Guanidine as a strong CO2 adsorbent: A DFT study on cooperative CO2 adsorption

Author(s):  
Sebastian Anila ◽  
Cherumuttathu Hariharan Suresh

Among the various carbon capture and storage (CCS) technologies, direct air capture (DAC) of CO2 by engineered chemical reactions on suitable adsorbents has attained more attention in recent times. Guanidine...

Author(s):  
Sabine Fuss

The 2°C target for global warming had been under severe scrutiny in the run-up to the climate negotiations in Paris in 2015 (COP21). Clearly, with a remaining carbon budget of 470–1,020 GtCO2eq from 2015 onwards for a 66% probability of stabilizing at concentration levels consistent with remaining below 2°C warming at the end of the 21st century and yearly emissions of about 40 GtCO2 per year, not much room is left for further postponing action. Many of the low stabilization pathways actually resort to the extraction of CO2 from the atmosphere (known as negative emissions or Carbon Dioxide Removal [CDR]), mostly by means of Bioenergy with Carbon Capture and Storage (BECCS): if the biomass feedstock is produced sustainably, the emissions would be low or even carbon-neutral, as the additional planting of biomass would sequester about as much CO2 as is generated during energy generation. If additionally carbon capture and storage is applied, then the emissions balance would be negative. Large BECCS deployment thus facilitates reaching the 2°C target, also allowing for some flexibility in other sectors that are difficult to decarbonize rapidly, such as the agricultural sector. However, the large reliance on BECCS has raised uneasiness among policymakers, the public, and even scientists, with risks to sustainability being voiced as the prime concern. For example, the large-scale deployment of BECCS would require vast areas of land to be set aside for the cultivation of biomass, which is feared to conflict with conservation of ecosystem services and with ensuring food security in the face of a still growing population.While the progress that has been made in Paris leading to an agreement on stabilizing “well below 2°C above pre-industrial levels” and “pursuing efforts to limit the temperature increase to 1.5°C” was mainly motivated by the extent of the impacts, which are perceived to be unacceptably high for some regions already at lower temperature increases, it has to be taken with a grain of salt: moving to 1.5°C will further shrink the time frame to act and BECCS will play an even bigger role. In fact, aiming at 1.5°C will substantially reduce the remaining carbon budget previously indicated for reaching 2°C. Recent research on the biophysical limits to BECCS and also other negative emissions options such as Direct Air Capture indicates that they all run into their respective bottlenecks—BECCS with respect to land requirements, but on the upside producing bioenergy as a side product, while Direct Air Capture does not need much land, but is more energy-intensive. In order to provide for the negative emissions needed for achieving the 1.5°C target in a sustainable way, a portfolio of negative emissions options needs to minimize unwanted effects on non–climate policy goals.


2013 ◽  
Vol 744 ◽  
pp. 392-395 ◽  
Author(s):  
Hao Xian Malcolm Chan ◽  
Eng Hwa Yap ◽  
Jee Hou Ho

Carbon Capture and Storage (CCS) is one of the global leading methods that could potentially retard the speed of climate change. However, CCS on point sources can only slowdown the rate of increase of atmospheric CO2 concentration. In order to mitigate CO2 released by previous emissions, a more proactive alternative is proposed where CO2 is directly extracted and captured from air Direct Air Capture (DAC). This paper presents a technical overview from our current research of a novel DAC concept which features a phase of axial compression to adapt pre-capture atmospheric air to a level suitable for carbon capture. Also detailed in the paper is the feasibility study addressing several key issues: the energy consumption and overall capturing efficiency of the proposed DAC system.


Materials ◽  
2019 ◽  
Vol 12 (13) ◽  
pp. 2088 ◽  
Author(s):  
Elizabeth Rodriguez Acevedo ◽  
Farid B. Cortés ◽  
Camilo A. Franco ◽  
Francisco Carrasco-Marín ◽  
Agustín F. Pérez-Cadenas ◽  
...  

The implementation of carbon capture and storage process (CCS) has been unsuccessful to date, mainly due to the technical issues and high costs associated with two main stages: (1) CO2 separation from flue gas and (2) CO2 injection in deep geological deposits, more than 300 m, where CO2 is in supercritical conditions. This study proposes, for the first time, an enhanced CCS process (e-CCS), in which the stage of CO2 separation is removed and the flue gas is injected directly in shallow reservoirs located at less than 300 m, where the adsorptive phenomena control CO2 storage. Nitrogen-rich carbon nanospheres were used as modifying agents of the reservoir porous texture to improve both the CO2 adsorption capacity and selectivity. For this purpose, sandstone was impregnated with a nanofluid and CO2 adsorption was evaluated at different pressures (atmospheric pressure and from 3 × 10−3 MPa to 3.0 MPa) and temperatures (0, 25, and 50 °C). As a main result, a mass fraction of only 20% of nanomaterials increased both the surface area and the molecular interactions, so that the increase of adsorption capacity at shallow reservoir conditions (50 °C and 3.0 MPa) was more than 677 times (from 0.00125 to 0.9 mmol g−1).


2007 ◽  
Vol 25 (5) ◽  
pp. 357-392 ◽  
Author(s):  
Havva Balat ◽  
Cahide Öz

This article deals with review of technical and economic aspects of Carbon Capture and Storage. Since the late 1980s a new concept is being developed which enables to make use of fossil fuels with a considerably reduced emission of carbon dioxide to the atmosphere. The concept is often called ‘Carbon Capture and Storage’ (CCS). CCS technologies are receiving increasing attention, mainly for their potential contribution to the optimal mitigation of carbon dioxide emissions that is intended to avoid future, dangerous climate change. CCS technologies attract a lot of attention because they could allow “to reduce our carbon dioxide emissions to the atmosphere whilst continuing to use fossil fuels”. CCS is not a completely new technology, e.g., the United States alone is sequestering about 8.5 MtC for enhanced oil recovery each year. Today, CCS technologies are widely recognised as an important means of progress in industrialized countries.


2018 ◽  
Author(s):  
Chelsey Bryson

In 2015, the historic Paris Agreement set a global goal of limiting warming to “well below 2 degrees” through a robust, country-driven framework. Unfortunately, just two years later, it is increasingly clear that the global community is not on track to meet this objective. This is evidenced by recent studies projecting that temperatures may increase by between 2.7-3.7°C by 2100, and continue to rise for many centuries thereafter given inertia in the climatic system.1 Further, the IPCC is increasingly including Negative Emissions Technology (NETs) in their models in order to achieve the 2-degree target. While many hear the term ‘CDR’ and think of Bioenergy and Carbon Capture and Storage (BECCS) or Direct Air Capture (DAC), blue carbon is a lesser-known but low-cost and effective CDR option that can help meet the goals set out in Paris.


2013 ◽  
Vol 869-870 ◽  
pp. 967-970 ◽  
Author(s):  
Chao Huang ◽  
Xiao Qin Li ◽  
Li Fei Chen

This paper studies the effect of policy incentives on investment strategies of carbon capture and storage (CCS) technologies. We establish CCS investment models based on real options theory for investment value evaluation of CCS, which consider CO2price, policy incentives and different CCS technologies that include the old existing CCS technology and the new one. We evaluate CCS investment option values and calculate the change of CCS investment values and thresholds due to the variation of CO2price and policy incentives. We conclude that the optimal strategy is investing in the new CCS technology when there are enough policy incentives, otherwise, it is optimal to firstly invest in the old existing CCS technology and then upgrade to the new one.


2017 ◽  
Vol 61 (4) ◽  
pp. 143-148 ◽  
Author(s):  
J. Poláčková ◽  
J. Petrů ◽  
M. Janák ◽  
J. Berka ◽  
A. Krausová

Abstract Carbon Capture and Storage (CCS) technologies are a perspective solution to reduce the amount of CO2 emissions. One of promising methods is Ca-looping, which is based on carbonation and calcination reactions. During both of these processes, especially calcination, high temperatures (650-950°C) are required. This means high demands on the corrosion resistance of equipment materials. Therefore, we carried out a study to suggest materials with suitable properties for calciner construction, which have to be particularly heat resistant: stainless steels (AISI 304, AISI 316L and AISI 316Ti) and nickel alloys (Inconel 713, Inconel 738, Incoloy 800H). A special device simulating calciner environment was built for this purpose. Chosen materials were tested in temperature 900°C, atmospheric pressure and gaseous environment with composition that can be possible in a calciner. The surfaces of materials were evaluated to determine composition and properties of formed oxide layers. High temperature oxidation was observed on all tested materials and oxide exfoliation occurred on some of tested materials (304, 316L).


2013 ◽  
Vol 1523 ◽  
Author(s):  
Michael Fernandez ◽  
Tom D Daff ◽  
Nicholas R. Trefiak ◽  
Tom K. Woo

ABSTRACTNanoporous metal-organic framework (MOF) materials are strong candidates for energy efficient carbon capture and storage (CCS) technologies. A total of ∼20,000 hypothetical MOFs were ab initio screened for CO2 adsorption using grand canonical Monte-Carlo (GCMC) simulations. Novel radial distribution function (RDF) scores were modified for periodic systems to predict the CO2 adsorption of MOFs using chemoinformatic models. The test set predictions yielded accuracies of 0.76 and 0.85 at 0.1 bar and 1 bar, respectively. The models were used to screen a large database for high performing MOFs and the top 100 structures were successfully validated by GCMC simulations. The chemoinformatic predictors of the CO2 adsorption of MOFs are available online at http://titan.chem.uottawa.ca/woolab/MOFIA/#carbondioxide.


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