From graphene to graphene oxide: the importance of extended topological defects.

2022 ◽  
Author(s):  
Alexander J. Marsden ◽  
Mark Skilbeck ◽  
Matthew Healey ◽  
Helen R. Thomas ◽  
Marc Walker ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Topological Defects

Graphene oxide (GO) represents a complex family of materials related to graphene: easy to produce in large quantities, easy to process, and convenient to use as a basis for further...

LDPE Building Blocks with Controlled Graphene-oxide Interfaces: Composite Manufacturing and Electric Property Investigation

2016 ◽  
Vol 136 (2) ◽  
pp. 93-98 ◽  
Author(s):  
Paolo Mancinelli ◽  
Valentina Santangelo ◽  
Davide Fabiani ◽  
Andrea Saccani ◽  
Maurizio Toselli ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Building Blocks ◽  
Electric Property ◽  
Oxide Interfaces ◽  
Composite Manufacturing

THERMAL PERFORMANCE OF GRAPHENE OXIDE NANOFLUID IN MICROCHANNEL HEAT EXCHANGER

2020 ◽  
Vol 27 (5) ◽  
pp. 439-461
Author(s):  
Yue Seong Ong ◽  
Ku Zilati Ku Shaari ◽  
Afiq Mohd Laziz ◽  
Inn Leon Lu ◽  
Mohamad Fakhrul Ridhwan Samsudin ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Heat Exchanger ◽  
Thermal Performance ◽  
Microchannel Heat Exchanger

A Pseudo Five-Fold Symmetrical Ligand Drives Geometric Frustration in Porous Metal-Organic and Hydrogen Bonded Frameworks

2020 ◽  
Author(s):  
Frederik Haase ◽  
Gavin Craig ◽  
Mickaele Bonneau ◽  
kunihisa sugimoto ◽  
Shuhei Furukawa
Keyword(s):  
Topological Defects ◽  
Porous Metal ◽  
Building Blocks ◽  
Structural Features ◽  
Equilibrium Structure ◽  
Sorption Behavior ◽  
Building Unit ◽  
Geometric Frustration ◽  
Secondary Building Units ◽  
Hydrogen Bonded

Reticular framework materials thrive on designability, but unexpected reaction outcomes are crucial in exploring new structures and functionalities. By combining “incompatible” building blocks, we employed geometric frustration in reticular materials leading to emergent structural features. The combination of a pseudo C<sub>5</sub> symmetrical organic building unit based on a pyrrole core, with a C<sub>4</sub> symmetrical copper paddlewheel synthon led to three distinct frameworks by tuning the synthetic conditions. The frameworks show structural features typical for geometric frustration: self-limiting assembly, internally stressed equilibrium structures and topological defects in the equilibrium structure, which manifested in the formation of a hydrogen bonded framework, distorted and broken secondary building units and dangling functional groups, respectively. The influence of geometric frustration on the CO<sub>2</sub> sorption behavior and the discovery of a new secondary building unit shows geometric frustration can serve as a strategy to obtain highly complex porous frameworks.

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