Hydroxy acid-functionalized ionic liquids as green alternatives for the efficient catalytic conversion of epoxides to cyclic carbonates under solvent and co-catalyst-free conditions

Author(s):  
Shuang Yue ◽  
Hongliu Qu ◽  
Xinxin Song ◽  
Shuliang Zang ◽  
Guichun Deng

Environmentally friendly synthesis route of carbonates from CO2 and epoxides catalysed by novel hydroxy acid ionic liquids under metal/halogen/cocatalyst/solvent-free conditions.

2016 ◽  
Vol 18 (9) ◽  
pp. 2851-2863 ◽  
Author(s):  
Mengshuai Liu ◽  
Lin Liang ◽  
Xin Li ◽  
Xiangxiang Gao ◽  
Jianmin Sun

Novel environmentally benign urea derivative-based ILs were successfully prepared and characterized, and displayed exceptional performances for both CO2 capture and CO2 catalytic conversion under metal-, cocatalyst- and solvent-free conditions.


2021 ◽  
pp. 174751982110325
Author(s):  
Yan Xiao ◽  
Jiyu Gao ◽  
Peng Chen ◽  
Guangliang Chen ◽  
Zicheng Li ◽  
...  

A series of symmetrical 1,4-disubstituted buta-1,3-diynes is prepared with excellent yields (up to 95%) through homocoupling of terminal alkynes catalyzed by a copper salt under solvent-free conditions. This method provides an environmentally friendly process to prepare 1,3-diynes in short reaction times under mild conditions. Furthermore, the method is suitable for a wide substrate scope and has excellent functional group compatibility. The reaction can also be scaled up to gram level.


RSC Advances ◽  
2016 ◽  
Vol 6 (60) ◽  
pp. 55319-55326 ◽  
Author(s):  
Reza Tayebee ◽  
Kokab Savoji ◽  
Maryam Kargar Razi ◽  
Behrooz Maleki

An efficient protocol for the synthesis of C3-symmetrical 1,3,5-triarylbenzenes under solvent-free conditions. γ-Al2O3/H5PW10V2O40 nanocomposite is introduced as a highly reusable catalyst.


Sign in / Sign up

Export Citation Format

Share Document