scholarly journals The Degradation of Phenol via in-situ H2O2 Production Over Supported Pd-based Catalysts

2021 ◽  
Author(s):  
Alba Santos ◽  
Richard Lewis ◽  
David John Morgan ◽  
Thomas Davies ◽  
Euan Hampton ◽  
...  
Keyword(s):  
Organic Contaminants ◽  
Oxidative Degradation ◽  
H2o2 Production ◽  
In Situ Production ◽  
Supported Pd

The oxidative degradation of phenol via the in-situ production of H2O2 from molecular H2 and O2 offers an attractive route to the destruction of organic contaminants in water streams, potentially...

scholarly journals Enhanced Selective Oxidation of Benzyl Alcohol via In Situ H2O2 Production over Supported Pd-Based Catalysts

ACS Catalysis ◽  
2021 ◽  
pp. 2701-2714
Author(s):  
Caitlin M. Crombie ◽  
Richard J. Lewis ◽  
Rebekah L. Taylor ◽  
David J. Morgan ◽  
Thomas E. Davies ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Selective Oxidation ◽  
H2o2 Production ◽  
Oxidation Of Benzyl Alcohol ◽  
Supported Pd

In-Situ Oxidative Degradation of Emerging Contaminants in Soil and Groundwater Using a New Class of Stabilized MnO2 Nanoparticles

2016 ◽  
pp. 112-136
Author(s):  
Bing Han ◽  
Wen Liu ◽  
Dongye Zhao
Keyword(s):  
Organic Contaminants ◽  
Emerging Contaminants ◽  
Low Cost ◽  
Oxidative Degradation ◽  
In Situ Remediation ◽  
New Class ◽  
Mno2 Nanoparticles ◽  
In Situ Degradation ◽  
Trace Concentrations

Emerging Organic Contaminants (EOCs) such as steroidal estrogen hormones are of growing concern in recent years, as trace concentrations of these hormones can cause adverse effects on the environmental and human health. While these hormones have been widely detected in soil and groundwater, effective technology has been lacking for in-situ degradation of these contaminants. This chapter illustrates a new class of stabilized MnO2 nanoparticles and a new in-situ technology for oxidative degradation of EOCs in soil and groundwater. The stabilized nanoparticles were prepared using a low-cost, food-grade Carboxymethyl Cellulose (CMC) as a stabilizer. The nanoparticles were then characterized and tested for their effectiveness for degradation of both aqueous and soil-sorbed E2 (17ß-estradiol). Column tests confirmed the effectiveness of the nanoparticles for in-situ remediation of soil sorbed E2. The nanoparticle treatment decreased both water leachable and soil-sorbed E2, offering a useful alternative for in-situ remediation of EOCs in the subsurface.

scholarly journals The Selective Oxidation of Cyclohexane via In-situ H2O2 Production Over Supported Pd-based Catalysts

2021 ◽  
Author(s):  
Caitlin M. Crombie ◽  
Richard J. Lewis ◽  
Dávid Kovačič ◽  
David J. Morgan ◽  
Thomas J. A. Slater ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Catalytic Performance ◽  
Environmental Concerns ◽  
H2o2 Production ◽  
X Ray ◽  
Mixed Oxidation ◽  
Order Of Magnitude ◽  
Oil Concentration ◽  
Supported Pd

AbstractThe oxidation of cyclohexane via the in-situ production of H2O2 from molecular H2 and O2 offers an attractive route to the current industrial means of producing cyclohexanone and cyclohexanol (KA oil), key materials in the production of Nylon. The in-situ route has the potential to overcome the significant economic and environmental concerns associated with the use of commercial H2O2, while also allowing for the use of far lower reaction temperatures than those typical of the purely aerobic route to KA oil. Herein we demonstrate the efficacy of a series of bi-functional Pd-based catalysts, which offer appreciable concentrations of KA oil, under conditions where limited activity is observed using O2 alone. In particular the introduction of V into a supported Pd catalyst is seen to improve KA oil concentration by an order of magnitude, compared to the Pd-only analogue. In particular we ascribe this improvement in catalytic performance to the development of Pd domains of mixed oxidation state upon V incorporation as evidenced through X-ray photoelectron spectroscopy. Graphic Abstract

scholarly journals Atomic-level design of CoOH+–hydroxyapatite@C catalysts for superfast degradation of organics via peroxymonosulfate activation

2018 ◽  
Vol 54 (39) ◽  
pp. 4919-4922 ◽  
Author(s):  
Feng Song ◽  
Huayang Zhang ◽  
Shaobin Wang ◽  
Lihong Liu ◽  
Xiaoyao Tan ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Organic Contaminants ◽  
Oxidative Degradation ◽  
Atomic Level ◽  
Simultaneous Adsorption ◽  
Adsorption Of Co ◽  
Level Design

In situ formation of CoOH+–hydroxyapatite@C via ion exchange between Ca and Co realises the simultaneous adsorption of Co2+ and catalytic peroxymonosulfate oxidation for superfast oxidative degradation of organic contaminants.

Downflow Bubble Column Electrochemical Reactor (DBCER): In-situ production of H2O2 and O3 to conduct Electroperoxone Process

2021 ◽  
pp. 105148
Author(s):  
Germán Santana-Martínez ◽  
Gabriela Roa-Morales ◽  
Leobardo Gómez-Olivan ◽  
Ever Peralta-Reyes ◽  
Rubí Romero ◽  
...  
Keyword(s):  
Bubble Column ◽  
Electrochemical Reactor ◽  
In Situ Production

scholarly journals Carbon nitride nanotubes with in situ grafted hydroxyl groups for highly efficient spontaneous H2O2 production

2021 ◽  
Vol 288 ◽  
pp. 119993
Author(s):  
Liang Zhou ◽  
Juying Lei ◽  
Fuchen Wang ◽  
Lingzhi Wang ◽  
Michael R. Hoffmann ◽  
...  
Keyword(s):  
Carbon Nitride ◽  
H2o2 Production ◽  
Hydroxyl Groups ◽  
Highly Efficient

scholarly journals Au Modified F-TiO2 for Efficient Photocatalytic Synthesis of Hydrogen Peroxide

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 3844
Author(s):  
Lijuan Li ◽  
Bingdong Li ◽  
Liwei Feng ◽  
Xiaoqiu Zhang ◽  
Yuqian Zhang ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Reaction System ◽  
Reaction Medium ◽  
Pure Tio2 ◽  
H2o2 Production ◽  
Tio2 Photocatalyst ◽  
H2o2 Decomposition ◽  
Spin Resonance ◽  
Photocatalytic Synthesis

In this work, Au-modified F-TiO2 is developed as a simple and efficient photocatalyst for H2O2 production under ultraviolet light. The Au/F-TiO2 photocatalyst avoids the necessity of adding fluoride into the reaction medium for enhancing H2O2 synthesis, as in a pure TiO2 reaction system. The F− modification inhibits the H2O2 decomposition through the formation of the ≡Ti–F complex. Au is an active cocatalyst for photocatalytic H2O2 production. We compared the activity of TiO2 with F− modification and without F− modification in the presence of Au, and found that the H2O2 production rate over Au/F-TiO2 reaches four times that of Au/TiO2. In situ electron spin resonance studies have shown that H2O2 is produced by stepwise single-electron oxygen reduction on the Au/F-TiO2 photocatalyst.

scholarly journals Riboflavin Production in Lactococcus lactis: Potential for In Situ Production of Vitamin-Enriched Foods

2004 ◽  
Vol 70 (10) ◽  
pp. 5769-5777 ◽  
Author(s):  
Catherine Burgess ◽  
Mary O'Connell-Motherway ◽  
Wilbert Sybesma ◽  
Jeroen Hugenholtz ◽  
Douwe van Sinderen
Keyword(s):  
Functional Analysis ◽  
Lactic Acid ◽  
Lactococcus Lactis ◽  
Regulatory Region ◽  
Northern Hybridization ◽  
Vitamin B ◽  
Fermented Foods ◽  
Riboflavin Production ◽  
In Situ Production

ABSTRACT This study describes the genetic analysis of the riboflavin (vitamin B2) biosynthetic (rib) operon in the lactic acid bacterium Lactococcus lactis subsp. cremoris strain NZ9000. Functional analysis of the genes of the L. lactis rib operon was performed by using complementation studies, as well as by deletion analysis. In addition, gene-specific genetic engineering was used to examine which genes of the rib operon need to be overexpressed in order to effect riboflavin overproduction. Transcriptional regulation of the L. lactis riboflavin biosynthetic process was investigated by using Northern hybridization and primer extension, as well as the analysis of roseoflavin-induced riboflavin-overproducing L. lactis isolates. The latter analysis revealed the presence of both nucleotide replacements and deletions in the regulatory region of the rib operon. The results presented here are an important step toward the development of fermented foods containing increased levels of riboflavin, produced in situ, thus negating the need for vitamin fortification.

scholarly journals Scaling-up of microbial electrosynthesis with multiple electrodes for in situ production of hydrogen peroxide

iScience ◽  
2021 ◽  
Vol 24 (2) ◽  
pp. 102094
Author(s):  
Rusen Zou ◽  
Aliyeh Hasanzadeh ◽  
Alireza Khataee ◽  
Xiaoyong Yang ◽  
Mingyi Xu ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Scaling Up ◽  
Microbial Electrosynthesis ◽  
Multiple Electrodes ◽  
Production Of Hydrogen ◽  
In Situ Production
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