Bioinspired spiky-like double yolk-shell structured TiO2@ZnIn2S4 for efficient photocatalytic CO2 reduction

2022 ◽  
Author(s):  
Ping She ◽  
Buyuan Guan ◽  
Jiyao Sheng ◽  
Yuanyuan Qi ◽  
Guanyu Qiao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Co2 Reduction ◽  
Value Added ◽  
Pcr Efficiency ◽  
Carbon Dioxide Co2 ◽  
Chemical Feedstock

Photocatalytic carbon dioxide (CO2) reduction (PCR) into syngas is one of the sustainable approaches for recycling CO2 into value-added chemical feedstock. However, the PCR efficiency is often limited by the...

Hierarchical three-dimensional copper selenide nanocubes microelectrodes for improved carbon dioxide reduction reaction

2021 ◽  
Author(s):  
Rajasekaran Elakkiya ◽  
Govindhan Maduraiveeran
Keyword(s):  
Carbon Dioxide ◽  
High Performance ◽  
Three Dimensional ◽  
Co2 Reduction ◽  
Value Added ◽  
Carbon Dioxide Reduction ◽  
Reduction Reaction ◽  
Earth Abundant ◽  
Carbon Dioxide Co2 ◽  
Co2 Reduction Reaction

Design of high-performance and Earth-abundant electrocatalysts for electrochemical carbon dioxide (CO2) reduction reaction (CO2RR) into fuels and value-added chemicals offers an emergent pathway for environment and energy sustainable concerns. Herein,...

Low Full‐Cell Voltage Driven High‐Current‐Density Selective Paired Formate Electrosynthesis

2021 ◽  
Author(s):  
Chuqian Xiao ◽  
Ling Cheng ◽  
Yating Wang ◽  
Jinze Liu ◽  
Rongzhen Chen ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
High Current Density ◽  
Co2 Reduction ◽  
Value Added ◽  
Cell Voltage ◽  
High Current ◽  
Oxidation Of Methanol ◽  
Promising Strategy ◽  
Electro Oxidation ◽  
Carbon Dioxide Co2

Anodic selective electro‐oxidation of methanol paring with cathodic carbon dioxide (CO2) reduction is regarded as a promising strategy to generate value added formate product. We firstly design a 3D‐assembled NiCo...

scholarly journals Generation of Fuel and Value-Added Chemicals from Carbon Dioxide (CO2)

2020 ◽  
Vol 12 (01) ◽  
pp. 41-44
Author(s):  
Pooja Srivastava
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal ◽  
Co2 Reduction ◽  
Value Added ◽  
Reduction Reaction ◽  
Long Term Effects ◽  
Industrial Chemicals ◽  
Continuous Increase ◽  
Carbon Dioxide Co2 ◽  
Co2 Reduction Reaction

Despite its life-threatening long term effects, the continuous increase of carbon dioxide (CO2) in the environment requires immediate actions to control the accelerating climate change. An appealing solution to this problem is to utilize CO2 as feedstock to generate useful chemicals, e.g., fuel, hydrocarbons, and valuable chemicals. The chemical inertness of CO2 needs considerably large energy for its conversion into useful chemicals. Therefore, CO2 reduction reaction requires an effective catalyst for its conversion into fuel (methanol, methane) and industrial chemicals (syngas, formic acid). Recently, two-dimensional layers of early transition metal carbides and nitrides, called MXene, have shown potential for catalysis due to its exposed transition metal sites, and mechanical and chemical stability at high temperatures. Herein, the author presents the MXene as a potential heterogeneous catalyst for the CO2 reduction reaction (CRR), and the future scope in this currently developing field.

scholarly journals Biochar-Supported BiOx for Effective Electrosynthesis of Formic Acid from Carbon Dioxide Reduction

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 363
Author(s):  
Juqin Zeng ◽  
Pravin Jagdale ◽  
Mirtha A. O. Lourenço ◽  
M. Amin Farkhondehfal ◽  
Daniele Sassone ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Techniques ◽  
Co2 Reduction ◽  
Value Added ◽  
Potential Range ◽  
Hydrogen Electrode ◽  
Faradaic Efficiency ◽  
Global Issues ◽  
Application Potential ◽  
Carbon Dioxide Co2

The electrochemical reduction of carbon dioxide (CO2) to value-added chemicals and fuels has attracted worldwide interest for its potential to address various contemporary global issues such as CO2-related climate change, the earth’s carbon deficit and the energy crisis. In the development of this technology, many efforts have been focused on the design of inexpensive, eco-friendly and effective catalysts. In this work, a bismuth (Bi)-based material was simply synthesized via a scalable method and fully characterized by physical, chemical and electrochemical techniques. The catalyst material consisted of Bi/Bi2O3 nanoparticles and a biochar prevenient from the pyrolysis of brewed coffee waste. It was observed that the surface of the biochar was thoroughly decorated with nanoparticles. Due to its uniform surface, the biochar–BiOx electrode demonstrated good selectivity for CO2 reduction, showing a faradaic efficiency of more than 90% for CO and HCOOH formation in a wide potential range. Particularly, the selectivity for HCOOH reached more than 80% from −0.9 V to −1.3 V vs the reversible hydrogen electrode and peaks at 87%. Besides the selectivity, the production rate of HCOOH also achieved significant values with a maximum of 59.6 mg cm−2 h−1, implying a good application potential for biochar–BiOx material in the conversion of CO2 to HCOOH.

Atomic-level engineering of two-dimensional electrocatalysts for CO2 Reduction

Nanoscale ◽  
2021 ◽  
Author(s):  
Wei Shao ◽  
Xiaodong Zhang
Keyword(s):  
Carbon Dioxide ◽  
Fossil Fuels ◽  
Co2 Reduction ◽  
Value Added ◽  
Atomic Level ◽  
Two Dimensional ◽  
Excessive Consumption

Carbon dioxide (CO2) from the excessive consumption of fossil fuels has exhibited a huge threat to the planet’s ecosystem. Electrocatalytic CO2 reduction into value-added chemicals have been regarded as a...

An overview of flow cell architectures design and optimization for electrochemical CO2 reduction

2021 ◽  
Author(s):  
Dui Ma ◽  
Ting Jin ◽  
Keyu Xie ◽  
Haitao Huang
Keyword(s):  
Carbon Dioxide ◽  
Global Warming ◽  
Electrochemical Reduction ◽  
Atmospheric Carbon Dioxide ◽  
Co2 Reduction ◽  
Value Added ◽  
Flow Cell ◽  
Design And Optimization ◽  
Electrochemical Co2 Reduction ◽  
Carbon Dioxide Levels

Converting CO2 into value-added fuels or chemical feedstocks through electrochemical reduction is one of the several promising avenues to reduce atmospheric carbon dioxide levels and alleviate global warming. This approach...

Carbon Dioxide (CO2) as Chemical Feedstock for Polymers – Technologies, Polymers, Developers and Producers

2021 ◽  
Author(s):  
Pauline Ruiz ◽  
Achim Raschka ◽  
Pia Skoczinski ◽  
Jan Ravenstijn ◽  
Michael Carus
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Co2 ◽  
Chemical Feedstock

scholarly journals Positional effects of second-sphere amide pendants on electrochemical CO2 reduction catalyzed by iron porphyrins

2018 ◽  
Vol 9 (11) ◽  
pp. 2952-2960 ◽  
Author(s):  
Eva M. Nichols ◽  
Jeffrey S. Derrick ◽  
Sepand K. Nistanaki ◽  
Peter T. Smith ◽  
Christopher J. Chang
Keyword(s):  
Carbon Dioxide ◽  
Greenhouse Gas ◽  
Electrochemical Reduction ◽  
Energy Input ◽  
Sustainable Energy ◽  
Co2 Reduction ◽  
Value Added ◽  
Iron Porphyrins ◽  
Electrochemical Co2 Reduction ◽  
Positional Effects

The development of catalysts for electrochemical reduction of carbon dioxide offers an attractive approach to transforming this greenhouse gas into value-added carbon products with sustainable energy input.

scholarly journals Electrocatalytic Processes for the Valorization of CO2: Synthesis of Cyanobenzoic Acid Using Eco-Friendly Strategies

Catalysts ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 413 ◽  
Author(s):  
Silvia Mena ◽  
Iluminada Gallardo ◽  
Gonzalo Guirado
Keyword(s):  
Carbon Dioxide ◽  
Global Warming ◽  
Electrochemical Techniques ◽  
Value Added ◽  
Green Technology ◽  
Green Solvents ◽  
Silver Cathodes ◽  
Carbon Dioxide Co2 ◽  
Environmentally Friendly Process ◽  
Value Added Products

Carbon dioxide (CO2) is a known greenhouse gas, and is the most important contributor to global warming. Therefore, one of the main challenges is to either eliminate or reuse it through the synthesis of value-added products, such as carboxylated derivatives. One of the most promising approaches for activating, capturing, and valorizing CO2 is the use of electrochemical techniques. In the current manuscript, we described an electrocarboxylation route for synthesizing 4-cyanobenzoic acid by valorizing CO2 through the synergistic use of electrochemical techniques (“green technology”) and ionic liquids (ILs) (“green solvents”)—two of the major entries in the general green chemistry tool kit. Moreover, the use of silver cathodes and ILs enabled the electrochemical potential applied to be reduced by more than 0.4 V. The “green” synthesis of those derivatives would provide a suitable environmentally friendly process for the design of plasticizers based on phthalate derivatives.

scholarly journals Extreme droughts drive tropical semi-arid eutrophic reservoirs towards CO2 sub-saturation

2018 ◽  
Vol 30 (0) ◽  
Author(s):  
Jurandir Rodrigues de Mendonça Júnior ◽  
André Megali Amado ◽  
Luciana de Oliveira Vidal ◽  
Arthur Mattos ◽  
Vanessa Becker
Keyword(s):  
Carbon Dioxide ◽  
Water Level ◽  
Chlorophyll A ◽  
Co2 Reduction ◽  
Water Volume ◽  
Drought Period ◽  
Autotrophic Metabolism ◽  
Semi Arid Region ◽  
Carbon Dioxide Co2 ◽  
Semi Arid

Abstract Aim: This study aimed to evaluate the carbon dioxide (CO2) dynamics in tropical semi-arid reservoirs during a prolonged drought period as well as to test if the trophic state affects the CO2 saturation. Methods This study was performed in four reservoirs located in the tropical semi-arid region in the northeast of Brazil. All samplings were performed between 9 and 12 am using a Van Dorn Bottle. Samples for partial pressure of carbon dioxide (pCO2 ) measurements were taken in the sub-surface as well as samples for total phosphorus and chlorophyll-a. Correlation analysis and linear regression were used to detect relations among the calculated pCO2, water volume and chlorophyll-a. Results The water level reduction due to atypical droughts caused chlorophyll-a concentrations to increase, which in turn, led to CO2 reduction in the water. However, CO2 concentrations were very variable and an alternation between CO2 sub-saturation and super-saturation conditions was observed. This paper showed that water volume and chlorophyll-a were important regulators of CO2 in the water, as well as important carbon balance predictors in the tropical semiarid reservoirs. Conclusions The results of this paper indicate that the eutrophication allied to drastic water level reductions lead to a tendency of autotrophic metabolism of these systems.

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