scholarly journals Throwing light on the current developments of two dimensional metal organic framework nanosheets (2D MONs)

2021 ◽  
Author(s):  
Shabnam Khan ◽  
M. Shahid

Due to the fascinating features such as ultra-thickness, great surface-to-volume atom ratios, abundantly available unsaturated coordination sites, highly porous structure, enhanced conductivity, and easily tunable structure, considerable research interest in...

RSC Advances ◽  
2021 ◽  
Vol 11 (16) ◽  
pp. 9353-9360
Author(s):  
Rui Fan ◽  
Ning Kang ◽  
Yuzhen Li ◽  
Lizhen Gao

Layered double hydroxide (LDH) is employed as a layered template to synthesize ultrathin Ni-MOF-74 nanosheets. The two-dimensional structure brings numerous exposed unsaturated active sites and enhanced conductivity for Ni-MOF-74.


2008 ◽  
Vol 73 (1) ◽  
pp. 24-31
Author(s):  
Dayu Wu ◽  
Genhua Wu ◽  
Wei Huang ◽  
Zhuqing Wang

The compound [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2 was obtained by the reaction of Cd(ClO4)2, bis(1-pyrazinylethylidene)hydrazine (L) and 4,4'-bipyridine in aqueous MeOH. Single-crystal X-ray diffraction has revealed its two-dimensional metal-organic framework. The 2-D layers superpose on each other, giving a channel structure. The square planar grids consist of two pairs of shared edges with Cd(II) ion and a 4,4'-bipyridine molecule each vertex and side, respectively. The square cavity has a dimension of 11.817 × 11.781 Å. Two guest molecules of bis(1-pyrazinylethylidene)hydrazine are clathrated in every hydrophobic host cavity, being further stabilized by π-π stacking and hydrogen bonding. The results suggest that the hydrazine molecules present in the network serve as structure-directing templates in the formation of crystal structures.


2017 ◽  
Vol 139 (24) ◽  
pp. 8312-8319 ◽  
Author(s):  
Ming Xu ◽  
Shuai Yuan ◽  
Xin-Yu Chen ◽  
Yu-Jie Chang ◽  
Gregory Day ◽  
...  

CrystEngComm ◽  
2021 ◽  
Author(s):  
Qing Luo ◽  
Zhen Ding ◽  
Huamin Sun ◽  
Zhen Cheng ◽  
Naien SHI ◽  
...  

Ultrathin two-dimensional (2D) metal-organic framework (MOF) nanosheets are prosperous advanced materials due to their particularly thin thickness and exposed active sites. The difficulty in the controlled synthesis of 2D MOF...


Author(s):  
Jiajun Song ◽  
Jianzhong Zheng ◽  
Anneng Yang ◽  
Hong Liu ◽  
Zeyu Zhao ◽  
...  

Two-dimensional (2D) conductive metal-organic frameworks (MOFs) can not only inherit the high porosity and tailorability of traditional MOFs but also exhibit unique charge transport properties, offering promising opportunities for applications...


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