scholarly journals Homogeneous hydrogenation of saturated bicarbonate slurry to formates using multiphase catalysis

2021 ◽  
Author(s):  
Christophe Rebreyend ◽  
Evgeny A Pidko ◽  
Georgy A Filonenko

Formic acid and formate salts are key intermediates along the pathways for CO2 utilization and hydrogen storage. Herein we report a highly efficient multiphase catalytic system utilizing ruthenium PNP pincer...

2019 ◽  
Author(s):  
Andreas Weilhard ◽  
Stephen Argent ◽  
Victor Sans

We present a highly efficient catalytic system to transform carbon dioxide to formic acid under base-free conditions. Our system employs a vbasic ionic liquid as a buffer for the producty. Our results show an exceptionally active catalyst with unprecedentedly high turnover numbers and frequency.


2019 ◽  
Author(s):  
Andreas Weilhard ◽  
Stephen Argent ◽  
Victor Sans

We present a highly efficient catalytic system to transform carbon dioxide to formic acid under base-free conditions. Our system employs a vbasic ionic liquid as a buffer for the producty. Our results show an exceptionally active catalyst with unprecedentedly high turnover numbers and frequency.


Author(s):  
Kuo-Wei Huang ◽  
Sudipta Chatterjee ◽  
Indranil Dutta ◽  
Yanwei Lum ◽  
Zhiping Lai

Formic acid has been proposed as a hydrogen energy carrier because of its many desirable properties, such as low toxicity and flammability, and a high volumetric hydrogen storage capacity of...


2008 ◽  
Vol 39 (1) ◽  
pp. 139-157 ◽  
Author(s):  
Abdolkarim Zare ◽  
Alireza Hasaninejad ◽  
Mohammad Hassan Beyzavi ◽  
Ahmad Reza Moosavi Zare ◽  
Ali Khalafi-Nezhad ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (1) ◽  
pp. 16-19 ◽  
Author(s):  
Ankur Gogoi ◽  
Anindita Dewan ◽  
Utpal Bora

A mild and efficient catalytic system based on PdCl2 and Na2SO4 has been developed for the Sonogashira reaction of aryl iodides at room temperature.


ChemInform ◽  
2014 ◽  
Vol 45 (27) ◽  
pp. no-no
Author(s):  
Dilip Kumar T. Yadav ◽  
Sanil S. Rajak ◽  
Bhalchandra M. Bhanage

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