A high-performance rocking-chair lithium-ion battery-supercapacitor hybrid device boosted by doubly matched capacity and kinetics of faradaic electrodes

2021 ◽  
Author(s):  
Feng Su ◽  
Jieqiong Qin ◽  
Pratteek Das ◽  
Feng Zhou ◽  
Zhong-Shuai Wu
Keyword(s):  
High Performance ◽  
Storage Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
Charge Storage ◽  
Electrode Kinetics ◽  
Hybrid Device ◽  
Hybrid Devices ◽  
Power Densities ◽  
Kinetics Of

Battery-supercapacitor hybrid devices (BSHDs) are promising for certain applications requiring both high energy and power densities, but restricted by the electrolyte-consuming mechanism and imbalance of charge-storage capacity and electrode kinetics...

scholarly journals C60/Na4FeO3/Li3V2(PO4)3/soft carbon quaternary hybrid superstructure for high-performance battery-supercapacitor hybrid devices

2020 ◽  
Vol 12 (1) ◽  
Author(s):  
Xudong Zhang ◽  
Xiaolong Xu ◽  
Yuebo Hu ◽  
Guogang Xu ◽  
Wen He ◽  
...  
Keyword(s):  
High Performance ◽  
Rational Design ◽  
Synergistic Effects ◽  
High Energy ◽  
Charge Storage ◽  
Ordered Mesoporous ◽  
Soft Carbon ◽  
Hybrid Devices ◽  
Power Densities ◽  
Cycling Life

AbstractTo develop battery-supercapacitor hybrid devices with high energy and power densities, we propose a rational design of a quaternary hybrid superstructure by using a high-energy biotemplate. This new superstructure is composed of stable fullerene C60 nanocages, electroactive Na4FeO3, high-energy Li3V2(PO4)3 and soft carbon as well as tubular ordered mesoporous channels. This design takes advantage of the unique properties of each component, resulting in nanocomposites with synergistic effects to improve the charge transfer and energy storage. We found that this quaternary hybrid electrode has both high energy and power densities as well as a long cycling life in a Li/Na mixed-ion electrolyte, outperforming a multitude of other battery-supercapacitor hybrid devices reported thus far. The charge storage mechanisms of this hybrid superstructure are proposed for optimizing the electrode design.

A novel calendula-like MnNb2O6 anchored on graphene sheet as high-performance intercalation pseudocapacitive anode for lithium-ion capacitors

2019 ◽  
Vol 7 (6) ◽  
pp. 2855-2863 ◽  
Author(s):  
Xu Zhang ◽  
Jinyu Zhang ◽  
Shuying Kong ◽  
Kai Zhu ◽  
Jun Yan ◽  
...  
Keyword(s):  
Graphene Sheet ◽  
Anode Material ◽  
High Performance ◽  
Storage Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Cycling Stability ◽  
Charge Storage ◽  
First Time ◽  
Superior Cycling Stability

In this paper, for the first time, we investigated MnNb2O6 as a new rate capability type anode material for lithium-ion capacitors (LICs), which exhibit excellent charge storage capacity and reasonably superior cycling stability.

scholarly journals S, O dual-doped porous carbon derived from activation of waste papers as electrodes for high performance lithium ion capacitors

2021 ◽  
Author(s):  
Jian Hao ◽  
Jun Bai ◽  
Xiu Wang ◽  
Yanxia Wang ◽  
Qingjie Guo ◽  
...  
Keyword(s):  
Porous Carbon ◽  
High Performance ◽  
Storage Capacity ◽  
Lithium Ion ◽  
Electrochemical Kinetics ◽  
Charge Storage ◽  
Carbon Based

To circumvent the imbalances of electrochemical kinetics and charge-storage capacity between Li+ ion battery anodes and capacitive cathodes in lithium-ion capacitors (LICs), dual carbon based LICs are constructed and investigated extensively.

scholarly journals Metal-Organic Framework Glass Anode with an Exceptional Cycling-Induced Capacity Enhancement for Lithium Ion Batteries

2021 ◽  
Author(s):  
Chengwei Gao ◽  
Zhenjing Jiang ◽  
Peixing Wang ◽  
Lars Rosgaard Jensen ◽  
Yanfei Zhang ◽  
...  
Keyword(s):  
Pore Structure ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Storage Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
Great Promise ◽  
Electrochemical Performances ◽  
Metal Organic

<p>Metal organic frameworks (MOFs) hold great promise as high-energy anode materials for next-generation lithium ion batteries (LIBs) due to their tuneable pore structure and abundant reaction sites. However, since the pore structure of crystalline MOFs tends to collapse during lithium ion insertion and extraction, it has been a challenge to develop crystalline MOF-based anodes for high performance lithium ion batteries. Here we report a breakthrough in developing the high-performance MOF anodes. In detail, we have developed the first MOF glass anode, i.e., melt-quenched Cobalt-ZIF-62 glass anode with exceptional electrochemical performances. Compared with its crystalline counterpart, the Co-ZIF-62 glass anode exhibits significantly higher lithium storage capacity (306 mAh g<sup>-1</sup> after 1000 cycles at the current density of 2 A g<sup>-1</sup>), outstanding cycling stability and superior rate performance. Amazingly, the Li-ion storage capacity of the MOF glass anode continuously rises with increasing the number of charge-discharge cycles and even <i>tripled</i> after 1000 cycles. We revealed the possible origin of the unusual cycling-enhanced performances of the MOF glass anode. These superior performances make MOF glasses ideal candidates for anode materials for LIBs. </p>

scholarly journals Metal-Organic Framework Glass Anode with an Exceptional Cycling-Induced Capacity Enhancement for Lithium Ion Batteries

2021 ◽  
Author(s):  
Chengwei Gao ◽  
Zhenjing Jiang ◽  
Peixing Wang ◽  
Lars Rosgaard Jensen ◽  
Yanfei Zhang ◽  
...  
Keyword(s):  
Pore Structure ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Storage Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
Great Promise ◽  
Electrochemical Performances ◽  
Metal Organic

<p>Metal organic frameworks (MOFs) hold great promise as high-energy anode materials for next-generation lithium ion batteries (LIBs) due to their tuneable pore structure and abundant reaction sites. However, since the pore structure of crystalline MOFs tends to collapse during lithium ion insertion and extraction, it has been a challenge to develop crystalline MOF-based anodes for high performance lithium ion batteries. Here we report a breakthrough in developing the high-performance MOF anodes. In detail, we have developed the first MOF glass anode, i.e., melt-quenched Cobalt-ZIF-62 glass anode with exceptional electrochemical performances. Compared with its crystalline counterpart, the Co-ZIF-62 glass anode exhibits significantly higher lithium storage capacity (306 mAh g<sup>-1</sup> after 1000 cycles at the current density of 2 A g<sup>-1</sup>), outstanding cycling stability and superior rate performance. Amazingly, the Li-ion storage capacity of the MOF glass anode continuously rises with increasing the number of charge-discharge cycles and even <i>tripled</i> after 1000 cycles. We revealed the possible origin of the unusual cycling-enhanced performances of the MOF glass anode. These superior performances make MOF glasses ideal candidates for anode materials for LIBs. </p>

Shuttle-Like CuO as High-Performance Anode Materials for Lithium Ion Batteries

2017 ◽  
Vol 727 ◽  
pp. 688-692
Author(s):  
Ji Xiang Chen ◽  
Dong Lin Zhao ◽  
Ze Wen Ding ◽  
Cheng Li ◽  
Xia Jun Wang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Specific Capacitance ◽  
High Performance ◽  
Specific Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Specific Capacity ◽  
Power Densities

Shuttle-like CuO has been synthesized by treating commercial Cu(OH)2 powder at room temperature for an appropriate time. As anode material of lithium-ion batteries, shuttle-like CuO exhibits high specific capacity, high stability, and good rate performance, superior to commercial CuO powder. The shuttle-like CuO exhibited a high specific capacitance of 456.8 mAh g-1 at a current density of 100 mAg-1 and maintained a good stability in 50 cycles, suggesting that it can be a promising candidate for lithium-ion batteries. The high specific capacitance and remarkable rate capability are promising for applications in lithium-ion batteries with both high energy and power densities.

Vacancies-engineered MoO3 and Na+-preinserted MnO2 in-situ grown N-doped graphene nanotubes as electrode materials for high-performance asymmetric supercapacitor

2021 ◽  
Author(s):  
Jian Zhao ◽  
He Cheng ◽  
Huanyu Li ◽  
Yan-Jie Wang ◽  
Qingyan Jiang ◽  
...  
Keyword(s):  
High Performance ◽  
Electrode Materials ◽  
High Energy ◽  
Cooperative Effect ◽  
Electrochemical Energy Storage ◽  
Asymmetric Supercapacitor ◽  
Asymmetric Supercapacitors ◽  
Doped Graphene ◽  
Power Densities

Developing advanced negative and positive electrode materials for asymmetric supercapacitors (ASCs) as the electrochemical energy storage can enable the device to reach high energy/power densities resulting from the cooperative effect...

scholarly journals Two-dimensional SnO2 anchored biomass-derived carbon nanosheet anode for high-performance Li-ion capacitors

RSC Advances ◽  
2021 ◽  
Vol 11 (17) ◽  
pp. 10018-10026
Author(s):  
Chang Liu ◽  
Zeyin He ◽  
Jianmin Niu ◽  
Qiang Cheng ◽  
Zongchen Zhao ◽  
...  
Keyword(s):  
High Performance ◽  
Lithium Ion ◽  
High Energy ◽  
Good Combination ◽  
Two Dimensional ◽  
Power Characteristics ◽  
Coffee Grounds ◽  
Lithium Ion Capacitor ◽  
Li Ion

In this work, we have fabricated lithium-ion capacitor using SnO2/PCN as anode and waste coffee grounds derived PCN as cathode, which delivers good combination of high energy and power characteristics.

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