scholarly journals Electrochemical upgrading of biomass-derived 5-hydroxymethylfurfural and furfural over oxygen vacancy-rich NiCoMn-layered double hydroxides nanosheets

2021 ◽  
Author(s):  
Biying Liu ◽  
Shaojun Xu ◽  
Man Zhang ◽  
Xin Li ◽  
Donato Decarolis ◽  
...  

Rational design of low-cost and active electrocatalysts is crucial for upgrading of biomass-derived chemicals into value-added products. Here, we report highly efficient catalysts of ternary NiCoMn-layered double hydroxides (NiCoMn-LDHs) nanosheets...

Author(s):  
Eva Donini ◽  
Andrea Firrincieli ◽  
Martina Cappelletti

AbstractRhodococcus spp. strains are widespread in diverse natural and anthropized environments thanks to their high metabolic versatility, biodegradation activities, and unique adaptation capacities to several stress conditions such as the presence of toxic compounds and environmental fluctuations. Additionally, the capability of Rhodococcus spp. strains to produce high value-added products has received considerable attention, mostly in relation to lipid accumulation. In relation with this, several works carried out omic studies and genome comparative analyses to investigate the genetic and genomic basis of these anabolic capacities, frequently in association with the bioconversion of renewable resources and low-cost substrates into triacylglycerols. This review is focused on these omic analyses and the genetic and metabolic approaches used to improve the biosynthetic and bioconversion performance of Rhodococcus. In particular, this review summarizes the works that applied heterologous expression of specific genes and adaptive laboratory evolution approaches to manipulate anabolic performance. Furthermore, recent molecular toolkits for targeted genome editing as well as genome-based metabolic models are described here as novel and promising strategies for genome-scaled rational design of Rhodococcus cells for efficient biosynthetic processes application.


Author(s):  
ShuXuan Liu ◽  
Huiwen Zhang ◽  
Enlai Hu ◽  
Tuyuan Zhu ◽  
ChunYan Zhou ◽  
...  

The sluggish kinetics and four electron oxidation process of oxygen evolution reaction (OER) limit the application of water splitting. Recently, NiFe-layered double hydroxides (NiFe LDHs) have shown great potential to...


2016 ◽  
Vol 52 (5) ◽  
pp. 908-911 ◽  
Author(s):  
Zhiyi Lu ◽  
Li Qian ◽  
Yang Tian ◽  
Yaping Li ◽  
Xiaoming Sun ◽  
...  

A ternary NiFeMn-LDH with an optimized transition metal ratio is developed as an advanced catalyst for the oxygen evolution reaction.


2021 ◽  
pp. 127613
Author(s):  
Jiahui Ge ◽  
Lili Lian ◽  
Xiyue Wang ◽  
Xueling Cao ◽  
Wenxiu Gao ◽  
...  

2019 ◽  
Vol 7 (6) ◽  
pp. 2831-2837 ◽  
Author(s):  
Qing Yan ◽  
Peng Yan ◽  
Tong Wei ◽  
Guiling Wang ◽  
Kui Cheng ◽  
...  

A highly-efficient water splitting device is assembled with the platinum sub-nanoclusters functionalized nickel iron layered double hydroxides and hierarchical nickel iron selenides.


2019 ◽  
Vol 55 (89) ◽  
pp. 13370-13373 ◽  
Author(s):  
Rushuo Li ◽  
Yanhui Wang ◽  
Wei Li ◽  
Shuyu Zhou ◽  
Pengfei Tian ◽  
...  

A novel Zr-doping strategy was highly effective to enhance the OER activity of NiFe LDHs via accelerating the charge transfer.


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