B-H and O-H bonds activation via a single electron transfer of frustrated radical pairs

2021 ◽  
Author(s):  
Yanlin Pan ◽  
Jie Cui ◽  
Yongliang Wei ◽  
Zhaochao Xu ◽  
Tongdao Wang
Keyword(s):  
Electron Transfer ◽  
Bond Activation ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Radical Pairs ◽  
Tempo Radical

The rare examples of B-H bond activation in frustrated radical pairs regime have been observed by treatment of TEMPO radical with Piers’ borane HB(C6F5)2 or bis-borane, respectively. The resulting concomitant...

Reversal of Polarity by Catalytic SET Oxidation: Synthesis of Azabicyclo[m.n.o]alkanes via Chemoselective Reduction of Amidines

2021 ◽  
Author(s):  
Sundarababu Baskaran ◽  
Kirana D V ◽  
Kanak Kanti Das
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Catalytic Method ◽  
One Pot ◽  
Oxidative System ◽  
Oxidation Synthesis

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this...

Evidence for single electron transfer in the reaction of alkoxides with alkyl halides

1984 ◽  
Vol 25 (45) ◽  
pp. 5107-5110 ◽  
Author(s):  
E.C. Ashby ◽  
Dong-Hak Bae ◽  
Won-Suh Park ◽  
Robert N. Depriest ◽  
Wei-Yang Su
Keyword(s):  
Electron Transfer ◽  
Alkyl Halides ◽  
Single Electron ◽  
Single Electron Transfer
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