Reaction of nitric oxide molecules on transition-metal-doped silver cluster cations: Size- and dopant-dependent reaction pathways

2021 ◽  
Author(s):  
Masashi Arakawa ◽  
Masataka Horioka ◽  
Kento Minamikawa ◽  
Tomoki Kawano ◽  
Akira Terasaki
Keyword(s):  
Nitric Oxide ◽  
Transition Metal ◽  
Gas Phase ◽  
Silver Cluster ◽  
Reaction Pathways ◽  
Metal Doped ◽  
Ni Clusters

We report size- and dopant-dependent reaction pathways as well as reactivity of gas-phase free AgnM+ (M = Sc–Ni) clusters interacting with NO. Reactivity of AgnM+, except for M = Cr...

Nitric Oxide as an Electron Donor, an Atom Donor, an Atom Acceptor, and a Ligand in Reactions with Atomic Transition-Metal and Main-Group Cations in the Gas Phase

2005 ◽  
Vol 109 (49) ◽  
pp. 11224-11235 ◽  
Author(s):  
Voislav Blagojevic ◽  
Eric Flaim ◽  
Michael J. Y. Jarvis ◽  
Gregory K. Koyanagi ◽  
Diethard K. Bohme
Keyword(s):  
Nitric Oxide ◽  
Transition Metal ◽  
Gas Phase ◽  
Electron Donor ◽  
Main Group ◽  
Atomic Transition

Reactions of Hydrated Singly Charged First-Row Transition-Metal Ions M+(H2O)n(M=V, Cr, Mn, Fe, Co, Ni, Cu, and Zn) toward Nitric Oxide in the Gas Phase

2013 ◽  
Vol 19 (11) ◽  
pp. 3741-3750 ◽  
Author(s):  
Christian van der Linde ◽  
Robert F. Höckendorf ◽  
O. Petru Balaj ◽  
Martin K. Beyer
Keyword(s):  
Nitric Oxide ◽  
Transition Metal ◽  
Metal Ions ◽  
Gas Phase ◽  
Transition Metal Ions ◽  
Singly Charged ◽  
Cu And Zn

The effect of partial exchange of sulphonated macroporous styrene-divinylbenzene copolymers for different ions on their catalytic activity

1981 ◽  
Vol 46 (10) ◽  
pp. 2354-2363 ◽  
Author(s):  
Svatomír Kmošták ◽  
Karel Setínek
Keyword(s):  
Catalytic Activity ◽  
Transition Metal ◽  
Metal Ions ◽  
Gas Phase ◽  
Transition Metal Ions ◽  
Exchange Capacity ◽  
Total Exchange Capacity ◽  
Styrene Divinylbenzene ◽  
Na Ions ◽  
Type Of Transition

The catalytic activity of sulphonated macroporous styrene-divinylbenzene copolymers, the exchange capacity of which was neutralized from 30, 50 and 80% by Fe(III) ions and from 30% by Na ions and that of Wofatit Y-37 ion exchanger neutralized from 10% of its total exchange capacity by several transition metal ions and by sodium has been studied in isomerisation of cyclohexene and dehydration of 1-propanol in the gas phase at 130 °C. It was demonstrated that in both reactions transition metal ions exhibit additional effect to the expected neutralization of the polymer acid groups. In the case of cyclohexene isomerization, this effect depends on the degree of crosslinking of polymer mass of the catalyst. Such dependence has not been, however, observed in dehydration of 1-propanol. The type of transition metal ions did not exhibit any significant effect on the catalytic activity of the polymer catalysts studied.

Superatomic properties of transition-metal-doped tetrahexahedral lithium clusters: TM@Li14

2019 ◽  
Vol 118 (2) ◽  
pp. e1592256 ◽  
Author(s):  
Lijuan Yan ◽  
Jun Liu ◽  
Jianmei Shao
Keyword(s):  
Transition Metal ◽  
Metal Doped ◽  
Lithium Clusters
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