scholarly journals An insight into thermal stability of DNA in hydrated ionic liquids from multi-wavelengths UV Resonance Raman experiments

Author(s):  
Barbara Rossi ◽  
Mariagrazia Tortora ◽  
Sara Catalini ◽  
Jacopo Vigna ◽  
Ines Mancini ◽  
...  

The utility of Ionic liquids (ILs) as alternative solvents for stabilizing and preserving for a long time the native structure of DNA may be envisaged for biotechnological and biomedical applications...

2013 ◽  
Vol 25 (8) ◽  
pp. 4779-4782 ◽  
Author(s):  
W.D. Liang ◽  
H.F. Li ◽  
G.J. Gou ◽  
A.Q. Wang

Author(s):  
Yong Huang ◽  
Zhichao Chen ◽  
Jacob M. Crosthwaite ◽  
Sudhir N.V.K. Aki ◽  
Joan F. Brennecke

2017 ◽  
Vol 656 ◽  
pp. 70-84 ◽  
Author(s):  
D. Blanco ◽  
P. Oulego ◽  
D. Ramos ◽  
B. Fernández ◽  
J.M. Cuetos

ARKIVOC ◽  
2012 ◽  
Vol 2012 (8) ◽  
pp. 262-281 ◽  
Author(s):  
Paweł Borowiecki ◽  
Marcin Poterała ◽  
Jan Maurin ◽  
Monika Wielechowska ◽  
Jan Plenkiewicz

2016 ◽  
Vol 86 (6) ◽  
pp. 1314-1318 ◽  
Author(s):  
L. I. Voronchikhina ◽  
O. E. Zhuravlev ◽  
N. V. Verolainen ◽  
N. I. Krotova

Molecules ◽  
2019 ◽  
Vol 24 (19) ◽  
pp. 3571
Author(s):  
Andrea Mezzetta ◽  
Lorenzo Poderelli ◽  
Felicia D’Andrea ◽  
Christian Silvio Pomelli ◽  
Cinzia Chiappe ◽  
...  

New thiol-functionalized carboxylate ionic liquids (ILs), varying both for the cation and for the anion structures, have been prepared as new potential redox switching systems by reacting either 3-mercapto propionic acid (3-MPA) or N-acetyl-cysteine (NAC) with commercially available methyl carbonate ILs. Different ratios of thiol/disulfide ILs were obtained depending both on the acid employed in the neutralization reaction and on the reaction conditions used. Surprisingly, the imidazolium ILs displayed limited thermal stability which resulted in the formation of an imidazole 2-thione and a new sulfide ionic liquid. Conversely, the formation of the imidazole 2-thione was not observed when phosphonium disulfide ILs were heated, thus confirming the involvement of the imidazolium ring in an unexpected side reaction. An insight into the mechanism of the decomposition has been provided by means of DFT calculations.


2015 ◽  
Vol 220-221 ◽  
pp. 218-223
Author(s):  
Tomasz Jan Kaldonski ◽  
Stanislaw Cudzilo

Some results of tests of the thermal stability (and volatility) of selected ionic liquids pondered as lubricating substances in comparison with typical lubricating, mineral and synthetic oils, are presented in the article. The research was carried out within the framework of PBR/15–249/2007/WAT–OR00002904 Research Project Financed by the Ministry of Science and Higher Education, during 2007–2011 [1]. The obtained results confirmed high thermal resistance of ionic liquids. It makes it possible to use the liquids as high temperature lubricating substances. At the same time, it has been stated that the thermal resistance of ionic liquids depends on the composition and chemical structure of anion and cation.


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