Complex crystal structure and photoluminescence of Bi3+-doped and Bi3+/Eu3+ co-doped Ca7Mg2Ga6O18

2021 ◽  
Author(s):  
Ju Li ◽  
Jinmei Huang ◽  
Pengfei Jiang ◽  
Wenliang Gao ◽  
Rihong Cong ◽  
...  

Recently, broad-band white-light-emitting using Eu2+, Ce3+, or Bi3+ in multi-sites of a single-phase phosphor have drawn extensive attention due to their potential to realize high-quality indoor lighting. This work reports...

RSC Advances ◽  
2016 ◽  
Vol 6 (29) ◽  
pp. 24577-24583 ◽  
Author(s):  
Haikun Liu ◽  
Libing Liao ◽  
Maxim S. Molokeev ◽  
Qingfeng Guo ◽  
Yuanyuan Zhang ◽  
...  

A novel single-phase white light emitting phosphor Ca9La(PO4)5(SiO4)F2:Dy3+ was prepared through traditional high-temperature solid state technology.


2019 ◽  
Vol 7 (27) ◽  
pp. 8374-8382 ◽  
Author(s):  
Jing Yan ◽  
Ziwang Zhang ◽  
Dawei Wen ◽  
Jianbang Zhou ◽  
Yiqin Xu ◽  
...  

A single phase color-tunable white light emitting Ca8ZnLu(PO4)7:Eu2+,Mn2+ phosphor with high color rendering index has been rationally designed via combination of cyan and red emissions.


2021 ◽  
Vol 11 (1) ◽  
pp. 54-62
Author(s):  
Jinpeng Xie ◽  
Bonan Liu ◽  
Qingtao Qong ◽  
Zhicheng Xu ◽  
Zhiqiang Jin ◽  
...  

In this work, we report Eu3+/Tb3+/Eu2+ co-activated Gd2O2 S as novel phosphor materials that can be effectively applied in the white-light emitting diode based on a near-UV chip with sensational performances. The luminescent properties and energy transfer mechanism have been thoroughly investigated. The as-prepared europium/terbium co-doped Gd2O2 S phosphors exhibit strong fluorescence with tunable color output under UV-vis light excitation. Furthermore, a high response to ultraviolet illumination of 398 nm wavelength was observed in the excitation spectra, indicating an excellent match with a light-emitting-diode chip in the dominant emissions. It is found that a tricolor (blue, green and red) emission band which results in a white light emission can be acquired when Eu3+, Eu2+ and Tb3+ ions are all co-doped into the single phase Gd2O2S, and an optimum ion doping level (10 at.% Eu and 0.7 at.% Tb) can effectively emit nearly pure white color photoluminescence with lifetime effectively tuned from 0.55 ms to 1.10 ms. The CIE (Commission International de I'Eclairage 1931 chromaticity) is X = 0.3507, Y = 0.3029. It is therefore expected that the newly found phosphor material with high-performance properties possess great potentials for the future advanced white LED applications.


2020 ◽  
Vol 817 ◽  
pp. 152687 ◽  
Author(s):  
Sayed Ali Khan ◽  
Abdul Jalil ◽  
Qudrat Ullah Khan ◽  
Rana Muhammad Irfan ◽  
Ikhtisham Mehmood ◽  
...  

2015 ◽  
Vol 618 ◽  
pp. 484-487 ◽  
Author(s):  
Feng Zhang ◽  
Ting Zhang ◽  
Guoqiang Li ◽  
Weifeng Zhang

2015 ◽  
Vol 08 (06) ◽  
pp. 1550077 ◽  
Author(s):  
Jianghui Zheng ◽  
Qijin Cheng ◽  
Cheng Zheng ◽  
Guo Chen ◽  
Feng Shi ◽  
...  

NaBa 0.97-x BO 3 0.03 Dy 3+, x Eu 3+(0 ≤ x ≤ 0.09) single-phase white phosphors with tunable correlated color temperature (CCT) were synthesized using a conventional solid state reaction method. The phase structure and luminescence properties of the as-prepared samples were investigated. The Dy 3+, Eu 3+ doped and Dy 3+/ Eu 3+ co-doped NaBaBO 3 phosphors excited by 361 nm show two blue and yellow emissions corresponding to the 4 F 9/2 → 6 H 15/2 and 4 F 9/2 → 6 H 13/2 transitions of Dy 3+ ions and two red emissions due to the 5 D 0 → 4 F J (J = 1, 2) transitions of Eu 3+ ions. Under 361-nm light excitation, the NaBa 0.97-x BO 3 0.03 Dy 3+, x Eu 3+(0 ≤ x ≤ 0.09) phosphors feature a white light emitting property. Through the Commission Internationale de L'Eclairage (CIE) chromaticity analysis and CCT calculation, the CIE chromaticity coordinates of the emission light are all located in the white region and can be tuned from bluish white light to reddish white light when the Eu 3+ concentration increases, and the CCT values of the obtained samples can vary from 5514.31 K to 8269.42 K. Furthermore, the energy transfer phenomenon from Dy 3+ ions to Eu 3+ ions in Dy 3+/ Eu 3+ co-doped samples was also investigated. The results indicated that, through tuning the Eu 3+ concentration of the NaBaBO 3: Dy 3+/ Eu 3+ phosphors, the NaBaBO 3-based phosphor can act as a potential single-phase white emitting phosphor for the application in the near-ultraviolet (NUV) white light emitting diodes.


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