Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes

2021 ◽  
Author(s):  
Aleksandra V. Paderina ◽  
Igor O Koshevoy ◽  
Elena V. Grachova
Keyword(s):  
Optical Properties ◽  
Metal Complexes ◽  
Crucial Role ◽  
Phosphine Ligands ◽  
Bridging Ligands ◽  
Coinage Metal ◽  
Metal Interactions ◽  
Metal Metal ◽  
State 1

The copper subgroup metal ions in the oxidation state +1 are classical candidates for the aggregation via non-covalent metal–metal interactions, which are supported by a number of the bridging ligands....

Theoretical Evidence for Transannular Metal−Metal Interactions in Dinuclear Coinage Metal Complexes†

1998 ◽  
Vol 37 (23) ◽  
pp. 6002-6006 ◽  
Author(s):  
Eduardo J. Fernández ◽  
José M. López-de-Luzuriaga ◽  
Miguel Monge ◽  
Miguel A. Rodríguez ◽  
Olga Crespo ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Coinage Metal ◽  
Metal Interactions ◽  
Metal Metal ◽  
Theoretical Evidence

scholarly journals Heterobimetallic lanthanide‐coinage metal compounds featuring possible metal‐metal interactions in the exited state

2021 ◽  
Author(s):  
Peter Werner Roesky ◽  
Milena Dahlen ◽  
Niklas Reinfandt ◽  
Chengyu Jin ◽  
Michael T. Gamer ◽  
...  
Keyword(s):  
Metal Compounds ◽  
Coinage Metal ◽  
Metal Interactions ◽  
Metal Metal

Formation of Ag2, Au2 and AgAu particles on MgO(100): DFT study on the role of support-induced charge transfer in metal–metal interactions

2009 ◽  
Vol 255 (16) ◽  
pp. 7380-7384 ◽  
Author(s):  
Silvia A. Fuente ◽  
Patricia G. Belelli ◽  
María M. Branda ◽  
Ricardo M. Ferullo ◽  
Norberto J. Castellani
Keyword(s):  
Charge Transfer ◽  
Dft Study ◽  
Metal Interactions ◽  
Metal Metal ◽  
Induced Charge

Syntheses and Structures of d10 Coinage Metal Complexes of Electron-Accepting Phosphine Ligands Featuring a 3,3,4,4,5,5-Hexafluorocyclopentene Framework

2018 ◽  
Vol 57 (15) ◽  
pp. 9105-9114 ◽  
Author(s):  
Tomohiro Agou ◽  
Nao Wada ◽  
Kiyoshi Fujisawa ◽  
Takaaki Hosoya ◽  
Yoshiyuki Mizuhata ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Phosphine Ligands ◽  
Coinage Metal

Mono- and binuclear molybdenum and tungsten complexes containing asymmetric bridging ligands: effects of ligand conjugation and conformation on metal-metal interactions

1993 ◽  
Vol 32 (10) ◽  
pp. 2145-2155 ◽  
Author(s):  
Amitava Das ◽  
John C. Jeffery ◽  
John P. Maher ◽  
Jon A. McCleverty ◽  
Erik Schatz ◽  
...  
Keyword(s):  
Bridging Ligands ◽  
Metal Interactions ◽  
Tungsten Complexes ◽  
Metal Metal ◽  
And Tungsten

Optical role of the thin metal layer in a TiOx/Ag/TiOx transparent and conductive electrode for organic solar cells

RSC Advances ◽  
2016 ◽  
Vol 6 (109) ◽  
pp. 108034-108044 ◽  
Author(s):  
Adrien Bou ◽  
Malika Chalh ◽  
Sylvain Vedraine ◽  
Bruno Lucas ◽  
Damien Barakel ◽  
...  
Keyword(s):  
Optical Properties ◽  
Solar Cells ◽  
Organic Solar Cells ◽  
Crucial Role ◽  
Silver Oxide ◽  
Metal Layer ◽  
Thin Metal ◽  
Thin Metal Layer

Quantification of the crucial role of the thin metal layer on the prediction of the optical properties of oxide/silver/oxide is established.

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