Heterogeneous catalysis with an organic–inorganic hybrid based on MoO3 chains decorated with 2,2′-biimidazole ligands

2021 ◽  
Author(s):  
Tatiana R. Amarante ◽  
Patrícia Neves ◽  
Filipe A. Almeida Paz ◽  
Ana C. Gomes ◽  
Martyn Pillinger ◽  
...  
Keyword(s):  
Heterogeneous Catalysis ◽  
Hybrid Materials ◽  
Recyclable Catalyst ◽  
Olefin Epoxidation ◽  
Inorganic Hybrid ◽  
One Dimensional

Polymeric [MoO3(2,2′-biimidazole)]·H2O outperforms other one-dimensional MoO3-ligand hybrid materials as a heterogeneous and recyclable catalyst for (bio)olefin epoxidation and sulfoxidation.

Ferroelasticity and piezoelectricity of organic–inorganic hybrid materials with a one-dimensional anionic structure: so similar, yet so different

CrystEngComm ◽  
2018 ◽  
Vol 20 (15) ◽  
pp. 2112-2119 ◽  
Author(s):  
Anna Piecha-Bisiorek ◽  
Klaudia Mencel ◽  
Vasyl Kinzhybalo ◽  
Aleksandra Szota ◽  
Ryszard Jakubas ◽  
...  
Keyword(s):  
Hybrid Materials ◽  
Dielectric Analysis ◽  
New Members ◽  
Inorganic Hybrid ◽  
One Dimensional ◽  
Halide Complexes ◽  
Structural Aspects

The synthesis, structural aspects, and thermal and dielectric analysis for new members of the ferroic family, polynuclear Bi(iii) and Sb(iii) halide complexes based on a pyrazolium cation with the formulas (C3N2H5)[BiCl4]·H2O and (C3N2H5)[SbCl4]·H2O, are presented.

One-Dimensional Organic-Inorganic Hybrid Materials Based on Antimony

2017 ◽  
Vol 2017 (28) ◽  
pp. 3401-3408 ◽  
Author(s):  
George A. Mousdis ◽  
Nikolaos-Minas Ganotopoulos ◽  
Hamdi Barkaoui ◽  
Younes Abid ◽  
Vassilis Psycharis ◽  
...  
Keyword(s):  
Hybrid Materials ◽  
Inorganic Hybrid ◽  
One Dimensional

Isostructural organic–inorganic hybrid compounds: triethylcholine tribromidocadmate and triethylcholine tribromidomercurate

2015 ◽  
Vol 71 (8) ◽  
pp. 728-732
Author(s):  
Dong-Yan Wang ◽  
Xue-Li Hou ◽  
Xue-Nan Li
Keyword(s):  
Hydrogen Bonding ◽  
Hybrid Materials ◽  
X Ray Diffraction ◽  
Inorganic Hybrid ◽  
One Dimensional ◽  
X Ray ◽  
Hybrid Compounds ◽  
Trigonal Bipyramidal ◽  
Hydrogen Bonding Interactions ◽  
Distorted Trigonal Bipyramidal

In order to search for new anionic architectures and develop useful organic–inorganic hybrid materials in halometallate systems, two new crystalline organic–inorganic hybrid compounds have been prepared,i.e. catena-poly[triethyl(2-hydroxyethyl)azanium [[bromidocadmate(II)]-di-μ-bromido]], {(C8H20NO)[CdBr3]}n, (1), andcatena-poly[triethyl(2-hydroxyethyl)azanium [[bromidomercurate(II)]-di-μ-bromido]], {(C8H20NO)[HgBr3]}n, (2), and the structures determined by X-ray diffraction analysis. The compounds are isostructural, crystallizing in the space groupP21/n. The metal centres are five-coordinated by bromide anions, giving a slightly distorted trigonal–bipyramidal geometry. The crystal structures consist of one-dimensional edge-sharing chains ofMBr5trigonal bipyramids, between which triethylcholine counter-cations are intercalated. O—H...Br hydrogen-bonding interactions are present between the cations and anions.

UV Curable Organic-Inorganic Hybrid Materials

2000 ◽  
Vol 628 ◽  
Author(s):  
Guang-Way Jang ◽  
Ren-Jye Wu ◽  
Yuung-Ching Sheen ◽  
Ya-Hui Lin ◽  
Chi-Jung Chang
Keyword(s):  
Hybrid Materials ◽  
Colloidal Silica ◽  
Sol Gel ◽  
Solution Ph ◽  
Uv Curable ◽  
Inorganic Hybrid ◽  
Degradation Temperature ◽  
Sol Gel Process ◽  
The Stability ◽  
Thermal Degradation Temperature

This work successfully prepared an UV curable organic-inorganic hybrid material consisting of organic modified colloidal silica. Applications of UV curable organic-inorganic hybrid materials include abrasion resistant coatings, photo-patternable thin films and waveguides. Colloidal silica containing reactive functional groups were also prepared by reacting organic silane and tetraethyl orthosilicate (TEOS) using sol-gel process. In addition, the efficiency of grafting organic moiety onto silica nanoparticles was investigated by applying TGA and FTIR techniques. Experimental results indicated a strong interdependence between surface modification efficiency and solution pH. Acrylate-SiO2 hybrid formation could result in a shifting of thermal degradation temperature of organic component from about 200°C to near 400°C. In addition, the stability of organic modified colloidal silica in UV curable formula and the physical properties of resulting coatings were discussed. Furthermore, the morphology of organic modified colloidal silica was investigated by performing TEM and SEM studies‥

Ecosustainable Development of Novel Bio-inorganic Hybrid Materials as UV Protection Systems for Potential Cosmetic Applications

2015 ◽  
Vol 16 (12) ◽  
pp. 1070-1077
Author(s):  
Carla Villa ◽  
Chiara Lacapra ◽  
Roberto Rosa ◽  
Paolo Veronesi ◽  
Cristina Leonelli
Keyword(s):  
Hybrid Materials ◽  
Uv Protection ◽  
Inorganic Hybrid ◽  
Protection Systems

Lead-free organic–inorganic hybrid semiconductors and NLO switches tuned by dimensional design

2021 ◽  
Vol 9 (12) ◽  
pp. 4338-4343
Author(s):  
Hong-Yi Shen ◽  
Lei He ◽  
Ping-Ping Shi ◽  
Qiong Ye
Keyword(s):  
Hybrid Materials ◽  
Lead Free ◽  
Inorganic Hybrid ◽  
Hybrid Semiconductors ◽  
Functional Regulation

Two organic–inorganic hybrid materials exhibit functional regulation by introducing homochiral cations and different reagent ratios.

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