Design and synthesis of three new copper coordination polymers: efficient degradation of an organic dye at alkaline pH

2021 ◽  
Vol 50 (39) ◽  
pp. 13866-13876
Author(s):  
Xiaxia Liu ◽  
Liping Lu ◽  
Miaoli Zhu ◽  
Ulli Englert
Keyword(s):  
Methylene Blue ◽  
Coordination Polymers ◽  
Organic Dye ◽  
Alkaline Ph ◽  
Design And Synthesis ◽  
Copper Coordination

New Cu(ii) coordination polymers can efficiently degrade methylene blue in the presence of light and H2O2 at alkaline pH.

scholarly journals A series of five-coordinated copper coordination polymers for efficient degradation of organic dyes under visible light irradiation

RSC Advances ◽  
2017 ◽  
Vol 7 (38) ◽  
pp. 23432-23443 ◽  
Author(s):  
Lu-Lu Shi ◽  
Tian-Rui Zheng ◽  
Min Li ◽  
Lin-Lu Qian ◽  
Bao-Long Li ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Methyl Orange ◽  
Visible Light ◽  
Coordination Polymers ◽  
Visible Light Irradiation ◽  
Rhodamine B ◽  
Organic Dyes ◽  
Light Irradiation ◽  
Highly Efficient ◽  
Copper Coordination

Five-coordinated copper(ii) coordination polymers 1–5 are highly efficient and universal photocatalysts for the degradation of the organic dyes methylene blue (MB), rhodamine B (RhB) and methyl orange (MO) under visible light irradiation.

Pattern Formation in the Methylene Blue-Fructose-Oxygen System in Aqueous Solution and in Gel Systems

2000 ◽  
Vol 65 (9) ◽  
pp. 1394-1402 ◽  
Author(s):  
Ľubica Adamčíková ◽  
Mária Hupková ◽  
Peter Ševčík
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Pattern Formation ◽  
Alkaline Ph ◽  
Initial Reactant ◽  
Nonlinear Reaction ◽  
Oxygen System ◽  
Hydrodynamic Processes ◽  
Liquid Layer Thickness ◽  
Catalyzed Oxidation

Spatial patterns in methylene blue-catalyzed oxidation of fructose at alkaline pH were found in aqueous solution and in gel systems. In a thin liquid layer (thickness >2.4 mm) a mixture of spots and stripes was formed by interaction of a nonlinear reaction and the Rayleigh or Maragoni instabilities. The pattern formation was affected by initial reactant concentrations and by the thickness of the reaction mixture layer. Long-lasting structures were formed in gel systems (polyacrylamide, agar, gelatin). These patterns also arise primarily from hydrodynamic processes.

Wavelength-Regulated Stereodivergent Synthesis of (Z)- and (E)-1,4-Enediones from Phosphonium Ylides

2021 ◽  
Author(s):  
Mei Wang ◽  
Yongqin He ◽  
Yao Zhu ◽  
Zhi-Bin Song ◽  
Xiao-Yu Wang ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Functional Groups ◽  
Organic Dye

A wavelength-regulated, organic dye methylene blue catalyzed stereodivergent synthesis of (Z)- and (E)-1,4-enediones from stabilized phosphorous ylides is reported. A broad range of substrates and functional groups are tolerated. Mechanistic...

scholarly journals Design and synthesis of coordination polymers with chelated units and their application in nanomaterials science

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42242-42288 ◽  
Author(s):  
Gulzhian I. Dzhardimalieva ◽  
Igor E. Uflyand
Keyword(s):  
Coordination Polymers ◽  
Design And Synthesis

The advances and problems associated with the preparation, properties and structure of coordination polymers with chelated units are presented and assessed.

Syntheses, structures and characterization of isomorphous CoII and NiII coordination polymers based on 2-[(1H-imidazol-1-yl)methyl]-6-methyl-1H-benzimidazole and benzene-1,4-dicarboxylate

2017 ◽  
Vol 73 (8) ◽  
pp. 645-651 ◽  
Author(s):  
Qiu-Ying Huang ◽  
Yang Zhao ◽  
Xiang-Ru Meng
Keyword(s):  
Coordination Polymers ◽  
Rational Design ◽  
Three Dimensional ◽  
Spectroscopic Properties ◽  
Polymeric Chain ◽  
Design And Synthesis ◽  
Carboxylate Groups ◽  
Metal Organic ◽  
The One ◽  
Ir Spectroscopic

Careful choice of the organic ligands is one of the most important parameters in the rational design and synthesis of coordination polymers. Aromatic polycarboxylates have been widely used in the preparation of metal–organic polymers since they can utilize various coordination modes to form diverse structures and can act as hydrogen-bond acceptors and donors in the assembly of supramolecular structures. Nitrogen-heterocyclic organic compounds have also been used extensively as ligands for the construction of polymers with interesting structures. In the polymers catena-poly[[[diaquabis{2-[(1H-imidazol-1-yl)methyl]-6-methyl-1H-benzimidazole-κN 3}cobalt(II)]-μ2-benzene-1,4-dicarboxylato-κ2 O 1:O 4] dihydrate], {[Co(C8H4O4)(C12H11N4)2(H2O)2]·2H2O} n , (I), and catena-poly[[[diaquabis{2-[(1H-imidazol-1-yl)methyl]-6-methyl-1H-benzimidazole-κN 3}nickel(II)]-μ2-benzene-1,4-dicarboxylato-κ2 O 1:O 4] dihydrate], {[Ni(C8H4O4)(C12H11N4)2(H2O)2]·2H2O} n , (II), the CoII or NiII ion lies on an inversion centre and exhibits a slightly distorted octahedral coordination geometry, coordinated by two N atoms from two imidazole rings and four O atoms from two monodentate carboxylate groups and two water molecules. The dicarboxylate ligands bridge metal ions forming a polymeric chain. The 2-[(1H-imidazol-1-yl)methyl]-6-methyl-1H-benzimidazole ligands coordinate to the CoII or NiII centres in monodentate modes through an imidazole N atom and are pendant on opposite sides of the main chain. The two structures are isomorphous. In the crystal, the one-dimensional chains are further connected through O—H...O, O—H...N and N—H...O hydrogen bonds, leading to a three-dimensional supramolecular architecture. In addition, the IR spectroscopic properties, PXRD patterns, thermogravimetric behaviours and fluorescence properties of both polymers have been investigated.

Two pure MOF-photocatalysts readily prepared for the degradation of methylene blue dye under visible light

2018 ◽  
Vol 47 (12) ◽  
pp. 4251-4258 ◽  
Author(s):  
Ming Zhang ◽  
Liwen Wang ◽  
Tianyu Zeng ◽  
Qigao Shang ◽  
Hong Zhou ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Visible Light ◽  
Coordination Polymers ◽  
Dye Degradation ◽  
Blue Dye ◽  
Methylene Blue Dye

Two 3D coordination polymers, bridged by 4,4′-bipyridine, were readily synthesized and fully characterized. As efficient photocatalysts in dye degradation under visible light, the mechanism and stability were studied.

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