Continuous-flow electro-oxidative coupling of sulfides with activated methylene compounds leading to sulfur ylides

2021 ◽  
Vol 23 (8) ◽  
pp. 2956-2961
Author(s):  
Chengkou Liu ◽  
Yang Lin ◽  
Chen Cai ◽  
Chengcheng Yuan ◽  
Zheng Fang ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Continuous Flow ◽  
Sulfur Ylides

Continuous-flow electrosynthesis of sulfur ylides under catalyst- and oxidant-free conditions at rt was developed.

Highly efficient continuous-flow oxidative coupling of amines using promising nanoscale CeO2–M/SiO2 (M = MoO3 and WO3) solid acid catalysts

RSC Advances ◽  
2016 ◽  
Vol 6 (97) ◽  
pp. 95252-95262 ◽  
Author(s):  
Bolla Govinda Rao ◽  
Putla Sudarsanam ◽  
Baithy Mallesham ◽  
Benjaram M. Reddy
Keyword(s):  
Oxidative Coupling ◽  
Continuous Flow ◽  
Solid Acid ◽  
Catalytic Performance ◽  
Solid Acid Catalysts ◽  
Acid Catalysts ◽  
Highly Efficient

Nanoscale CeO2–MoO3/SiO2 solid acid shows an outstanding catalytic performance in the oxidative coupling of amines under industrially-favourable conditions.

Catalyst- and oxidant-free electrochemical para-selective hydroxylation of N-arylamides in batch and continuous-flow

2020 ◽  
Vol 22 (19) ◽  
pp. 6437-6443
Author(s):  
Cheng-Kou Liu ◽  
Meng-Yi Chen ◽  
Xin-Xin Lin ◽  
Zheng Fang ◽  
Kai Guo
Keyword(s):  
Ammonium Salt ◽  
Quaternary Ammonium ◽  
Continuous Flow ◽  
Quaternary Ammonium Salt ◽  
Selective Hydroxylation

A catalyst-, oxidant-, acidic solvent- and quaternary ammonium salt-free electrochemical para-selective hydroxylation of N-arylamides at rt in batch and continuous-flow was developed.

Development of a Progression-Based Signal-Timing Strategy for Continuous-Flow Intersections

2021 ◽  
Vol 147 (3) ◽  
pp. 04021002
Author(s):  
Wenrui Qu ◽  
Shaojie Liu ◽  
Qun Zhao ◽  
Yi Qi
Keyword(s):  
Continuous Flow ◽  
Signal Timing

Avalanche Stratification - Experimental Tests of the “Metastable Wedge” and “Continuous Flow” Models

2000 ◽  
Vol 627 ◽  
Author(s):  
M. E. Swanson ◽  
M. Landreman ◽  
J. Michel ◽  
J. Kakalios
Keyword(s):  
Continuous Flow ◽  
Granular Media ◽  
Experimental Tests ◽  
Coarse Sand ◽  
Angle Of Repose ◽  
Flow Models ◽  
Maximum Angle ◽  
Stratification Effect ◽  
Upward Moving ◽  
Moving Layer

ABSTRACTWhen an initially homogeneous binary mixture of granular media such as fine and coarse sand is poured near the closed edge of a “quasi-two-dimensional” Hele-Shaw cell consisting of two vertical transparent plates held a narrow distance apart, the mixture spontaneously forms alternating segregated layers. Experimental measurements of this stratification effect are reported in order to determine which model, one which suggests that segregation only occurs when the granular material contained within a metastable heap between the critical and maximum angle of repose avalanches down the free surface, or one for which the segregation results from smaller particles becoming trapped in the top surface and being removed from the moving layer during continuous flow. The result reported here indicate that the Metastable Wedge model provides a natural explanation for the initial mixed zone which precedes the formation of the layers, while the Continuous Flow model explains the observed upward moving kink of segregated material for higher granular flux rates, and that both mechansims are necessary in order to understand the observed pairing of segregated layersfor intermediate flow rates and cell separations.

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