https://doi.org/10.1021/acssuschemeng.7b03635.[8] Sun Chao, Yang Sheng-Tao, Gao Zhenjie, Yang Shengnan, Yilihamu Ailimire, Ma Qiang, Zhao Ru-Song, Xue Fumin, Fe3O4/TiO2/reduced graphene oxide composites as highly efficient Fenton-like catalyst for the decoloration of methylene blue, Materials Chemistry and Physics, 223 (2019) 751-757 https://doi.org/ 10.1016/j.matchemphys.2018.11.056.[9] Guo Hui, Ma Xinfeng, Wang Chubei, Zhou Jianwei, Huang Jianxin, Wang Zijin, Sulfhydryl-Functionalized Reduced Graphene Oxide and Adsorption of Methylene Blue, Environmental Engineering Science, 36 (2019) 81-89 https://doi. org/10.1089/ees.2018.0157.[10] Zhao Lianqin, Yang Sheng-Tao, Feng Shicheng, Ma Qiang, Peng Xiaoling, Wu Deyi, Preparation and application of carboxylated graphene oxide sponge in dye removal, International journal of environmental research and public health, 14 (2017) 1301 https://doi.org/10.3390/ijerph14111301.[11] Yu Dandan, Wang Hua, Yang Jie, Niu Zhiqiang, Lu Huiting, Yang Yun, Cheng Liwei, Guo Lin, Dye wastewater cleanup by graphene composite paper for tailorable supercapacitors, ACS applied materials & interfaces, 9 (2017) 21298-21306 https://doi.org/10.1021/acsami.7b05318.[12] Wang Hou, Yuan Xingzhong, Wu Yan, Huang Huajun, Peng Xin, Zeng Guangming, Zhong Hua, Liang Jie, Ren MiaoMiao, Graphene-based materials: fabrication, characterization and application for the decontamination of wastewater and wastegas and hydrogen storage/generation, Advances in Colloid and Interface Science, 195 (2013) 19-40 https://doi. org/10.1016/j.cis.2013.03.009.[13] Marcano Daniela C, Kosynkin Dmitry V, Berlin Jacob M, Sinitskii Alexander, Sun Zhengzong, Slesarev Alexander, Alemany Lawrence B, Lu Wei, Tour James M, Improved synthesis of graphene oxide, ACS nano, 4 (2010) 4806-4814 https://doi.org/10.1021/nn1006368.[14] Zhang Jiali, Yang Haijun, Shen Guangxia, Cheng Ping, Zhang Jingyan, Guo Shouwu, Reduction of graphene oxide via L-ascorbic acid, Chemical Communications, 46 (2010) 1112-1114 http://doi. org/10.1039/B917705A [15] Gong Ming, Zhou Wu, Tsai Mon-Che, Zhou Jigang, Guan Mingyun, Lin Meng-Chang, Zhang Bo, Hu Yongfeng, Wang Di-Yan, Yang Jiang, Nanoscale nickel oxide/nickel heterostructures for active hydrogen evolution electrocatalysis, Nature communications, 5 (2014) 4695 https:// doi.org/10.1038/ncomms5695.[16] Wu Zhong-Shuai, Yang Shubin, Sun Yi, Parvez Khaled, Feng Xinliang, Müllen Klaus, 3D nitrogen-doped graphene aerogel-supported Fe3O4 nanoparticles as efficient electrocatalysts for the oxygen reduction reaction, Journal of the American Chemical Society, 134 (2012) 9082-9085 https://doi.org/10.1021/ja3030565.[17] Nguyen Son Truong, Nguyen Hoa Tien, Rinaldi Ali, Nguyen Nam Van, Fan Zeng, Duong Hai Minh, Morphology control and thermal stability of binderless-graphene aerogels from graphite for energy storage applications, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 414 (2012) 352-358 https://doi.org/ 10.1016/j.colsurfa.2012.08.048.[18] Deng Yang, Englehardt James D, Treatment of landfill leachate by the Fenton process, Water research, 40 (2006) 3683-3694 https://doi.org/ 10.1016/j.watres.2006.08.009.    

scholarly journals Enhanced Electrocatalytic Activity of Pt Particles Supported on Reduced Graphene Oxide/Poly(3,4-ethylenedioxythiophene) RGO/PEDOT Composite towards Ethanol Oxidation

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Juanito Raphael F. Foronda ◽  
Stellar Marie R. Cabrera ◽  
Darrel L. Cumpas ◽  
Paolo Gio A. Villar ◽  
Joshua L. Tan ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Fuel Cells ◽  
Reduced Graphene Oxide ◽  
Electrocatalytic Activity ◽  
Ethanol Oxidation ◽  
Hybrid Composites ◽  
Anodic Current Density ◽  
Direct Ethanol Fuel Cells ◽  
Reduced Graphene ◽  
Platinum Particles

Catalysts in fuel cells are normally platinum based because platinum exhibits high electrocatalytic activity towards ethanol oxidation in acidic medium. However, bulk Pt is expensive and rare in nature. To reduce the consumption of Pt, a support material or matrix is needed to disperse Pt on its surface as micro- or nanoparticles with potential application as anode material in direct ethanol fuel cells (DEFCs). In this study, a composite material consisting of platinum particles dispersed on reduced graphene oxide/poly(3,4-ethylenedioxythiophene) (RGO/PEDOT) support was electrochemically prepared for ethanol oxidation in sulfuric acid electrolyte. PEDOT, a conductive polymer, was potentiodynamically polymerized from the corresponding monomer, 0.10 M EDOT in 0.10 M HClO4electrolyte. The PEDOT-modified electrode was used as a substrate for exfoliated graphene oxide (EGO) which was prepared by electrochemical exfoliation of graphite from carbon rod of spent batteries and subsequently reduced to form RGO. The Pt/RGO/PEDOT composite gave the highest electrocatalytic activity with an anodic current density of 2688.7 mA·cm−2at E = 0.70 V (versus Ag/AgCl) towards ethanol oxidation compared to bare Pt electrode and other composites. Scanning electron microscopy (SEM) revealed the surface morphology of the hybrid composites while energy dispersive X-ray (EDX) confirmed the presence of all the elements for the Pt/RGO/PEDOT composite.

Cobalt-iron spinel/reduced graphene oxide composite material for supercapacitor applications

2021 ◽  
Vol 717 (1) ◽  
pp. 60-71
Author(s):  
M. A. Hodlevska ◽  
R. I. Zapukhlyak ◽  
V. M. Boychuk ◽  
V. O. Kotsyubynsky ◽  
A. I. Kachmar ◽  
...  
Keyword(s):  
Composite Material ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Oxide Composite ◽  
Reduced Graphene ◽  
Cobalt Iron ◽  
Oxide Composite Material ◽  
Supercapacitor Applications
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