scholarly journals The Role of Coordination Strength in Solid Polymer Electrolytes: Compositional Dependence of Transference Numbers in the Poly(ε-Caprolactone)–Poly(Trimethylene Carbonate) System

2021 ◽  
Author(s):  
Therese Eriksson ◽  
Amber Mace ◽  
Jonas Mindemark ◽  
Daniel Brandell
Keyword(s):  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Transference Numbers ◽  
Trimethylene Carbonate ◽  
Compositional Dependence ◽  
Carbonate System ◽  
Host Materials

Both polyesters and polycarbonates have been proposed as alternatives to polyethers as host materials for future polymer electrolytes for solid-state lithium-ion batteries. While being comparatively similar functional groups, the electron...

scholarly journals ε-Caprolactone-based solid polymer electrolytes for lithium-ion batteries: synthesis, electrochemical characterization and mechanical stabilization by block copolymerization

RSC Advances ◽  
2018 ◽  
Vol 8 (30) ◽  
pp. 16716-16725 ◽  
Author(s):  
Andreas Bergfelt ◽  
Matthew J. Lacey ◽  
Jonas Hedman ◽  
Christofer Sångeland ◽  
Daniel Brandell ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Electrochemical Characterization ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Trimethylene Carbonate ◽  
Block Copolymerization ◽  
Mechanical Stabilization

Three different polymers were synthesized and evaluated as solid polymer electrolytes: poly(ε-caprolactone) (PCL), polystyrene-poly(ε-caprolactone) (SC), and polystyrene-poly(ε-caprolactone-r-trimethylene carbonate) (SCT).

scholarly journals Novel solid polymer electrolytes based on poly(trimethylene carbonate) and lithium hexafluoroantimonate

2006 ◽  
Vol 8 (11) ◽  
pp. 1318-1321 ◽  
Author(s):  
Maria Manuela Silva ◽  
Paula Barbosa ◽  
Alan Evans ◽  
Michael John Smith
Keyword(s):  
Polymer Electrolytes ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Trimethylene Carbonate

scholarly journals Development of the PEO Based Solid Polymer Electrolytes for All-Solid State Lithium Ion Batteries

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1237 ◽  
Author(s):  
Yu Jiang ◽  
Xuemin Yan ◽  
Zhaofei Ma ◽  
Ping Mei ◽  
Wei Xiao ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
High Performance ◽  
Lithium Salt ◽  
Rapid Development ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Potential Candidate

Solid polymer electrolytes (SPEs) have attracted considerable attention due to the rapid development of the need for more safety and powerful lithium ion batteries. The prime requirements of solid polymer electrolytes are high ion conductivity, low glass transition temperature, excellent solubility to the conductive lithium salt, and good interface stability against Li anode, which makes PEO and its derivatives potential candidate polymer matrixes. This review mainly encompasses on the synthetic development of PEO-based SPEs (PSPEs), and the potential application of the resulting PSPEs for high performance, all-solid-state lithium ion batteries.

scholarly journals Contribution Succinonitrile additive for Performa LiTFSi Solid Polymer Electrolytes for Li-Ion Battery

2020 ◽  
Vol 20 (2) ◽  
Author(s):  
Qolby Sabrina ◽  
Titik Lestariningsih ◽  
Christin Rina Ratri ◽  
Achmad Subhan
Keyword(s):  
Ionic Conductivity ◽  
Polymer Electrolytes ◽  
Room Temperature ◽  
Lithium Salt ◽  
Ionic Conduction ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Half Cell ◽  
Li Ion

Solid polymer electrolyte (SPE) appropriate to solve packaging leakage and expansion volume in lithium-ion battery systems. Evaluation of electrochemical performance of SPE consisted of mixture lithium salt, solid plasticizer, and polymer precursor with different ratio. Impedance spectroscopy was used to investigate ionic conduction and dielectric response lithium bis(trifluoromethane)sulfony imide (LiTFSI) salt, and additive succinonitrile (SCN) plasticizer. The result showing enhanced high ionic conductivity. In half-cell configurations, wide electrochemical stability window of the SPE has been tested. Have stability window at room temperature, indicating great potential of SPE for application in lithium ion batteries. Additive SCN contribute to forming pores that make it easier for the li ion to move from the anode to the cathode and vice versa for better perform SPE. Pore of SPE has been charaterization with FE-SEM. Additive 5% w.t SCN shows the best ionic conductivity with 4.2 volt wide stability window and pretty much invisible pores.

scholarly journals Salt Concentration Effect on Electrical and Dielectric Properties of Solid Polymer Electrolytes based Carboxymethyl Cellulose for Lithium-ion Batteries

2021 ◽  
Vol 12 (5) ◽  
pp. 6114-6123
Keyword(s):  
Dielectric Properties ◽  
Ionic Conductivity ◽  
Polymer Electrolytes ◽  
Carboxymethyl Cellulose ◽  
Electrochemical Impedance ◽  
Lithium Ion ◽  
Lithium Perchlorate ◽  
Linear Sweep Voltammetry ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer

Solid polymer electrolytes (SPEs) based carboxymethyl cellulose (CMC) with lithium perchlorate (LiClO4) were prepared via solution drop-cast technique. The CMC host is complexed by different concentrations of LiClO4 salt. SPEs were characterized by Electrochemical Impedance Spectroscopy (EIS) and Linear Sweep Voltammetry (LSV) in coin cells with lithium metal electrodes. EIS performed unique results based on various ionic conductivity values and dielectric properties. The higher ionic conductivity (1.32 × 10-5 S/cm) was obtained by SPEs 2 following by short-range ionic transport results based on dielectric properties depending on frequency. SPEs with LiClO4 addition are electrochemically stable over 2 V in lithium battery coin cells from LSV results.

Probing the Fast Lithium-Ion Transport in Small-Molecule Solid Polymer Electrolytes by Solid-State NMR

2020 ◽  
Vol 53 (22) ◽  
pp. 10078-10085
Author(s):  
Xiaobin Fu ◽  
Yiyang Liu ◽  
Wei Wang ◽  
Ling Han ◽  
Jing Yang ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Small Molecule ◽  
Polymer Electrolytes ◽  
Solid State Nmr ◽  
Lithium Ion ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer
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