Insight into the reversible behavior of Lewis-Brønsted basic poly(ionic liquid)s in one-pot two-step chemical fixation of CO2 to linear carbonates

2021 ◽  
Author(s):  
Yuting He ◽  
Huimin Lu ◽  
Xue Li ◽  
Jun Wu ◽  
Tiancheng Pu ◽  
...  

The multi-step reaction of CO2 over basic catalysts significantly improves the diversity of products, vividly embodying the ability of green chemistry to turn waste into treasure. However, under a Lewis...

2016 ◽  
Vol 37 (14) ◽  
pp. 1181-1187 ◽  
Author(s):  
Daniela Cordella ◽  
Antoine Debuigne ◽  
Christine Jérôme ◽  
Zdravko Kochovski ◽  
Daniel Taton ◽  
...  

ChemCatChem ◽  
2016 ◽  
Vol 8 (19) ◽  
pp. 3050-3056 ◽  
Author(s):  
Yogesh Thopate ◽  
Richa Singh ◽  
Arun K. Sinha ◽  
Vikash Kumar ◽  
Mohammad Imran Siddiqi

RSC Advances ◽  
2020 ◽  
Vol 10 (62) ◽  
pp. 37743-37748
Author(s):  
Ruka Hirai ◽  
Tatsuki Hibino ◽  
Takaichi Watanabe ◽  
Takashi Teranishi ◽  
Tsutomu Ono

Clickable ionic liquid monomers realize the one-pot synthesis of ionically conducting poly(ionic liquid)s with 1,2,3-triazolium-based backbones via click chemistry.


2022 ◽  
Vol 165 ◽  
pp. 107278
Author(s):  
Jian Wu ◽  
Yanlong Luo ◽  
Yifeng Chen ◽  
Xiaohua Lu ◽  
Xin Feng ◽  
...  

2016 ◽  
Vol 7 (14) ◽  
pp. 2521-2530 ◽  
Author(s):  
Mathilde Weiss-Maurin ◽  
Daniela Cordella ◽  
Christine Jérôme ◽  
Daniel Taton ◽  
Christophe Detrembleur

Nanogels of controlled kinetic chain length were synthesized by cobalt-mediated radical cross-linking copolymerization (CMRccP) involving a vinyl monomer and a divinyl cross-linker.


Author(s):  
Prapakorn Tantayotai ◽  
Marttin Paulraj Gundupalli ◽  
Elizabeth Jayex Panakkal ◽  
Malinee Sriariyanun ◽  
Kittipong Rattanaporn ◽  
...  

The effect of [Emim][OAc] on Celluclast 1.5 L, Accellerase 1500, and IL-tolerant (MSL2) cellulase during the saccharification of carboxymethylcellulose (CMC), Avicel (AV), rice straw (RS) was studied in one pot process (pretreatment and saccharification). The inhibition caused by [Emim][OAc] (0.5–2.0 M) with substrate loading (20–50 mg/mL) were also evaluated. In most cases, the inhibition mode of saccharification for CMC and AV was identified to be uncompetitive inhibition when the concentration of [Emim][OAc] was higher than 0.5 M. Under the influence of 0.5 M of [Emim][OAc], the Critical Concentration of Substrate (CCS) values of the Celluclast 1.5 L and Accellerase 1500 on CMC hydrolysis were determined to be at 26.59 and 33.65 mg/mL, respectively. Also, increasing in [Emim][OAc] concentration could increase in CCS values, suggesting the positive effect of [Emim][OAc] on the improvement of enzymatic saccharification. This study provides insight into the process optimization for integration of [Emim][OAc] in one pot process of biorefinery.


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