scholarly journals On the reaction mechanism of MnOx/SAPO-34 bifunctional catalysts for the conversion of syngas to light olefins

Author(s):  
Christophe Coudercy ◽  
Valentin L'hospital ◽  
Ruben Checa ◽  
Anthony Le Valant ◽  
Pavel Afanasiev ◽  
...  

MnOx/SAPO-34 bifunctional catalysts are efficient for the conversion of syngas to light olefins. However, the reaction mechanism is still debated in particular the nature of the intermediate formed on MnOx...

2021 ◽  
Vol 57 (27) ◽  
pp. 3323-3326
Author(s):  
Miao Yu ◽  
Nicoló Tormene ◽  
Aleksei Bolshakov ◽  
Brahim Mezari ◽  
Anna Liutkova ◽  
...  

We demonstrated that methanethiol can be selectively converted to light olefins over 8MR zeolites which provides clues about the reaction mechanism of MTH chemistry.


2020 ◽  
Vol 10 (5) ◽  
pp. 1507-1517 ◽  
Author(s):  
Adrian Ramirez ◽  
Abhishek Dutta Chowdhury ◽  
Mustafa Caglayan ◽  
Alberto Rodriguez-Gomez ◽  
Nimer Wehbe ◽  
...  

The conversion of CO2 to light olefins via bifunctional catalysts (i.e. metal oxides/zeolites) is a promising approach to tackle CO2 emissions and, at the same time, reduce fossil-fuel dependence by closing the carbon cycle.


Energies ◽  
2021 ◽  
Vol 14 (23) ◽  
pp. 8190
Author(s):  
Zahra Gholami ◽  
Fatemeh Gholami ◽  
Zdeněk Tišler ◽  
Mohammadtaghi Vakili

Light olefins are the main building blocks used in the petrochemical and chemical industries for the production of different components such as polymers, synthetic fibers, rubbers, and plastic materials. Currently, steam cracking of hydrocarbons is the main technology for the production of light olefins. In steam cracking, the pyrolysis of feedstocks occurs in the cracking furnace, where hydrocarbon feed and steam are first mixed and preheated in the convection section and then enter the furnace radiation section to crack to the desired products. This paper summarizes olefin production via the steam cracking process; and the reaction mechanism and cracking furnace are also discussed. The effect of different operating parameters, including temperature, residence time, feedstock composition, and the steam-to-hydrocarbon ratio, are also reviewed.


2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Junjie Su ◽  
Haibo Zhou ◽  
Su Liu ◽  
Chuanming Wang ◽  
Wenqian Jiao ◽  
...  

2019 ◽  
Vol 129 ◽  
pp. 105711 ◽  
Author(s):  
Jian Li ◽  
Tie Yu ◽  
Dengyun Miao ◽  
Xiulian Pan ◽  
Xinhe Bao

Author(s):  
Hongyu Chen ◽  
Zhengmao Liu ◽  
Na Li ◽  
Feng Jiao ◽  
Yuxiang Chen ◽  
...  

Direct conversion of syngas into light olefins (C2=-C4=) using bifunctional catalyst composed of oxide and zeolite (OXZEO) has attracted extensive attention in both academia and industry. However, the reaction intermediates...


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