scholarly journals Elucidating the role of non-covalent interactions in unexpectedly high and selective CO2 uptake and catalytic conversion of porphyrin-based ionic organic polymers

2021 ◽  
Author(s):  
Sinem Tuncel Kostakoğlu ◽  
Yu. Chumakov ◽  
Yunus Zorlu ◽  
Ali Enis Sadak ◽  
Serpil Denizalti ◽  
...  
Keyword(s):  
Specific Surface ◽  
Catalytic Conversion ◽  
Co2 Uptake ◽  
Organic Polymers ◽  
Surface Areas ◽  
Non Covalent Interactions ◽  
Specific Surface Areas ◽  
Covalent Interactions

Here, we present the viologen-porphyrin based ionic covalent organic polymers (H2-ICOP and Zn-ICOP) with multiple CO2-philic sites. The specific surface areas of H2-ICOP and Zn-ICOP were found to be 9...

Truxene-based porous polymers: from synthesis to catalytic activity

2018 ◽  
Vol 9 (36) ◽  
pp. 4585-4595 ◽  
Author(s):  
Jordy Guadalupe ◽  
Ana M. Ray ◽  
Eva M. Maya ◽  
Berta Gómez-Lor ◽  
Marta Iglesias
Keyword(s):  
Catalytic Activity ◽  
Specific Surface ◽  
Porous Polymers ◽  
Organic Polymers ◽  
Porous Organic Polymers ◽  
Surface Areas ◽  
Specific Surface Areas

New, robust, insoluble porous organic polymers based on the semiconducting platform of hexamethyltruxene with high Brunauer–Emmett–Teller specific surface areas and interesting catalytic activity are presented.

scholarly journals Advances in Porous Organic Polymers: Syntheses, Structures, and Diverse Applications

2021 ◽  
Author(s):  
Mohamed Gamal Mohamed ◽  
Ahmed F. M. EL-Mahdy ◽  
Mohammed G. Kotp ◽  
Shiao-Wei Kuo
Keyword(s):  
Specific Surface ◽  
Organic Polymers ◽  
High Chemical ◽  
Porous Organic Polymers ◽  
Thermal Stabilities ◽  
Surface Areas ◽  
Specific Surface Areas

Porous organic polymers (POPs) are organic macromolecules that are considered emerging materials because of their high specific surface areas, tunable porosities, low densities, high chemical and thermal stabilities, variable compositions,...

Role of non-covalent interactions in the supramolecular architectures of mercury(ii) diphenyldithiophosphates: An experimental and theoretical investigation

2021 ◽  
Vol 45 (4) ◽  
pp. 2249-2263
Author(s):  
Pretam Kumar ◽  
Snehasis Banerjee ◽  
Anu Radha ◽  
Tahira Firdoos ◽  
Subash Chandra Sahoo ◽  
...  
Keyword(s):  
Theoretical Investigation ◽  
Supramolecular Organization ◽  
Π Interactions ◽  
Supramolecular Architectures ◽  
Non Covalent Interactions ◽  
Covalent Interactions

The H-bond, spodium bond and CH⋯π interactions playing an important role in the supramolecular organization of two mercury(ii) diphenyldithiophosphate complexes have been discussed.

scholarly journals Ultrafine porous boron nitride nanofibers synthesized via a freeze-drying and pyrolysis process and their adsorption properties

RSC Advances ◽  
2016 ◽  
Vol 6 (2) ◽  
pp. 1253-1259 ◽  
Author(s):  
Jing Lin ◽  
Lulu Xu ◽  
Yang Huang ◽  
Jie Li ◽  
Weijia Wang ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Specific Surface ◽  
Freeze Drying ◽  
Adsorption Properties ◽  
Pyrolysis Process ◽  
Surface Areas ◽  
Aspect Ratios ◽  
Large Pore ◽  
Specific Surface Areas

Ultrafine porous boron nitride nanofibers with high aspect ratios, high specific surface areas and large pore volumes has been synthesized in large quantity via a freeze-drying and post pyrolysis process.

scholarly journals Experimental Investigation of Coal Dust Wettability Based on Surface Contact Angle

2016 ◽  
Vol 2016 ◽  
pp. 1-8 ◽  
Author(s):  
Gang Zhou ◽  
Han Qiu ◽  
Qi Zhang ◽  
Mao Xu ◽  
Jiayuan Wang ◽  
...  
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Specific Surface ◽  
Coal Dust ◽  
Single Point ◽  
Contact Angles ◽  
Critical Surface ◽  
Volume Percentage ◽  
Surface Areas ◽  
Specific Surface Areas

Wettability is one of the key chemical properties of coal dust, which is very important to dedusting. In this paper, the theory of liquid wetting solid was presented firstly; then, taking the gas coal of Xinglongzhuang coal mine in China as an example, by determination of critical surface tension of coal piece, it can be concluded that only when the surface tension of surfactant solution is less than 45 mN/m can the coal sample be fully wetted. Due to the effect of particle dispersity, compared with the contact angle of milled coal particle, not all the contact angles of screened coal powder with different sizes have a tendency to increase. Furthermore, by the experiments of coal samples’ specific surface areas and porosities, it can be achieved that the volume of single-point total pore decreases with the gradual decreasing of coal’s porosity, while the ultramicropores’ dispersities and multipoint BET specific surface areas increase. Besides, by a series of contact angle experiments with different surfactants, it can be found that with the increasing of porosity and the decreasing of volume percentage of ultramicropore, the contact angle tends to reduce gradually and the coal dust is much easier to get wetted.

Facile Method To Synthesize Mesoporous Multimetal Oxides (ATiO3, A = Sr, Ba) with Large Specific Surface Areas and Crystalline Pore walls

2010 ◽  
Vol 22 (4) ◽  
pp. 1276-1278 ◽  
Author(s):  
Xiaoxing Fan ◽  
Ying Wang ◽  
Xinyi Chen ◽  
Ling Gao ◽  
Wenjun Luo ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Areas ◽  
Specific Surface Areas

The important role of non-covalent interactions for the vibrational circular dichroism of lactic acid in aqueous solution

2021 ◽  
Author(s):  
Sascha Jähnigen ◽  
Daniel Sebastiani ◽  
Rodolphe Vuilleumier
Keyword(s):  
Lactic Acid ◽  
Circular Dichroism ◽  
Computational Study ◽  
Bulk Water ◽  
Vibrational Circular Dichroism ◽  
Ab Initio Molecular Dynamics ◽  
Non Covalent Interactions ◽  
Circular Dichroïsm ◽  
Covalent Interactions

We present a computational study of vibrational circular dichroism (VCD) in solutions of (S)-lactic acid, relying on ab initio molecular dynamics (AIMD) and full solvation with bulk water. We discuss...

Carbon Microspheres Prepared by High Internal Phase Emulsion Polymerization

2011 ◽  
Vol 239-242 ◽  
pp. 3105-3108
Author(s):  
Ming Xian Liu ◽  
Li Hua Gan ◽  
Jun Hu ◽  
Hong Lai Liu ◽  
Long Wu Chen
Keyword(s):  
Electron Microscopy ◽  
Specific Surface ◽  
Aqueous Phase ◽  
Apparent Density ◽  
Tween 80 ◽  
Carbon Microspheres ◽  
High Internal Phase Emulsion ◽  
Surface Areas ◽  
Internal Phase ◽  
Specific Surface Areas

In this paper, we present a novel approach for the synthesis of carbon microspheres via the polymerization of a high internal phase emulsion (HIPE). By using Span 80 and Tween 80 as emulsifiers, 1iquid paraffin as oil phase, and the mixture of resorcinol/formaldehyde (R/F) solution as aqueous phase, an O/W emulsion was obtained. This emulsion phase inverted to a W/O HIPE induced by ammonia which served as the polymerization catalyst. Carbon microspheres (CMs) were prepared by polymerization of the HIPE, followed by drying and carbonization. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) analyzer were used to characterize as-prepared CMs. The results indicate that, in case of 0.25 wt% ammonia of the HIPE, the diameters of CMs decreased from about 2 to 1 μm when the mass fraction of aqueous R/F decreased from 0.714 to 0.357; the apparent density and the specific surface areas of the CMs, however, did not change obviously, which are about 0.6 g/cm3and 200 m2/g, respectively. The dosage of ammonia has a significant influence on the morphology and properties of CMs. With increasing of the ammonia mass to 1 wt% of the HIPE, the resultant carbon materials comprise not only CMs, but also some carbon sheets; the apparent density of which increased to 0.9 g/cm3and the specific surface areas of which decreased to below 100 m2/g. In addition, the other parameters for CMs preparation were also investigated. It was found that the proper conditions were controlling the temperature of 303-333 K and the oil/aqueous phase mass ratio of 2.5:7.

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