One-step calcination synthesis of WC-Mo2C heterojunction nanoparticles as novel H2-production cocatalysts for enhanced photocatalytic activity of TiO2

Author(s):  
Lulu Gao ◽  
Jinfeng Liu ◽  
Haoyu Long ◽  
Ping Wang ◽  
Huogen Yu

Hexagonal molybdenum carbide (Mo2C) as a high-efficiency non-noble cocatalyst has been widely applied in the photocatalytic H2-generation area due to its platinum-like H+-adsorption potential, high thermal stability, and excellent electrochemistry...

Nanomaterials ◽  
2018 ◽  
Vol 8 (5) ◽  
pp. 294 ◽  
Author(s):  
Peisan Wang ◽  
Chunxia Qi ◽  
Pengchao Wen ◽  
Luyuan Hao ◽  
Xin Xu ◽  
...  

2021 ◽  
pp. 126497
Author(s):  
Adriano Gennari ◽  
Renate Simon ◽  
Nathalia Denise de Moura Sperotto ◽  
Cristiano Valim Bizarro ◽  
Luiz Augusto Basso ◽  
...  

2019 ◽  
Vol 45 (9) ◽  
pp. 11749-11755 ◽  
Author(s):  
Shangkai He ◽  
Biaolin Peng ◽  
Glenn J.T. Leighton ◽  
Christopher Shaw ◽  
Ningzhang Wang ◽  
...  

Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2449
Author(s):  
Shiliang Heng ◽  
Lei Li ◽  
Weiwei Li ◽  
Haiyan Li ◽  
Jingyu Pang ◽  
...  

The development of high-efficiency, recyclable, and inexpensive photocatalysts for water splitting for hydrogen production is of great significance to the application of solar energy. Herein, a series of graphene-decorated polyoxoniobate photocatalysts Nb6/PPy-RGO (Nb6 = K7HNb6O19, RGO = reduced graphene oxide, PPy = polypyrrole), with the bridging effect of polypyrrole were prepared through a simple one-step solvothermal method, which is the first example of polyoxoniobate-graphene-based nanocomposites. The as-fabricated photocatalyst showed a photocatalytic H2 evolution activity without any co-catalyst. The rate of 1038 µmol g−1 in 5 h under optimal condition is almost 43 times higher than that of pure K7HNb6O19·13H2O. The influencing factors for photocatalysts in photocatalytic hydrogen production under simulated sunlight were studied in detail and the feasible mechanism is presented in this paper. These results demonstrate that Nb6O19 acts as the main catalyst and electron donor, RGO provides active sites, and PPy acted as an electronic bridge to extend the lifetime of photo-generated carriers, which are crucial factors for photocatalytic H2 production.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Zhihui Li ◽  
Hanchu Chen ◽  
Yanyan Li ◽  
Hui Wang ◽  
Yanru Liu ◽  
...  

Photocatalytic water-splitting with Z-scheme semiconductor heterojunctions is a promising way to achieve renewable solar fuels. Nevertheless, developing earth-abundant direct Z-scheme photocatalytic systems for efficient H2 production is still under-developed. In...


Author(s):  
Xueyou Gao ◽  
Deqian Zeng ◽  
Qingru Zeng ◽  
Zongzhuo Xie ◽  
Toyohisha Fujita ◽  
...  

Co-based cocatalysts have attracted considerable attention as potential alternatives for the noble-metal (Pt) in photocatalytic water splitting. However, the two-dimensional (2D) porous-structured Co-based cocatalysts toward photocatalytic hydrogen (H2) production application...


CrystEngComm ◽  
2014 ◽  
Vol 16 (30) ◽  
pp. 6841-6847 ◽  
Author(s):  
Weiwei Xia ◽  
Haibo Wang ◽  
Xianghua Zeng ◽  
Jie Han ◽  
Jun Zhu ◽  
...  

Flower-like hollow microspheres were synthesized on a large scale using a one-step hydrothermal route.


2012 ◽  
Vol 125 ◽  
pp. 367-374 ◽  
Author(s):  
Hongwei Bai ◽  
Jermyn Juay ◽  
Zhaoyang Liu ◽  
Xiaoxiao Song ◽  
Siew Siang Lee ◽  
...  

Catalysts ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 655 ◽  
Author(s):  
Yifan Zhang ◽  
Young-Jung Heo ◽  
Ji-Won Lee ◽  
Jong-Hoon Lee ◽  
Johny BajGai ◽  
...  

Photocatalytic H2 generation via water splitting is increasingly gaining attention as a viable alternative for improving the performance of H2 production for solar energy conversion. Many methods were developed to enhance photocatalyst efficiency, primarily by modifying its morphology, crystallization, and electrical properties. Here, we summarize recent achievements in the synthesis and application of various photocatalysts. The rational design of novel photocatalysts was achieved using various strategies, and the applications of novel materials for H2 production are displayed herein. Meanwhile, the challenges and prospects for the future development of H2-producing photocatalysts are also summarized.


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