Polymer-directed Crystallization of HMX to Construct Nano-/Microstructured Aggregates with Tunable Polymorph and Microstructure

CrystEngComm ◽  
2021 ◽  
Author(s):  
Xin Zhou ◽  
Yan Ren ◽  
Hongzhen Li ◽  
Xiaoqin Zhou ◽  
Shilong Hao ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Structural Control ◽  
High Stability ◽  
Polyvinyl Pyrrolidone ◽  
Directed Crystallization ◽  
Unique Combination ◽  
Length Scales ◽  
Multiple Length Scales ◽  
Low Sensitivity

The nano-/microstructured energetic materials (EMs) often display a unique combination of low-sensitivity and high-stability, but their structural control across multiple-length scales has proven difficult. Here, a polyvinyl pyrrolidone (PVP) polymer-directed...

scholarly journals Multiscale structural control of linked metal–organic polyhedra gel by aging-induced linkage-reorganization

2021 ◽  
Vol 12 (38) ◽  
pp. 12556-12563
Author(s):  
Zaoming Wang ◽  
Christian Villa Santos ◽  
Alexandre Legrand ◽  
Frederik Haase ◽  
Yosuke Hara ◽  
...  
Keyword(s):  
Structural Control ◽  
Aging Process ◽  
Length Scales ◽  
Multiple Length Scales ◽  
Metal Organic

By a controlled post-synthetic aging process, we demonstrate a protocol to induce the linkage reorganization in metal–organic polyhedra-linked gel networks, leading to the control of gel structures over multiple length scales and their properties.

scholarly journals Molecular Dynamics Simulation of the Influence of RDX Internal Defects on Sensitivity

Crystals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 329
Author(s):  
Pengmin Yan ◽  
Xue Zhao ◽  
Jiuhou Rui ◽  
Juan Zhao ◽  
Min Xu ◽  
...  
Keyword(s):  
Energetic Materials ◽  
Low Cost ◽  
Relative Sensitivity ◽  
Dynamics Simulation ◽  
Safety Properties ◽  
Internal Defects ◽  
X Ray ◽  
X Ray Computed ◽  
Low Sensitivity ◽  
Higher Sensitivity

The internal defect is an important factor that could influence the energy and safety properties of energetic materials. RDX samples of two qualities were characterized and simulated to reveal the influence of different defects on sensitivity. The internal defects were characterized with optical microscopy, Raman spectroscopy and microfocus X-ray computed tomography technology. The results show that high-density RDX has fewer defects and a more uniform distribution. Based on the characterization results, defect models with different defect rates and distribution were established. The simulation results show that the models with fewer internal defects lead to shorter N-NO2 maximum bond lengths and greater cohesive energy density (CED). The maximum bond length and CED can be used as the criterion for the relative sensitivity of RDX, and therefore defect models doped with different solvents are established. The results show that the models doped with propylene carbonate and acetone lead to higher sensitivity. This may help to select the solvent to prepare low-sensitivity RDX. The results reported in this paper are aiming at the development of a more convenient and low-cost method for studying the influence of internal defects on the sensitivity of energetic materials.

Fracture resistance of human cortical bone across multiple length-scales at physiological strain rates

Biomaterials ◽  
2014 ◽  
Vol 35 (21) ◽  
pp. 5472-5481 ◽  
Author(s):  
Elizabeth A. Zimmermann ◽  
Bernd Gludovatz ◽  
Eric Schaible ◽  
Björn Busse ◽  
Robert O. Ritchie
Keyword(s):  
Cortical Bone ◽  
Fracture Resistance ◽  
Strain Rates ◽  
Physiological Strain ◽  
Length Scales ◽  
Human Cortical Bone ◽  
Multiple Length Scales

Patterning of Soft Matter across Multiple Length Scales

2016 ◽  
Vol 26 (16) ◽  
pp. 2609-2616 ◽  
Author(s):  
Pim van der Asdonk ◽  
Hans C. Hendrikse ◽  
Marcos Fernandez-Castano Romera ◽  
Dion Voerman ◽  
Britta E. I. Ramakers ◽  
...  
Keyword(s):  
Soft Matter ◽  
Length Scales ◽  
Multiple Length Scales

Surface integrity analysis of machined Inconel 718 over multiple length scales

CIRP Annals ◽  
2012 ◽  
Vol 61 (1) ◽  
pp. 99-102 ◽  
Author(s):  
Rachid M'Saoubi ◽  
Tommy Larsson ◽  
José Outeiro ◽  
Yang Guo ◽  
Sergey Suslov ◽  
...  
Keyword(s):  
Surface Integrity ◽  
Inconel 718 ◽  
Length Scales ◽  
Multiple Length Scales ◽  
Integrity Analysis

An Energetic Approach to Modeling Cytoskeletal Architecture in Maturing Cardiomyocytes

2021 ◽  
Author(s):  
William F Sherman ◽  
Mira Asad ◽  
Anna Grosberg
Keyword(s):  
Cardiac Tissue ◽  
Length Scales ◽  
Functional Changes ◽  
Physical Constraints ◽  
Scale Parameters ◽  
Structure And Dynamics ◽  
Energetic Approach ◽  
Cytoskeletal Network ◽  
Multiple Length Scales ◽  
Potential Factors

Abstract Through a variety of mechanisms, a healthy heart is able to regulate its structure and dynamics across multiple length scales. Disruption of these mechanisms can have a cascad- ing effect, resulting in severe structural and/or functional changes that permeate across different length scales. Due to this hierarchical structure, there is interest in understand- ing how the components at the various scales coordinate and influence each other. However, much is unknown regarding how myofibril bundles are organized within a densely packed cell and the influence of the subcellular components on the architecture that is formed. To elucidate potential factors influencing cytoskeletal development, we proposed a compu- tational model that integrated interactions at both the cel- lular and subcelluar scale to predict the location of indi- vidual myofibril bundles that contributed to the formation of an energetically favorable cytoskeletal network. Our model was tested and validated using experimental metrics derived from analyzing single cell cardiomyocytes. We demonstrated that our model-generated networks were capable of repro- ducing the variation observed in experimental cells at different length scales as a result of the stochasticity inher- ent in the different interaction between the various cellu- lar components. Additionally, we showed that incorporat- ing length-scale parameters resulted in physical constraints that directed cytoskeletal architecture towards a structurally consistent motif. Understanding the mechanisms guiding the formation and organization of the cytoskeleton in individual cardiomyocytes can aid tissue engineers towards developing functional cardiac tissue.

scholarly journals 4D and In Situ X-ray Microscopy for Studying Damage Evolution in Materials Across Multiple Length Scales

2018 ◽  
Vol 24 (S1) ◽  
pp. 1010-1011
Author(s):  
Will Harris ◽  
Hrishikesh Bale ◽  
Steve Kelly ◽  
Benjamin Hornberger
Keyword(s):  
Damage Evolution ◽  
Length Scales ◽  
X Ray ◽  
Multiple Length Scales
Sign in / Sign up

Export Citation Format

Share Document