Rhodium Catalysts with Cofactor Mimics for Biomimetic Reduction of C=N Bonds

2021 ◽  
Author(s):  
Jie Tang ◽  
Wenjin Dong ◽  
FuShan Chen ◽  
Li Deng ◽  
Mo Xian
Keyword(s):  
Transfer Hydrogenation ◽  
Rhodium Complex ◽  
Rhodium Catalysts

A strategy based on the cooperation between metal and bonded cofactor mimics was applied to the transfer hydrogenation of C=N bonds. We designed and synthesized a rhodium complex containing 1,3-dimethylbenzoimidazole...

Rhodium-catalyzed asymmetric transfer hydrogenation of 4-quinolone derivatives

2020 ◽  
Vol 7 (8) ◽  
pp. 975-979 ◽  
Author(s):  
Bin He ◽  
Phannarath Phansavath ◽  
Virginie Ratovelomanana-Vidal
Keyword(s):  
Formic Acid ◽  
Transfer Hydrogenation ◽  
Rhodium Complex ◽  
Asymmetric Transfer Hydrogenation ◽  
Quinolone Derivatives

4-Quinolone derivatives were conveniently reduced to 1,2,3,4-tetrahydroquinoline-4-ols with excellent enantioselectivities through asymmetric transfer hydrogenation using a tethered rhodium complex and formic acid/triethylamine as the hydride source.

The highly chemoselective transfer hydrogenation of the carbon–carbon double bond of conjugated nitroalkenes by a rhodium complex

Tetrahedron ◽  
2012 ◽  
Vol 68 (24) ◽  
pp. 4609-4620 ◽  
Author(s):  
Jing Xiang ◽  
Er-Xiao Sun ◽  
Chun-Xia Lian ◽  
Wei-Cheng Yuan ◽  
Jin Zhu ◽  
...  
Keyword(s):  
Double Bond ◽  
Transfer Hydrogenation ◽  
Rhodium Complex ◽  
Carbon Double Bond

Asymmetric transfer hydrogenation catalysed by hydrophobic dendritic DACH–rhodium complex in water

2006 ◽  
Vol 4 (17) ◽  
pp. 3319-3324 ◽  
Author(s):  
Lin Jiang ◽  
Tong-Fei Wu ◽  
Ying-Chun Chen ◽  
Jin Zhu ◽  
Jin-Gen Deng
Keyword(s):  
Transfer Hydrogenation ◽  
Rhodium Complex ◽  
Asymmetric Transfer Hydrogenation
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