Promotion of hydrogen evolution catalysis by ordered hierarchically porous electrodes

Author(s):  
Yihuan Yu ◽  
Pengdong Liu ◽  
Meiling Dou ◽  
Jin Niu ◽  
Zhengping Zhang ◽  
...  

Ru-Based ordered hierarchically porous electrodes promote fast mass transfer and diffusion for hydrogen evolution under high current densities.

2021 ◽  
pp. 2105579
Author(s):  
Yeshu Tan ◽  
Ruikuan Xie ◽  
Siyu Zhao ◽  
Xuekun Lu ◽  
Longxiang Liu ◽  
...  

1963 ◽  
Vol 85 (4) ◽  
pp. 395-401 ◽  
Author(s):  
Reno R. Cole ◽  
Yoram Hopenfeld

A method of polishing metals by means of an electrolytic jet at extremely high current densities (to 1750 amps per sq in.) is described. Data are presented on the relation of polishing effect on various metals to current density and electrolyte flow rate for several electrolytes. An experimental method is described whereby the relationship of the above factors can be determined. It was found that all metals investigated could be polished at high enough current densities. Previous theories of electrolytic polishing are discussed and shown to not fully account for the process investigated. A modified theory to account for polishing at the high current densities observed is presented and is supported by mathematical analysis based on fundamental mass transfer considerations.


2020 ◽  
Vol 59 (46) ◽  
pp. 20423-20427 ◽  
Author(s):  
Tongtong Liu ◽  
Wenbin Gao ◽  
Qiqi Wang ◽  
Meiling Dou ◽  
Zhengping Zhang ◽  
...  

2019 ◽  
Vol 258 ◽  
pp. 117965 ◽  
Author(s):  
Peng Jiang ◽  
Hao Huang ◽  
Jiefeng Diao ◽  
Shipeng Gong ◽  
Shi Chen ◽  
...  

2019 ◽  
Vol 489 ◽  
pp. 435-445 ◽  
Author(s):  
Jingtao Zhang ◽  
Zhen Zhang ◽  
Yuanjun Yao ◽  
Xinzhou Ma ◽  
Yibin Yang ◽  
...  

2012 ◽  
Vol 77 (5) ◽  
pp. 651-665 ◽  
Author(s):  
Gökhan Orhan ◽  
Güzey Gezgin

The effects of copper ion concentrations and electrolyte temperature on the morphologies and on the apparent densities of electrolytic copper powders at high current densities under galvanostatic regime were examined. These parameters were evaluated by the current efficiency of hydrogen evolution. In addition, scanning electron microscopy was used for analyzing the morphology of the copper powders. It was found that the morphology was dependent over the copper ion concentration and electrolyte temperature under same current density (CD) conditions. At 150 mA cm-2 and the potential of 1000?20 mV (vs. SCE), porous and disperse copper powders were obtained at low concentrations of Cu ions (0.120 M Cu2+ in 0.50 M H2SO4). Under this condition, high rate of hydrogen evolution reaction took place parallel to copper electrodeposition. The morphology was changed from porous, disperse and cauliflower-like to coral-like, shrub-like and stalk-stock like morphology with the increasing of Cu ion concentrations towards 0.120 M, 0.155 M, 0.315 M, 0.475 M and 0.630 M Cu2+ in 0.5 M H2SO4 respectively at the same CD. Similarly, as the temperature was increased, powder morphology and apparent density were observed to be changed. The apparent density values of copper powders were found to be suitable for many of the powder metallurgy applications.


2020 ◽  
Vol 132 (46) ◽  
pp. 20603-20607
Author(s):  
Tongtong Liu ◽  
Wenbin Gao ◽  
Qiqi Wang ◽  
Meiling Dou ◽  
Zhengping Zhang ◽  
...  

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