Directed Gas-Phase Preparation of the Elusive Phosphinosilylidyne (SiPH2, X2A’’) and Cis/Trans Phosphinidenesilyl (HSiPH; X2A’) Radicals Under Single-Collision Conditions

2021 ◽  
Author(s):  
Chao He ◽  
Shane Joseph Goettl ◽  
Zhenghai Yang ◽  
Srinivas Doddipatla ◽  
Ralf I. Kaiser ◽  
...  
Keyword(s):  
Gas Phase ◽  
Molecular Beams ◽  
Experimental Results ◽  
Single Collision ◽  
Crossed Molecular Beams

The reaction of the D1-silylidyne radical (SiD; X2Π) with phosphine (PH3; X1A1) was conducted in a crossed molecular beams machine under single collision conditions. Merging of the experimental results with...

Gas-Phase Synthesis of Boronylallene (H2CCCH(BO)) under Single Collision Conditions: A Crossed Molecular Beams and Computational Study

2014 ◽  
Vol 118 (21) ◽  
pp. 3810-3819 ◽  
Author(s):  
Surajit Maity ◽  
Dorian S. N. Parker ◽  
Ralf I. Kaiser ◽  
Brad Ganoe ◽  
Stefan Fau ◽  
...  
Keyword(s):  
Gas Phase ◽  
Computational Study ◽  
Molecular Beams ◽  
Phase Synthesis ◽  
Single Collision ◽  
Gas Phase Synthesis ◽  
Crossed Molecular Beams

A combined crossed molecular beams and ab initio investigation on the formation of vinylsulfidoboron (C2H311B32S)

2014 ◽  
Vol 16 (33) ◽  
pp. 17580-17587 ◽  
Author(s):  
Tao Yang ◽  
Beni B. Dangi ◽  
Dorian S. N. Parker ◽  
Ralf I. Kaiser ◽  
Yi An ◽  
...  
Keyword(s):  
Ab Initio ◽  
Gas Phase ◽  
Phase Formation ◽  
Molecular Beams ◽  
Single Collision ◽  
Crossed Molecular Beams

Bimolecular gas phase formation of vinylsulfidoboron (C2H311B32S) under single collision conditions.

scholarly journals A combined crossed molecular beams and computational study on the formation of distinct resonantly stabilized C5H3 radicals via chemically activated C5H4 and C6H6 intermediates

2018 ◽  
Vol 20 (16) ◽  
pp. 10906-10925 ◽  
Author(s):  
Aaron M. Thomas ◽  
Michael Lucas ◽  
Long Zhao ◽  
Jerid Liddiard ◽  
Ralf I. Kaiser ◽  
...  
Keyword(s):  
Computational Study ◽  
Molecular Beams ◽  
Single Collision ◽  
Crossed Molecular Beams

In a single-collision environment dicarbon reacts with 1-butyne to form resonantly stabilized C5H3 radical products.

A Chemical Dynamics Study of the Reaction of the Methylidyne Radical (CH, X2Π) with Dimethylacetylene (CH3CCCH3, X1A1g)

2021 ◽  
Author(s):  
Chao He ◽  
Kazuumi Fujioka ◽  
Anatoliy A Nikolayev ◽  
Long Zhao ◽  
Srinivas Doddipatla ◽  
...  
Keyword(s):  
Gas Phase ◽  
Collision Energy ◽  
Experimental Results ◽  
Phase Reaction ◽  
Chemical Dynamics ◽  
Single Collision ◽  
Gas Phase Reaction

The gas-phase reaction of the methylidyne (CH; X2Π) radical with dimethylacetylene (CH3CCCH3; X1A1g) was studied at a collision energy of 20.6 kJ mol-1 under single collision conditions with experimental results...

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