scholarly journals DFT Benchmark Studies on Representative Species and Poisons of Methane Steam Reforming on Ni(111)

2021 ◽  
Author(s):  
Sai Sharath Yadavalli ◽  
Glenn Jones ◽  
Michail Stamatakis
Keyword(s):  
Steam Reforming ◽  
Graphitic Carbon ◽  
Methane Steam Reforming ◽  
Ni Catalysts ◽  
Methane Steam ◽  
Representative Species ◽  
Industrial Operations ◽  
Major Impediment ◽  
Carbon Based

Ni catalysts used in Methane Steam Reforming (MSR) are highly susceptible to poisoning by carbon-based species, which poses a major impediment to the productivity of industrial operations. These graphitic carbon-like...

Methane steam reforming for hydrogen production using low water-ratios without carbon formation over ceria coated Ni catalysts

2008 ◽  
Vol 345 (2) ◽  
pp. 119-127 ◽  
Author(s):  
Jiahui Xu ◽  
Connie M.Y. Yeung ◽  
Jun Ni ◽  
Frederic Meunier ◽  
Nadia Acerbi ◽  
...  
Keyword(s):  
Hydrogen Production ◽  
Steam Reforming ◽  
Methane Steam Reforming ◽  
Carbon Formation ◽  
Ni Catalysts ◽  
Methane Steam

Fabrication of Ce-Promoted Ni/Al2O3 Methane Steam Reforming Catalysts by Impregnation

2020 ◽  
Vol 20 (7) ◽  
pp. 4327-4330
Author(s):  
Ye Sol Lim ◽  
Min-Jin Lee ◽  
Kyoung-Jin Lee ◽  
Sangjin Lee ◽  
Haejin Hwang
Keyword(s):  
Particle Size ◽  
Microstructural Evolution ◽  
Steam Reforming ◽  
Carbon Deposition ◽  
Methane Steam Reforming ◽  
Ni Catalysts ◽  
Good Dispersion ◽  
Methane Steam ◽  
Reforming Catalysts ◽  
Steam Reforming Catalysts

CeO2-promoted Ni/Al2O3 catalysts were fabricated by impregnation. The effects of the CeO2 promotion and impregnation order on the microstructural evolution and catalytic durability were investigated for methane steam reforming. The CeO2-promoter nanoparticles resulted in good dispersion and reduced particle size of Ni catalysts. The enhanced durability of CeO2-promoted Ni/Al2O3 catalysts might be associated with the depression of carbon deposition by the presence of CeO2-promoter nanoparticles.

scholarly journals Ni catalysts with Mo promoter for methane steam reforming

Fuel ◽  
2009 ◽  
Vol 88 (9) ◽  
pp. 1547-1553 ◽  
Author(s):  
S.S. Maluf ◽  
E.M. Assaf
Keyword(s):  
Steam Reforming ◽  
Methane Steam Reforming ◽  
Ni Catalysts ◽  
Methane Steam

Ni-Catalysts Supported on Gd-Doped Ceria for Solid Oxide Fuel Cells in Methane Steam Reforming

2014 ◽  
Vol 37 (2) ◽  
pp. 343-348 ◽  
Author(s):  
Maria Luiza Andrade ◽  
Lindaura Almeida ◽  
Maria do Carmo Rangel ◽  
Francisco Pompeo ◽  
Nora Nichio
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Steam Reforming ◽  
Solid Oxide ◽  
Methane Steam Reforming ◽  
Doped Ceria ◽  
Oxide Fuel ◽  
Ni Catalysts ◽  
Methane Steam

Ultra-Low Amounts of Palladium (0.005-0.05 Wt% Pd) Supported on Titania: Remarkable Low-Temperature Activity for NO Reduction with CO and Structure-Function Property Relationships in Methane Oxidation

2020 ◽  
Author(s):  
Konstantin Khivantsev ◽  
Libor Kovarik ◽  
Nicholas R. Jaegers ◽  
János Szanyi ◽  
Yong Wang
Keyword(s):  
Nitric Oxide ◽  
Carbon Monoxide ◽  
Methane Oxidation ◽  
Steam Reforming ◽  
Methane Steam Reforming ◽  
Oxide Reduction ◽  
Water Steam ◽  
Methane Steam ◽  
Anatase Titania ◽  
Nitric Oxide Reduction

<p>Atomically dispersed Pd +2 cations with ultra-dilute loading of palladium (0.005-0.05 wt%) were anchored on anatase titania and characterized with FTIR, microscopy and catalytic tests. CO infrared adsorption produces a sharp, narrow mono-carbonyl Pd(II)-CO band at ~2,130 cm<sup>-1</sup> indicating formation of highly uniform and stable Pd+2 ions on anatase titania. The 0.05 wt% Pd/TiO<sub>2</sub> sample was evaluated for methane combustion under dry and wet (industrially relevant) conditions in the presence and absence of carbon monoxide. Notably, we find the isolated palladium atoms respond dynamically upon oxygen concentration modulation (switching-on and switching off). When oxygen is removed from the wet methane stream, palladium ions are reduced to metallic state by methane and catalyze methane steam reforming instead of complete methane oxidation. Re-admission of oxygen restores Pd<sup>+2</sup> cations and switches off methane steam reforming activity. Moreover, 0.05 wt% Pd/TiO<sub>2</sub> is a competent CO oxidation catalyst in the presence of water steam with 90% CO conversion and TOF ~ 4,000 hr<sup>-1</sup> at 260 ⁰C. </p><p>More importantly, we find that diluting 0.05 wt% Pd/titania sample with titania to ultra-low 0.005 wt% palladium loading produces a remarkably active material for nitric oxide reduction with carbon monoxide under industrially relevant conditions with >90% conversion of nitric oxide at 180 ⁰C (~460 ppm NO and 150 L/g*hr flow rate in the presence of >2% water steam) and TOF ~6,000 hr<sup>-1</sup>. Pd thus outperforms state-of-the-art rhodium containing catalysts with (15-20 times higher rhodium loading; rhodium is ~ 3 times more expensive than palladium). Furthermore, palladium catalysts are more selective towards nitrogen and produce significantly less ammonia relative to the more traditional rhodium catalysts due to lower Pd amount nd lower water-gas-shift activity. Our study is the first example of utilizing ultra-low (0.05 wt% and less) noble metal (Pd) amounts to produce heterogeneous catalysts with extraordinary activity for nitric oxide reduction. This opens up a pathway to study other Pd, Pt and Rh containing materials with ultra-low loadings of expensive noble metals dispersed on titania or titania-coated oxides for industrially relevant nitric oxide abatement.</p>

scholarly journals Retraction: Computational fluid dynamics modeling of the millisecond methane steam reforming in microchannel reactors for hydrogen production

RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12531-12531
Author(s):  
Junjie Chen ◽  
Xuhui Gao ◽  
Longfei Yan ◽  
Deguang Xu
Keyword(s):  
Fluid Dynamics ◽  
Computational Fluid Dynamics ◽  
Hydrogen Production ◽  
Steam Reforming ◽  
Methane Steam Reforming ◽  
Dynamics Modeling ◽  
Computational Fluid Dynamics Modeling ◽  
Microchannel Reactors ◽  
Methane Steam

Retraction of ‘Computational fluid dynamics modeling of the millisecond methane steam reforming in microchannel reactors for hydrogen production’ by Junjie Chen et al., RSC Adv., 2018, 8, 25183–25200, DOI: 10.1039/C8RA04440F.

scholarly journals Methane steam reforming at low steam-to-carbon ratio: The effect of Y doping in Rh substituted lanthanum zirconates

2020 ◽  
Vol 606 ◽  
pp. 117802
Author(s):  
Yan Zhou ◽  
Daniel Haynes ◽  
John Baltrus ◽  
Amitava Roy ◽  
Dushyant Shekhawat ◽  
...  
Keyword(s):  
Steam Reforming ◽  
Methane Steam Reforming ◽  
Methane Steam
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