Metal-Free Hydrogen Evolution Cross-Coupling Enabled by Synergistic Photoredox and Polarity Reversal Catalysis

2021 ◽  
Author(s):  
Jilei Cao ◽  
Xiaona Yang ◽  
Lishuang Ma ◽  
Kanghui Lu ◽  
Rong Zhou
Keyword(s):  
Hydrogen Evolution ◽  
Cross Coupling ◽  
Polarity Reversal ◽  
Metal Free ◽  
Free Hydrogen ◽  
Synergistic Combination

A synergistic combination of photoredox and polarity reversal catalysis enabled a hydrogen evolution cross-coupling of silanes with H2O, alcohols, phenols, and silanols, which afforded the corresponding silanols, monosilyl ethers, and...

Noble metal-free hydrogen evolution catalysts for water splitting

2015 ◽  
Vol 44 (15) ◽  
pp. 5148-5180 ◽  
Author(s):  
Xiaoxin Zou ◽  
Yu Zhang
Keyword(s):  
Hydrogen Evolution ◽  
Water Splitting ◽  
Noble Metal ◽  
Metal Free ◽  
Free Hydrogen

This review summarizes the recent research efforts toward noble metal-free hydrogen evolution electrocatalysts.

A sandwich-type polyoxometalate for efficient noble-metal-free hydrogen evolution upon visible light irradiation

2019 ◽  
Vol 369 ◽  
pp. 54-59 ◽  
Author(s):  
Guan-Hua Zhang ◽  
Wen-Bin Yang ◽  
Wei-Ming Wu ◽  
Xiao-Yuan Wu ◽  
Lei Zhang ◽  
...  
Keyword(s):  
Visible Light ◽  
Hydrogen Evolution ◽  
Noble Metal ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Metal Free ◽  
Free Hydrogen ◽  
Sandwich Type

Facile Synthesis of CoSe2 Nanoparticles and their Electrocatalytic Performance for Hydrogen Evolution Reaction

2016 ◽  
Vol 852 ◽  
pp. 916-920 ◽  
Author(s):  
Hong Xue Qi ◽  
Yuan Qiang Song ◽  
Zhong Ping Liu ◽  
Lan Xiang Ji ◽  
Jian Guo Deng
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Energy Efficient ◽  
Average Diameter ◽  
Facile Synthesis ◽  
One Pot ◽  
Metal Free ◽  
Highly Active ◽  
Electrocatalytic Performance ◽  
Free Hydrogen

For more energy-efficient and economical hydrogen production, highly active noble metal-free hydrogen evolution catalysts are a priority for all. Herein, we report a facile one-pot hydrothermal synthesis of CoSe2 nanoparticles with their electrocatalytic performance for hydrogen evolution reaction. The synthesized CoSe2 nanoparticles have an average diameter of 50-70 nm with a uniform distribution. They also exhibited good electrocatalytic performance for hydrogen evolution reaction with the onset overpotential and Tafel slope of 140 mV and 95 mV/dec, respectively. The results provide a facile and effective way for the exploration of efficient Co-based HER catalysts.

Conjugated polymer dots/graphitic carbon nitride nanosheet heterojunctions for metal-free hydrogen evolution photocatalysis

2019 ◽  
Vol 7 (1) ◽  
pp. 303-311 ◽  
Author(s):  
Wei Zhou ◽  
Tao Jia ◽  
Haixian Shi ◽  
Dingshan Yu ◽  
Wei Hong ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Conjugated Polymer ◽  
Carbon Nitride ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Metal Free ◽  
Polymer Dots ◽  
Free Hydrogen ◽  
Metallic Catalyst

Pdot/g-C3N4 heterojunctions exhibit an HER of 929.3 μmol h−1 g−1 and AQE of 5.7% at 420 nm without a metallic catalyst.

scholarly journals Surface modification of g-C3N4 by hydrazine: Simple way for noble-metal free hydrogen evolution catalysts

2016 ◽  
Vol 286 ◽  
pp. 339-346 ◽  
Author(s):  
Yin Chen ◽  
Bin Lin ◽  
Hong Wang ◽  
Yong Yang ◽  
Haibo Zhu ◽  
...  
Keyword(s):  
Surface Modification ◽  
Hydrogen Evolution ◽  
Noble Metal ◽  
Metal Free ◽  
Free Hydrogen

Surface Functionalization of g-C3N4: Molecular-Level Design of Noble-Metal-Free Hydrogen Evolution Photocatalysts

2015 ◽  
Vol 21 (29) ◽  
pp. 10290-10295 ◽  
Author(s):  
Yin Chen ◽  
Bin Lin ◽  
Weili Yu ◽  
Yong Yang ◽  
Shahid M. Bashir ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Noble Metal ◽  
Surface Functionalization ◽  
Molecular Level ◽  
Metal Free ◽  
Free Hydrogen ◽  
Level Design

scholarly journals Metal-free hydrogen evolution with nanoparticles derived from pyrene via two-photon ionization induced by laser irradiation

2015 ◽  
Vol 51 (57) ◽  
pp. 11515-11518 ◽  
Author(s):  
Kei Ohkubo ◽  
Naoki Kohno ◽  
Yusuke Yamada ◽  
Shunichi Fukuzumi
Keyword(s):  
Laser Irradiation ◽  
Hydrogen Evolution ◽  
Laser Excitation ◽  
Metal Free ◽  
Two Photon ◽  
Free Hydrogen ◽  
Photon Ionization

H2 evolution occurred efficiently with nanoparticles of pyrene oligomers produced by two-photon laser excitation in cyclohexane.

scholarly journals A high-performance metal-free hydrogen-evolution reaction electrocatalyst from bacterium derived carbon

2015 ◽  
Vol 3 (14) ◽  
pp. 7210-7214 ◽  
Author(s):  
Li Wei ◽  
Huseyin Enis Karahan ◽  
Kunli Goh ◽  
Wenchao Jiang ◽  
Dingshan Yu ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Mesoporous Carbon ◽  
High Performance ◽  
Nitrogen And Phosphorus ◽  
Metal Free ◽  
Free Hydrogen

Nitrogen and phosphorus dual-doped mesoporous carbon derived from bacteria as a high performance electrocatalyst for the hydrogen evolution reaction.

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