scholarly journals Multifunctional lignin-based nanocomposites and nanohybrids

2021 ◽  
Author(s):  
Erlantz Lizundia ◽  
Mika Henrikki Sipponen ◽  
Luiz Guilherme Garcia Greca ◽  
Mikhail Balakshin ◽  
Blaise Leopold Tardy ◽  
...  
Keyword(s):  
Green Chemistry ◽  
High Performance ◽  
Chemical Engineering ◽  
Significant Progress ◽  
Sustainable Materials ◽  
Lignin Utilization

Significant progress in lignins valorization and development of high-performance sustainable materials have been achieved in recent years. Reports related to lignin utilization indicate excellent prospects considering green chemistry, chemical engineering,...

Microstructures in Elastic Media

1994 ◽  
Author(s):  
Nhan Phan-Thien ◽  
Sangtae Kim
Keyword(s):  
Computational Methods ◽  
High Performance ◽  
Chemical Engineering ◽  
Elliptic Partial Differential Equations ◽  
Parallel Computers ◽  
Computational Algorithms ◽  
Applied Physics ◽  
Advanced Students ◽  
Particulate Solids ◽  
Modeling Software

This monograph describes various methods for solving deformation problems of particulate solids, taking the reader from analytical to computational methods. The book is the first to present the topic of linear elasticity in mathematical terms that will be familiar to anyone with a grounding in fluid mechanics. It incorporates the latest advances in computational algorithms for elliptic partial differential equations, and provides the groundwork for simulations on high performance parallel computers. Numerous exercises complement the theoretical discussions, and a related set of self-documented programs is available to readers with Internet access. The work will be of interest to advanced students and practicing researchers in mechanical engineering, chemical engineering, applied physics, computational methods, and developers of numerical modeling software.

scholarly journals To separate or not to separate: what is necessary and enough for a green and sustainable extraction of bioactive compounds from Brazilian citrus waste

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Vânia G. Zuin ◽  
Luize Z. Ramin ◽  
Mateus L. Segatto ◽  
Aylon M. Stahl ◽  
Karine Zanotti ◽  
...  
Keyword(s):  
High Performance ◽  
Orange Peel ◽  
Solvent Ratio ◽  
Biomass Waste ◽  
Chemical Profiles ◽  
Orange Waste ◽  
Sustainable Materials ◽  
Citrus Waste ◽  
Sustainable Extraction

AbstractIncreasing demands to obtain chemicals via greener and more sustainable materials and processes introduces concepts that should be considered and applied from lab to larger scales. Obtaining bioactive chemicals from agro-industrial non-food biomass waste can combine benign techniques and bio-circular economy to reach this goal. After extraction, evaluating profitability and environmental impacts to decide whether separation – and to what extent – is necessary or not is indispensable. This could be integrated into an approach known as sufficiency, as an important criterion for sustainability. From this perspective, Brazil’s annual generation of 8 million tons of orange waste is relevant, since citrus waste has large amounts of high-value compounds, such as pectin, d-limonene and flavonoids. This case study aimed at developing and comparing green and sustainable analytical methods to obtain flavonoids from orange peel. Homogenizer, ultrasound and microwave-assisted extractions were employed using chemometric tools, considering time, sample/solvent ratio, temperature and ethanol concentration as variables to obtain extracts containing hesperidin, naringenin, hesperetin and nobiletin. The bioactive flavonoids were determined by high-performance liquid chromatography (HPLC-UV). Microwave extraction was the most efficient method for obtaining the majority of flavonoids studied, six times more for hesperidin. Moreover, orange waste from different farming models showed diverse chemical profiles showing the importance of this alternative in natural product resources.

scholarly journals Thermal Degradation Characteristic and Flame Retardancy of Polylactide-Based Nanobiocomposites

Molecules ◽  
2018 ◽  
Vol 23 (10) ◽  
pp. 2648 ◽  
Author(s):  
Kuruma Malkappa ◽  
Jayita Bandyopadhyay ◽  
Suprakas Ray
Keyword(s):  
Thermal Degradation ◽  
Flame Retardancy ◽  
High Performance ◽  
Flame Retardants ◽  
Degradable Polymers ◽  
Melt Blending ◽  
Degradation Characteristic ◽  
Sustainable Materials ◽  
Fire Properties ◽  
Intumescent Flame Retardants

Polylactide (PLA) is one of the most widely used organic bio-degradable polymers. However, it has poor flame retardancy characteristics. To address this disadvantage, we performed melt-blending of PLA with intumescent flame retardants (IFRs; melamine phosphate and pentaerythritol) in the presence of organically modified montmorillonite (OMMT), which resulted in nanobiocomposites with excellent intumescent char formation and improved flame retardant characteristics. Triphenyl benzyl phosphonium (OMMT-1)- and tributyl hexadecyl phosphonium (OMMT-2)-modified MMTs were used in this study. Thermogravimetric analysis in combination with Fourier transform infrared spectroscopy showed that these nanocomposites release a smaller amount of toxic gases during thermal degradation than unmodified PLA. Melt-rheological behaviors supported the conclusions drawn from the cone calorimeter data and char structure of the various nanobiocomposites. Moreover, the characteristic of the surfactant used for the modification of MMT played a crucial role in controlling the fire properties of the composites. For example, the nanocomposite containing 5 wt.% OMMT-1 showed significantly improved fire properties with a 47% and 68% decrease in peak heat and total heat release rates, respectively, as compared with those of unmodified PLA. In summary, melt-blending of PLA, IFR, and OMMT has potential in the development of high-performance PLA-based sustainable materials.

High performance sustainable materials for automotive applications: dream or reality?

2021 ◽  
pp. 139-155
Author(s):  
Philippe Godano ◽  
James Taylor ◽  
Pascaline Bregeon ◽  
Davide Caprioli ◽  
Luca Mazzarella ◽  
...  
Keyword(s):  
High Performance ◽  
Automotive Applications ◽  
Sustainable Materials

Green Chemistry and Chemical Engineering, Introduction

2012 ◽  
pp. 1-4
Author(s):  
Robert A. Meyers ◽  
Paul T. Anastas ◽  
Julie B. Zimmerman
Keyword(s):  
Green Chemistry ◽  
Chemical Engineering

scholarly journals Robust formation of amorphous Sb2S3 on functionalized graphene for high-performance optoelectronic devices in the cyan-gap

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Ju-Hung Chen ◽  
Sheng-Kuei Chiu ◽  
Jin-De Luo ◽  
Shu-Yu Huang ◽  
Hsiang-An Ting ◽  
...  
Keyword(s):  
High Performance ◽  
Carrier Transport ◽  
Deposition Process ◽  
Semiconductor Materials ◽  
Functionalized Graphene ◽  
Significant Progress ◽  
Graphene Glass ◽  
Comprehensive Characterization

Abstract Despite significant progress in the fabrication and application of semiconductor materials for optical emitters and sensors, few materials can cover the cyan-gap between 450 and 500 nm. We here introduce a robust and facile method to deposit amorphous Sb2S3 films with a bandgap of 2.8 eV. By exploiting the tunable functionality of graphene, a two-dimensional material, efficient deposition from a chemical was achieved. Ozone-generated defects in the graphene were shown to be required to enhance the morphology and quality of the material and comprehensive characterization of the seed layer and the Sb2S3 film were applied to design an optimal deposition process. The resulting material exhibits efficient carrier transport and high photodetector performance as evidenced by unprecedented responsivity and detectivity in semiconductor/graphene/glass vertical heterostructures. (112 A/W, 2.01 × 1012 Jones, respectively).

scholarly journals Attempted fractionation of LB Lennox medium via reversed phase high performance liquid chromatography

2020 ◽  
Author(s):  
Wenfa Ng
Keyword(s):  
High Performance Liquid Chromatography ◽  
Liquid Chromatography ◽  
Growth Medium ◽  
Yeast Extract ◽  
High Performance ◽  
Chemical Engineering ◽  
Reversed Phase ◽  
Model Systems ◽  
Water Mixture ◽  
Rp Hplc

AbstractMass balance analysis is a highly useful tool for chemical engineering analysis of biological processes. Specifically, composition and amounts of inputs to a cell could be correlated with measurement of metabolic byproducts and outputs for inferring metabolic fluxes flowing through specific cellular metabolic pathways. However, the composition of many common microbiological growth medium remains ill-defined with batch-to-batch variation. Thus, a need exists for developing methods for effective fractionation and separation of common growth medium. Using 5 g/L yeast extract, 10 g/L tryptone, and LB Lennox medium as model systems, this work attempted the fractionation of the three complex growth mixtures using C-18 reversed phase high performance liquid chromatography (RP-HPLC). Results revealed no effective fractionation of the three mixtures. More importantly, experiment results indicated that appropriate choice of detection wavelength for visualizing the chromatogram made a huge difference to understanding the effectiveness of fractionation achieved. Specifically, in the case of yeast extract, tryptone and LB Lennox medium, 194 nm may be a more appropriate detection wavelength compared to 280 nm. Collectively, C-18 RP-HPLC was not effective in separating 5 g/L yeast extract, 10 g/L tryptone and LB Lennox medium with hydrophilic mobile phases (ethanol/water mixture).Graphical abstractShort description: Visualization of the reversed phase HPLC chromatogram at 194 nm revealed broad peaks and lack of distinct peaks indicative of fractionation of LB Lennox medium by the chromatography method. More importantly, complex ensemble of different components in the growth medium present a significant separation challenge that precludes separation or fractionation by modern liquid chromatography methods. Overall, combinatorial use of both hydrophobic and hydrophilic mobile phase with a C-18 reversed phase column could reveal the presence of a couple of main fractions in a mixture otherwise unable to be separated into distinct components.

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