scholarly journals Review on green carbon dot-based materials for the photocatalytic degradation of dyes: fundamentals and future perspective

2021 ◽  
Author(s):  
Nivetha Basavaraj ◽  
Anithadevi Sekar ◽  
Rakhi Yadav

Systematic illustration of CDs derived from green sources for potential photocatalytic dye degradation by altering the fundamental properties.

2019 ◽  
Vol 19 (6) ◽  
pp. 3479-3486 ◽  
Author(s):  
Nilam Qureshi ◽  
Manish Shinde ◽  
Sudhir Arbuj ◽  
Sunit Rane ◽  
Anand Bhalerao ◽  
...  

We report tunable-morphology oriented facile yet scalable route to synthesize 1D (nanorod) and 2D (nanobelt) MoO3 nanostructures at gram scale using conventional as well as sonochemistry assisted sol–gel technique. The structural, morphological and optical properties of the samples can be befittingly altered by varying the synthesis protocol. The resultant orthorhombic MoO3 nanomorphs demonstrated efficient and expeditious photocatalytic degradation of the pollutant dye, Methylene Blue (MB). We have observed that appreciable photocatalytic MB dye-degradation can be accomplished within 30 minutes with high rate constants of 0.0786 min−1 and 0.233 min−1 for rod and belt-like MoO3-nanostructures, respectively. The pilot results indicate that the resultant MoO3 nanomorphs can be potentially used as solar light driven industrial photocatalyst material with their intrinsic photostability.


RSC Advances ◽  
2020 ◽  
Vol 10 (70) ◽  
pp. 43066-43074
Author(s):  
Daniel Saliba ◽  
Salah Eddin El Jamal ◽  
Antranik Jonderian ◽  
Manal Ammar ◽  
Mohamad Hmadeh ◽  
...  

Hierarchical structures of Cd Al LDH of various cationic ratios of Cd : Al are successfully synthesized via the reaction diffusion framework. The obtained microspheres are investigated for the photocatalytic degradation of methylene blue.


Crystals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 923
Author(s):  
Nasir Shehzad ◽  
Muhammad Zafar ◽  
Muhammad Ashfaq ◽  
Abdul Razzaq ◽  
Parveen Akhter ◽  
...  

Dyestuff is one of the most widely released pollutants into the environment. Many approaches have been considered to deal with the dye removal from polluted water such as adsorption, ultrafiltration, osmosis, solvent extraction and photocatalytic degradation. The photocatalytic degradation process is one of the most beneficial, economical and environmentally friendly ways to degrade the organic pollutants from wastewater. In this study, an efficient ferrite-based photocatalyst, AgFeO2/rGO/TiO2 was successfully developed using simple deposition and reflux method. Physical, chemical and structural properties were analyzed by using XRD, FTIR Raman and PL spectroscopy. The efficiency of photocatalyst was investigated for the decolorization of methyl blue (MB) dye and activity was measured through UV-vis spectroscopy. The effect of parameters like pH, concentrations of MB dye, and loading of silver ferrite (AgFeO2) was investigated. The study depicted that the properties of TiO2 were improved due to addition of silver ferrite and reduced graphene oxide (rGO). The 2.5% AgFeO2/rGO/TiO2 exhibited the highest efficiency and completely degraded the 50 ppm of MB dye in 30 min. The parametric study revealed that dye decolorization is faster in a neutral solution than in basic and acidic medium. The higher performance of the photocatalyst was attributed to the reduced charge recombination and improved optical properties. Thus, AgFeO2/rGO/TiO2 can be a potential composite for photocatalytic dye degradation and other photocatalytic applications under UV-Visible light irradiations.


RSC Advances ◽  
2015 ◽  
Vol 5 (54) ◽  
pp. 43815-43823 ◽  
Author(s):  
Aarti Sharma ◽  
Raj Kumar Dutta

Photocatalytic dye degradation of CuO nanoparticles in the presence of K2S2O8.


RSC Advances ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 6027-6038 ◽  
Author(s):  
Zichan Xin ◽  
Li Li ◽  
Xiuli Zhang ◽  
Wenzhi Zhang

A series of chrysanthemum-like composites Ag/ZnO were prepared by the microwave-assisted hydrothermal synthesis, which well showed the ability of photocatalytic degradation of dyes and hydrogen production.


2019 ◽  
Vol 43 (44) ◽  
pp. 17457-17465 ◽  
Author(s):  
Marjan Abedi ◽  
Ghodrat Mahmoudi ◽  
Payam Hayati ◽  
Barbara Machura ◽  
Fedor I. Zubkov ◽  
...  

A new picolinate-driven Ni/K MOF was prepared by different methods, fully characterized, and explored in the photocatalytic degradation of bromocresol green.


2021 ◽  
Vol 5 (3) ◽  
pp. 82
Author(s):  
Preety Ahuja ◽  
Sanjeev Kumar Ujjain ◽  
Rajni Kanojia ◽  
Pankaj Attri

Transition metal oxides (TMO) and their carbon composites have become a glittering upcoming material science candidate. Their interesting properties, such as their meticulous morphology, plentiful availability, flexible surface chemistry along with outstanding mechanical, thermal, and optical properties make them ideal for efficient photocatalytic dye degradation. An extensive range of TMO, and their carbon composites are reviewed highlighting the progression and opportunities for the photocatalytic degradation of dyes. Here, we concisely describe the numerous techniques to extend the optical absorption of these TMOs involving dye sensitization, metal doping, etc. Besides this, an overview of all aspects of dye degradation along with the prevailing challenges for future utilization and development of such nanocomposites towards highly efficient dye degradation system are also reported.


2017 ◽  
Vol 10 (2) ◽  
pp. 109-117 ◽  
Author(s):  
Dnyaneshwar R. Shinde ◽  
Popat S. Tambade ◽  
Manohar G. Chaskar ◽  
Kisan M. Gadave

Abstract. In this study, we evaluated the photocatalytic activities of analytical reagent (AR) grade ZnO, TiO2, and SnO2 to identify a low-cost photocatalyst for dye degradation. The obtained samples of ZnO, TiO2, and SnO2 were characterised by X-ray diffractogram (XRD), scanning electron microscope imaging, and UV-VIS diffuse reflectance spectroscopy. The decolourisation of three structurally diverse dyes, namely crystal violet, basic blue, and methyl red under solar irradiation, was used to evaluate the photocatalytic activities of three metal oxides. The photocatalytic activities of the received three metal oxides were tested with the photocatalytic degradation of dyes and compared with Degussa P-25. Dye solutions with each metal oxide at initial pH 9 were subjected to irradiation under sunlight and monitored for up to the stage of complete decolourisation. The results indicate that ZnO exhibited the highest photocatalytic activity as compared to TiO2 and SnO2 as well as that of Degussa P-25 (TiO2). The photocatalytic dye decolourisation rates with ZnO were 1.14–1.35, 1.70–3.1, and 4–8.5 times higher than those of the Degussa P-25, TiO2, and SnO2, respectively. The percentage COD removal was studied for ZnO and partial removal was observed at the decolourisation stage. To enhance photocatalytic activity of AR grade ZnO, it was loaded with Ag metal and about 20 % enhancement in the activity was observed.


2019 ◽  
Vol 51 (3) ◽  
pp. 337-341
Author(s):  
R. Rehman ◽  
W. Uz-Zaman ◽  
A. Abbas ◽  
L. Mitu

The aim of this work was to investigate the removal of dyes from wastewater by photocatalytic degradation using a modified assembly of photolysis reactor. It was more efficient and dye degradation occurred very fast. UV/Visible spectrophotometry was used to monitor the reaction. The degradation of dyes with different catalysts was compared and found to follow first-order kinetics. The optimal result for Methylene Blue was t(1/2)=4 min, k = 0.4471 min-1, R2 = 0.9650, for Tartrazine - t(1/2) = 1.2 min, k = 0.9723 min-1, R2 = 0.9980 and for Brilliant Green - t(1/2) = 0.8 min, k = 0.9716 min-1, R2 = 0.9938. So, it can be efficiently employed on a larger scale. Keywords: Methylene Blue, Tartrazine, Brilliant Green, Photolysis, Degradation.


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