TiN@C nanocages as multifunctional sulfur hosts for superior lithium-sulfur batteries

2021 ◽  
Author(s):  
Ning Zhang ◽  
Shuangshuang Zheng ◽  
Menglong Zhao ◽  
Yang Lu ◽  
Jinbing Cheng ◽  
...  
Keyword(s):  
Performance Improvement ◽  
Shuttle Effect ◽  
Redox Kinetics ◽  
Lithium Sulfur Batteries ◽  
Sulfur Hosts ◽  
Lithium Sulfur

The lithium polysulfides (LiPSs) shuttle effect and low redox kinetics is the key problem that hinders the performance improvement and prevents the achievement of commercial requirement for lithium-sulfur batteries (LSBs),...

Borophene as Efficient Sulfur Hosts for Lithium–Sulfur Batteries: Suppressing Shuttle Effect and Improving Conductivity

2017 ◽  
Vol 121 (29) ◽  
pp. 15549-15555 ◽  
Author(s):  
Lin Zhang ◽  
Pei Liang ◽  
Hai-bo Shu ◽  
Xiao-lei Man ◽  
Feng Li ◽  
...  
Keyword(s):  
Shuttle Effect ◽  
Lithium Sulfur Batteries ◽  
Sulfur Hosts ◽  
Lithium Sulfur

scholarly journals Facile synthesis of sulfur@titanium carbide Mxene as high performance cathode for lithium-sulfur batteries

Nanophotonics ◽  
2020 ◽  
Vol 9 (7) ◽  
pp. 2025-2032
Author(s):  
Fan Zhang ◽  
Yunlei Zhou ◽  
Yi Zhang ◽  
Dongchan Li ◽  
Zhichao Huang
Keyword(s):  
Titanium Carbide ◽  
High Performance ◽  
High Capacity ◽  
Shuttle Effect ◽  
Lithium Polysulfide ◽  
Lithium Sulfur Batteries ◽  
Potential Applications ◽  
Sulfur Hosts ◽  
Lithium Sulfur ◽  
Sulfur Nanoparticles

AbstractThe design of sulfur hosts with polar, sulfurphilic, and conductive network is critical to lithium-sulfur (Li-S) batteries whose potential applications are greatly limited by the lithium polysulfide shuttle effect. Mxenes, possessing layered-stacked structures and high electrical conductivities, have a great potential in sulfur hosts. Herein, sulfur nanoparticles uniformly decorated on titanium carbide Mxene (S@Ti3C2Tx Mxene) are synthesized via a hydrothermal method and then utilized as a cathode for lithium-sulfur batteries. This unique architecture could accommodate sulfur nanoparticles expansion during cycling, suppress the shuttling of lithium polysulfide, and enhance electronical conductivity. Consequently, the S@Mxene with a high areal sulfur loading (∼4.0 mg cm−2) exhibits a high capacity (1477.2 mAh g−1) and a low capacity loss per cycle of 0.18% after 100 cycles at 0.2 C. This work may shed lights on the development of high performance sulfur-based cathode materials for Li-S batteries.

Metallic C5N Monolayers as Efficient Catalysts for Accelerating Redox Kinetics of Sulfur in Lithium-Sulfur Batteries

2021 ◽  
Author(s):  
Zhihao Wang ◽  
zhihao zeng ◽  
Wei Nong ◽  
Zhen Yang ◽  
Chenze Qi ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Storage Devices ◽  
Shuttle Effect ◽  
Storage Devices ◽  
Redox Kinetics ◽  
Lithium Sulfur Batteries ◽  
Commercial Applications ◽  
Sulfur Battery ◽  
Kinetics Of ◽  
Lithium Sulfur

Lithium sulfur battery is one of the most promising applicants for the next generation of energy storage devices whose commercial applications are impeded by the key issue of shuttle effect....

scholarly journals Rational design of zwitterionic porous organic framework loading Co (II) ions to host sulfur and synergistically boost polysulfides redox kinetics for lithium sulfur batteries

2022 ◽  
Author(s):  
Miao Sun ◽  
Gaojie Yan ◽  
Haifeng Ji ◽  
Yi Feng ◽  
Xiaojie Zhang ◽  
...  
Keyword(s):  
Rational Design ◽  
Volume Changes ◽  
Shuttle Effect ◽  
Redox Kinetics ◽  
Lithium Sulfur Batteries ◽  
Kinetics Of ◽  
Porous Organic Framework ◽  
Lithium Sulfur ◽  
Organic Framework

In the development of lithium-sulfur batteries (LiSBs), the irreversible volume changes, annoying shuttle effect and slow conversion kinetics of lithium polysulfides (LiPSs) are main obstacles for further commercialization. Therefore, a...

Three-in-one cathode host based on Nb3O8/graphene superlattice heterostructures for high-performance Li–S batteries

2021 ◽  
Author(s):  
Chenhui WANG ◽  
Nobuyuki Sakai ◽  
Yasuo Ebina ◽  
Takayuki KIKUCHI ◽  
Monika Snowdon ◽  
...  
Keyword(s):  
Energy Storage ◽  
High Performance ◽  
Next Generation ◽  
Shuttle Effect ◽  
Lithium Sulfur Batteries ◽  
Graphene Superlattice ◽  
Lithium Sulfur

Lithium-sulfur batteries have high promise for application in next-generation energy storage. However, further advances have been hindered by various intractable challenges, particularly three notorious problems: the “shuttle effect”, sluggish kinetics...

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