Family of Lanthanide Metal-Organic Frameworks Based on Redox-Active Tetrathiafulvalene-Dicarboxylic Ligand Showing Slow Relaxation of Magnetisation and Electronic Conductivity

2021 ◽  
Author(s):  
Jun-Jie Hu ◽  
Yu-Guang Li ◽  
He-Rui Wen ◽  
Sui-Jun Liu ◽  
Yan Peng ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Electronic Conductivity ◽  
Metal Organic Frameworks ◽  
Lanthanide Ions ◽  
Framework Materials ◽  
Redox Active ◽  
Important Approach ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Electro Magnetic

The reaction of redox-active tetrathiafulvalene ligand and lanthanide ions is an important approach to prepare photo-electro-magnetic multifunctional metal-organic framework materials. A series of isostructural lanthanide metal-organic frameworks (Ln-MOFs) based on...

Metal–organic frameworks for radionuclide sequestration from aqueous solution: a brief overview and outlook

2017 ◽  
Vol 46 (47) ◽  
pp. 16381-16386 ◽  
Author(s):  
Chengliang Xiao ◽  
Mark A. Silver ◽  
Shuao Wang
Keyword(s):  
Aqueous Solution ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

137Cs, 90Sr, 238U, 79Se, and 99Tc sequestrations from aqueous solution by metal–organic framework materials are summarized in this Frontier article.

Lanthanide metal–organic frameworks based on the 4,4′-oxybisbenzoic acid ligand: synthesis, structures and physical properties

2015 ◽  
Vol 39 (12) ◽  
pp. 9872-9878 ◽  
Author(s):  
Yun Li ◽  
Ning Wang ◽  
Yan-Ju Xiong ◽  
Qian Cheng ◽  
Jie-Fang Fang ◽  
...  
Keyword(s):  
Physical Properties ◽  
Solvothermal Synthesis ◽  
Metal Organic Frameworks ◽  
Lanthanide Ions ◽  
Acid Ligand ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Ligand Synthesis

Using solvothermal synthesis, eight new 3D microporous lanthanide-ions-based MOFs constructed from 4,4′-oxybisbenzoic acid were obtained and displayed two types of architecture.

Selective adsorption behaviour of carbon dioxide in OH-functionalized metal–organic framework materials

CrystEngComm ◽  
2017 ◽  
Vol 19 (36) ◽  
pp. 5346-5350 ◽  
Author(s):  
Jinjie Qian ◽  
Jinni Shen ◽  
Qipeng Li ◽  
Yue Hu ◽  
Shaoming Huang
Keyword(s):  
Carbon Dioxide ◽  
Hydrogen Bond ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Adsorption Behaviour ◽  
Weak Hydrogen Bond ◽  
Oh Groups ◽  
Framework Materials ◽  
Metal Organic

The theoretically optimal adsorption locations in hydroxyl (OH)-decorated metal–organic frameworks show that the captured CO2 molecules interact with the cis-μ2-OH groups in an end-on mode, which shows a moderate to weak hydrogen bond.

Novel metal–organic framework materials: blends, liquids, glasses and crystal–glass composites

2019 ◽  
Vol 55 (60) ◽  
pp. 8705-8715 ◽  
Author(s):  
Joshua M. Tuffnell ◽  
Christopher W. Ashling ◽  
Jingwei Hou ◽  
Shichun Li ◽  
Louis Longley ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Crystal Glass ◽  
Zeolitic Imidazolate Framework ◽  
Feature Article ◽  
Glass Composites ◽  
Framework Materials ◽  
Recent Advances ◽  
Metal Organic ◽  
Organic Framework

This Feature Article reviews a range of amorphisation mechanisms of Metal–Organic Frameworks (MOFs) and presents recent advances to produce novel MOF materials including porous MOF glasses, MOF crystal–glass composites, flux melted MOF glasses and blended zeolitic imidazolate framework glasses.

Metal–organic frameworks utilising an interlocked, hexadentate linker containing a tetra-carboxylate axle and a bis(pyridine) wheel

2017 ◽  
Vol 46 (8) ◽  
pp. 2462-2470 ◽  
Author(s):  
Ghazale Gholami ◽  
Giorgio Baggi ◽  
Kelong Zhu ◽  
Stephen J. Loeb
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

A mechanically interlocked ligand which combines an H-shaped axle containing four terminal 3-carboxyphenyl groups and a macrocyclic wheel with two 4-pyridyl groups was used to create Zn(ii) and Cu(ii) metal–organic framework materials that contain unique frameworks threaded solely due to the interpenetrated nature of the linker.

Luminescent lanthanide metal–organic frameworks for chemical sensing and toxic anion detection

2017 ◽  
Vol 46 (30) ◽  
pp. 9859-9867 ◽  
Author(s):  
Rui-Zhi Wu ◽  
Xing Yang ◽  
Liang-Wei Zhang ◽  
Pan-Pan Zhou
Keyword(s):  
Chemical Sensing ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Anion Detection ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Toxic Anion ◽  
Co Doped ◽  
Organic Framework

A co-doped lanthanide metal–organic framework (LnMOF) consisting of anion affinity sites exhibits self-calibrating, high distinguishable and stable photoluminescent signals for detecting toxic anions.

Excellent photoreduction performance of Cr(vi) over (WO4)2−-doped metal organic framework materials

2020 ◽  
Vol 44 (47) ◽  
pp. 20704-20714
Author(s):  
Xinyun Zhao ◽  
Lamei Wu ◽  
Xi Chen ◽  
Juncheng Hu ◽  
Tsung-hsueh Wu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Organic Framework

Negatively charged (WO4)2− anions doped into 2D layered metal organic frameworks bismuth terephthalate provides a valuable strategy for excellent photoreduction of Cr(vi).

Rational synthesis of isomorphic rare earth metal-organic framework materials for simultaneous adsorption and photocatalytic degradation of organic dyes in water

CrystEngComm ◽  
2021 ◽  
Author(s):  
Meng-Ting Hang ◽  
Yi Cheng ◽  
Yi-Tong Wang ◽  
Huan Li ◽  
Meng-Qi Zheng ◽  
...  
Keyword(s):  
Active Sites ◽  
Organic Dyes ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Dye Wastewater ◽  
Porous Structures ◽  
Framework Materials ◽  
Metal Organic ◽  
Ordered Porous

In recent years, the treatment of dye wastewater has attracted widespread attention. Metal-organic frameworks (MOFs) adopt ordered porous structures and abundant active sites, which endorses them promising photocatalysts for the...

Water interactions in metal organic frameworks

CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 247-260 ◽  
Author(s):  
Kui Tan ◽  
Nour Nijem ◽  
Yuzhi Gao ◽  
Sebastian Zuluaga ◽  
Jing Li ◽  
...  
Keyword(s):  
Structural Variation ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Framework Materials ◽  
Metal Organic ◽  
Insight Into ◽  
Organic Framework

Insight into the structural variation of metal organic framework materials upon hydration.

A lanthanide metal–organic framework (MOF-76) for adsorbing dyes and fluorescence detecting aromatic pollutants

RSC Advances ◽  
2016 ◽  
Vol 6 (14) ◽  
pp. 11570-11576 ◽  
Author(s):  
Xiao Lian ◽  
Bing Yan
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Dye Adsorption ◽  
Fluorescence Sensing ◽  
Aromatic Pollutants ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Monoaromatic Hydrocarbons ◽  
Organic Framework

A series of nano-sized luminescent lanthanide metal–organic frameworks (Ln-MOFs) are developed for application in dye adsorption and fluorescence sensing for monoaromatic hydrocarbons (BTEX).

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