Interfacial Modification of Co(OH)2/Co3O4 Nanosheet Heterostructure Arrays for Efficient Oxygen Evolution Reaction

2021 ◽  
Author(s):  
Lekai Zheng ◽  
Lina Hu ◽  
Yongchuan Hu ◽  
Fang Liu ◽  
Zhiming Liu ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Low Cost ◽  
Cobalt Hydroxide ◽  
Interfacial Modification ◽  
Production Of Hydrogen ◽  
Co3o4 Nanosheet

The development of efficient, stable and low-cost oxygen evolution reaction (OER) catalysts in anodes is essential for the production of hydrogen resources by electrolyzing water. Cobalt hydroxide (α-Co(OH)2) is one...

scholarly journals Effects of Annealing Temperature on the Oxygen Evolution Reaction Activity of Copper–Cobalt Oxide Nanosheets

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 657
Author(s):  
Geul Han Kim ◽  
Yoo Sei Park ◽  
Juchan Yang ◽  
Myeong Je Jang ◽  
Jaehoon Jeong ◽  
...  
Keyword(s):  
High Activity ◽  
Cobalt Oxide ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Low Cost ◽  
High Surface ◽  
High Surface Area ◽  
Cobalt Hydroxide ◽  
Ni Foam ◽  
Electron Conduction

Developing high performance, highly stable, and low-cost electrodes for the oxygen evolution reaction (OER) is challenging in water electrolysis technology. However, Ir- and Ru-based OER catalysts with high OER efficiency are difficult to commercialize as precious metal-based catalysts. Therefore, the study of OER catalysts, which are replaced by non-precious metals and have high activity and stability, are necessary. In this study, a copper–cobalt oxide nanosheet (CCO) electrode was synthesized by the electrodeposition of copper–cobalt hydroxide (CCOH) on Ni foam followed by annealing. The CCOH was annealed at various temperatures, and the structure changed to that of CCO at temperatures above 250 °C. In addition, it was observed that the nanosheets agglomerated when annealed at 300 °C. The CCO electrode annealed at 250 °C had a high surface area and efficient electron conduction pathways as a result of the direct growth on the Ni foam. Thus, the prepared CCO electrode exhibited enhanced OER activity (1.6 V at 261 mA/cm2) compared to those of CCOH (1.6 V at 144 mA/cm2), Co3O4 (1.6 V at 39 mA/cm2), and commercial IrO2 (1.6 V at 14 mA/cm2) electrodes. The optimized catalyst also showed high activity and stability under high pH conditions, demonstrating its potential as a low cost, highly efficient OER electrode material.

A binuclear Co-based metal-organic framework towards efficient oxygen evolution reaction

2021 ◽  
Author(s):  
Ning Liu ◽  
Qiaoqiao Zhang ◽  
Jingqi Guan
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Research Interest ◽  
Metal Organic ◽  
Organic Framework

Seeking for low-cost and high-performance electrocatalysts for oxygen evolution reaction (OER) has drawn enormous research interest in the last few years. Reported herein is the topotactic construction of a binuclear...

Controllable growth of graphdiyne layered nanosheets for high-performance water oxidation

2021 ◽  
Author(s):  
Shuya Zhao ◽  
Yurui Xue ◽  
Zhongqiang Wang ◽  
Zhiqiang Zheng ◽  
Xiaoyu Luan ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
High Performance ◽  
Low Cost ◽  
Highly Active ◽  
Controllable Growth

Developing highly active, stable and low-cost electrocatalysts capable of an efficient oxygen evolution reaction (OER) is urgent and challenging.

MOF-derived M-OOH with rich oxygen defects by in-situ electro-oxidation reconstitution for highly efficient oxygen evolution reaction

2021 ◽  
Author(s):  
Zhikai Shi ◽  
Zebin Yu ◽  
Ronghua Jiang ◽  
Jun Huang ◽  
Yanping Hou ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Energy Production ◽  
Low Cost ◽  
Highly Efficient ◽  
Oxygen Defects ◽  
Electro Oxidation

The oxygen evolution reaction (OER) is an important half-reaction in the field of energy production. However, how effectively, simply, and greenly to prepare low-cost OER electrocatalysts remains a problem. Herein,...

High-performance anion exchange membrane alkaline seawater electrolysis

2021 ◽  
Author(s):  
Yoo Sei Park ◽  
Jooyoung Lee ◽  
Myeong-Je Jang ◽  
Juchan Yang ◽  
Jae Hoon Jeong ◽  
...  
Keyword(s):  
Anion Exchange ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Anion Exchange Membrane ◽  
Hydrogen Energy ◽  
Highly Active ◽  
Production Of Hydrogen ◽  
Exchange Membrane ◽  
Seawater Electrolysis

Seawater electrolysis is a promising technology for the production of hydrogen energy and seawater desalination. To produce hydrogen energy through seawater electrolysis, highly active electrocatalysts for the oxygen evolution reaction...

scholarly journals Nickel-cobalt oxalate as efficient non-precious electrocatalyst for improved alkaline oxygen evolution reaction

2021 ◽  
Author(s):  
Venkataramanan Mahalingam ◽  
Sourav Ghosh ◽  
Rajkumar Jana ◽  
Sagar Ganguli ◽  
Harish Reddy Inta ◽  
...  
Keyword(s):  
Aqueous Medium ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Low Cost ◽  
Next Generation ◽  
Synthetic Strategy ◽  
Nickel Cobalt ◽  
Cobalt Oxalate

The quest for developing next-generation non-precious electrocatalyst is getting aroused in recent times. Herein, we have designed and developed a low cost electrocatalyst by ligand-assisted synthetic strategy in aqueous medium....

scholarly journals Spin-sate reconfiguration induced by alternating magnetic field for efficient oxygen evolution reaction

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Gang Zhou ◽  
Peifang Wang ◽  
Hao Li ◽  
Bin Hu ◽  
Yan Sun ◽  
...  
Keyword(s):  
Reaction Kinetics ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Active Sites ◽  
Reaction Pathway ◽  
Low Cost ◽  
Orbital Interaction ◽  
New Paradigm ◽  
Metal Organic ◽  
Energy Conversion Devices

AbstractOxygen evolution reaction (OER) plays a determining role in electrochemical energy conversion devices, but challenges remain due to the lack of effective low-cost electrocatalysts and insufficient understanding about sluggish reaction kinetics. Distinguish from complex nano-structuring, this work focuses on the spin-related charge transfer and orbital interaction between catalysts and intermediates to accelerate catalytic reaction kinetics. Herein, we propose a simple magnetic-stimulation approach to rearrange spin electron occupation in noble-metal-free metal-organic frameworks (MOFs) with a feature of thermal-differentiated superlattice, in which the localized magnetic heating in periodic spatial distribution makes the spin flip occur at particular active sites, demonstrating a spin-dependent reaction pathway. As a result, the spin-rearranged Co0.8Mn0.2 MOF displays mass activities of 3514.7 A gmetal−1 with an overpotential of ~0.27 V, which is 21.1 times that of pristine MOF. Our findings provide a new paradigm for designing spin electrocatalysis and steering reaction kinetics.

Constructing oxygen vacancy-enriched Fe2O3@NiO heterojunctions for highly efficient electrocatalytic alkaline water splitting

CrystEngComm ◽  
2021 ◽  
Author(s):  
Yan Sang ◽  
Xi Cao ◽  
Gaofei Ding ◽  
Zixuan Guo ◽  
Yingying Xue ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
High Purity ◽  
Oxygen Evolution Reaction ◽  
High Efficiency ◽  
Low Cost ◽  
Dual Function ◽  
Alkaline Water ◽  
High Purity Hydrogen

Electrolysis of water to produce high-purity hydrogen is a very promising method. The development of green, high-efficiency, long-lasting and low-cost dual function electrocatalysts for oxygen evolution reaction (OER) and hydrogen...

Low-Cost Pb-Co-Sn film for the Oxygen Evolution Reaction in Acid Media

2021 ◽  
Author(s):  
Marisol Maril ◽  
Pablo Tobosque ◽  
Nataly Cisternas ◽  
Marie-Paule Delplancke ◽  
Jean Luc Delplancke ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Low Cost ◽  
Acid Media
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