A ratiometric fluorescent sensor of a terbium coordination polymer for the anthrax biomarker 2,6-dipicolinic acid with on-site detection assisted by smartphone APP

CrystEngComm ◽  
2021 ◽  
Author(s):  
Miao-Miao Qiu ◽  
Ke-Fu Chen ◽  
Qi-Rui Liu ◽  
Wei-Ni Miao ◽  
Bing Liu ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Hydrothermal Reaction ◽  
Fluorescent Sensor ◽  
Dipicolinic Acid ◽  
Smartphone App ◽  
Anthrax Spores

2,6-Dipicolinic acid (DPA) is the biomarker of anthrax spores, whose detection is in great need. A hydrothermal reaction of 2,6-naphthalenedicarboxylic acid (H2NDBC) with Tb3+ gave out a terbium coordination polymer,...

A (4,4)-connected zinc(II) coordination polymer constructed with the flexible 2-carboxy phenoxyacetate ligand: synthesis, conformation alteration and fluorescent properties

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jun-Xia Li ◽  
Tian Zhang ◽  
He-Jun Chen ◽  
Zhong-Xiang Du
Keyword(s):  
Coordination Polymer ◽  
Hydrothermal Reaction ◽  
Layer Structure ◽  
Fluorescence Emission ◽  
Phenoxyacetic Acid ◽  
X Ray Diffraction ◽  
Fluorescent Properties ◽  
Sulfate Heptahydrate ◽  
X Ray ◽  
Related Compounds

Abstract A new binary ZnII coordination polymer, [Zn(2-cpa)(H2O)] n (2D-Zn) has been prepared by a 120 °C hydrothermal reaction of zinc(II) sulfate heptahydrate and 2-carboxy phenoxyacetic acid (2-H2cpa) in the presence of potassium hydroxide. Single-crystal X-ray diffraction analysis shows that the ZnII ion is located in a deformed ZnO6 octahedron bonded by one water and three 2-carboxy phenoxyacetate (2-cpa) ligands. The 2-cpa exhibits pentadentate double bridging chelate-μ 3 coordination mode and connects adjacent ZnII ions to generate a corrugated (4,4)-connected layer structure. The structures, conformation of 2-cpa and photoluminescence spectra for 2D-Zn have been carefully analyzed and compared with its two closely related compounds ̶ 1D [Zn(2-cpa)(H2O)] n (1D-Zn) and mononuclear [Zn(2-cpa)(H2O)3] (0D-Zn). The results showed that the conformation of 2-cpa in 2D-Zn has the maximum alteration and the corresponding fluorescence emission peak of 2D-Zn has the largest red-shift of 62 nm compared with that of free 2-H2cpa.

A novel 3D Zn-coordination polymer based on a multiresponsive fluorescent sensor demonstrating outstanding sensitivities and selectivities for the efficient detection of multiple analytes

2021 ◽  
Author(s):  
Yu Liu ◽  
Yan Wang ◽  
Xiao-Sa Zhang ◽  
Yu-Shu Sheng ◽  
Wen-Ze Li ◽  
...  
Keyword(s):  
Detection Limit ◽  
Coordination Polymer ◽  
Fluorescent Sensor ◽  
Lower Detection Limit ◽  
Ph Values ◽  
Efficient Detection ◽  
Wide Range ◽  
Lower Detection ◽  
Multiple Analytes

A Zn-CP exhibits remarkable fluorescence behaviours and stability in a wide range of pH values. It can become an outstanding candidate in the selective sensing of Fe3+, Mg2+, Cr2O72−, MnO4−, NB and NM at a lower detection limit.

Hydrothermal synthesis, crystal structure and properties of a two-dimensional uranyl coordination polymer based on a flexible zwitterionic ligand

2018 ◽  
Vol 74 (3) ◽  
pp. 366-371 ◽  
Author(s):  
Wen Cui ◽  
Ruyu Wang ◽  
Xi Shu ◽  
Yu Fan ◽  
Yang Liu ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Hydrothermal Reaction ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Uranyl Compounds ◽  
X Ray ◽  
Potential Applications ◽  
Ft Ir ◽  
Fuel Reprocessing ◽  
Ft Ir Spectroscopy

The interaction between the uranyl cation, (UO2)2+, and organic species is of interest due to the potential applications of the resulting compounds with regard to nuclear waste disposal and nuclear fuel reprocessing. The hydrothermal reaction of various uranyl compounds with flexible zwitterionic 1,1′-[1,4-phenylenebis(methylene)]bis(pyridin-1-ium-4-carboxylate) dihydrochloride (Bpmb·2HCl) in deionized water containing drops of H2SO4resulted in the formation of a novel two-dimensional uranyl coordination polymer, namely poly[tetraoxido{μ2-1,1′-[1,4-phenylenebis(methylene)]bis(pyridin-1-ium-4-carboxylate)}di-μ3-sulfato-diuranium(VI)], [(UO2)2(SO4)2(C20H16N2O4)]n, (1). Single-crystal X-ray diffraction reveals that this coordination polymer exhibits a layered arrangement and the (UO2)2+centre is coordinated by five equatorial O atoms. The structure was further characterized by FT–IR spectroscopy, powder X-ray diffraction (PXRD) and thermogravimetric analysis (TGA). The polymer shows high thermal stability up to 696 K. Furthermore, the photoluminescence properties of (1) has also been studied, showing it to exhibit a typical uranyl fluorescence.

A three-dimensional manganese(II) coordination polymer with two functional properties: magnetism and photochemical detection

2021 ◽  
Vol 77 (12) ◽  
Author(s):  
Dan Zhao ◽  
Yanyan An ◽  
Tingting Guo ◽  
Juanzhi Yan ◽  
Danmei Song
Keyword(s):  
Coordination Polymer ◽  
Hydrothermal Reaction ◽  
Three Dimensional ◽  
Building Blocks ◽  
Photoluminescence Properties ◽  
X Ray Diffraction ◽  
Detection Mechanism ◽  
Susceptibility Data ◽  
Dichromate Ions ◽  
Ditopic Ligand

Hydrothermal reaction of Mn2+ with the ditopic ligand 2,5-bis(1H-1,2,4-triazol-1-yl)benzoic acid (Hdtba) resulted in the complex poly[aqua[μ3-2,5-bis(1H-1,2,4-triazol-1-yl)benzoato-κ3 N 4:N 4′:O]chloridomanganese(II)] monohydrate], {[Mn(C11H7N6O2)Cl(H2O)]·H2O} n , (I). Coordination polymer I has been characterized by X-ray diffraction, IR spectroscopy, elemental analysis, thermogravimetry and susceptibility measurements. The topology of I corresponds to a three-dimensional (3,6)-conn net linked by {Mn2Cl2(COO)2} building blocks and dtba− anions. Significant antiferromagnetic exchange is observed within the dinuclear {Mn2Cl2(COO)2} subunits. A fit of the susceptibility data resulted in the magnetic parameters g = 1.93 and J = −1.52. Studies of the photoluminescence properties revealed that I represents a promising luminescence sensor for sensitively detecting dichromate ions in aqueous solution. The associated photochemical detection mechanism was studied in detail.

Ratiometric fluorescence determination of the anthrax biomarker 2,6-dipicolinic acid using a Eu3+/Tb3+-doped nickel coordination polymer

2019 ◽  
Vol 43 (46) ◽  
pp. 18259-18267 ◽  
Author(s):  
Hang Lei ◽  
Cui-Xing Qi ◽  
Xuan-Bo Chen ◽  
Tian Zhang ◽  
Ling Xu ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Dipicolinic Acid ◽  
High Sensitivity ◽  
Fluorescence Sensor ◽  
Rapid Response ◽  
Ratiometric Fluorescence ◽  
Fluorescence Determination

Tb3+0.6/Eu3+0.4@Ni-BTC is a quantitative ratiometric fluorescence sensor for DPA detection with high sensitivity, anti-interference, rapid response and durability.

A new three-dimensional coordination polymer of SrIIbased on dipicolinic acid, with different coordination environments for SrII

2014 ◽  
Vol 70 (6) ◽  
pp. 613-616
Author(s):  
Janet Soleimannejad ◽  
Zohreh Derikvand ◽  
Farzaneh Koleiae
Keyword(s):  
Coordination Polymer ◽  
Alkaline Earth ◽  
Dipicolinic Acid ◽  
Three Dimensional ◽  
Earth Metal ◽  
Alkaline Earth Metal ◽  
Asymmetric Unit ◽  
Uncoordinated Water Molecule ◽  
Coordination Framework ◽  
Trigonal Prismatic

A three-dimensional coordination polymer of SrIIbased on dipicolinic acid (pydcH2) has been synthesized and characterized, namely poly[[diaquabis(μ3-6-carboxypyridine-2-carboxylato)bis(μ4-pyridine-2,6-dicarboxylato)tristrontium(II)] dihydrate], {[Sr3(C7H3NO4)2(C7H4NO4)2(H2O)2]·2H2O}n. The asymmetric unit consists of two unique SrIIcentres (one of them situated on an inversion centre), two independent pydc2−ligands, and one coordinated and one uncoordinated water molecule. The two independent SrIIcations are surrounded by water and dipicolinate molecules in distorted square-antiprism and distorted tricapped trigonal prismatic geometries. The dipicolinate ligands adopt μ3- and μ4-bridging modes, linking the alkaline earth metal centres into a three-dimensional coordination framework. One dipicolinate ligand is doubly deprotonated, while the other is singly deprotonated.

A zinc(II) coordination polymer based on a flexible bis(benzimidazole) ligand: synthesis, crystal structure and fluorescence study

2020 ◽  
Vol 75 (12) ◽  
pp. 1005-1009
Author(s):  
Geng Zhang ◽  
Xinzhao Xia ◽  
Jianhua Xu ◽  
Lixian Xia ◽  
Cong Wang ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Hydrothermal Reaction ◽  
Emission Peak ◽  
Stacking Interactions ◽  
X Ray Diffraction ◽  
Fluorescence Study ◽  
One Dimensional ◽  
X Ray ◽  
Π Stacking ◽  
Solid State Fluorescence

AbstractA new one-dimensional Zn(II) coordination polymer, {[ZnCl2(BBM)]·CH3OH}n (2,2-(1,4-butanediyl)bis-1,3-benzimidazole [BBM]), has been obtained from the hydrothermal reaction of zinc chloride with the flexible bis-benzimidazole ligand BBM and characterized by single-crystal X-ray diffraction, elemental analysis, IR and UV–vis spectra. Structural analysis has revealed that the BBM ligand connects the Zn(II) atoms to form a square-wave chain, which is further extended into supramolecular layers through hydrogen bonds and π···π stacking interactions. Solid-state fluorescence investigations showed that the Zn(II) coordination polymer has an emission peak at 381 nm upon excitation at 330 nm, which is attributed to ligand-centered luminescence. It is only slightly red shifted as compared to the ligand but partially quenched due to the strong π···π stacking interactions.

A turn on fluorescent sensor based on lanthanide coordination polymer nanoparticles for the detection of mercury(ii) in biological fluids

RSC Advances ◽  
2016 ◽  
Vol 6 (22) ◽  
pp. 17811-17817 ◽  
Author(s):  
Qian Li ◽  
Chengjuan Wang ◽  
Hongliang Tan ◽  
Gonge Tang ◽  
Jie Gao ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Fluorescent Sensor ◽  
Biological Fluids ◽  
Polymer Nanoparticles ◽  
Turn On ◽  
Lanthanide Coordination Polymer

Im-quenched fluorescence of Eu/IPA CPNPs can be recovered upon the addition of Hg2+ through the formation of a Hg/Im complex.

Hydrothermal Synthesis, Crystal Structure and Properties of a 1DMetal- Organic Coordination Polymer {[Zn2(2,2´,3,3´-odpa)(py)3(H2O)]·H2O}n

2010 ◽  
Vol 65 (6) ◽  
pp. 674-678 ◽  
Author(s):  
Qi-Yao Li ◽  
Shang-Quan Zang ◽  
Jia-Bin Li ◽  
Hong-Wei Hou
Keyword(s):  
Coordination Polymer ◽  
Hydrothermal Reaction ◽  
Thermal Analyses ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Structure And Properties ◽  
Thermal Gravimetric ◽  
One Dimensional ◽  
Metal Organic ◽  
Thermal Stability Of

Hydrothermal reaction of Zn(NO3)2·6H2O with 2,2´,3,3´-oxydiphthalic acid (H4odpa) and pyridine (py) at 120 °C yielded a one-dimensional metal-organic coordination polymer {[Zn2(2,2´,3,3´- odpa)(py)3(H2O)]·H2O}n (1), which is further connected together through hydrogen bonds, π· · ·π and C−H· · ·π interactions to give a three-dimensional supramolecular network. The thermal stability of complex 1 was studied by thermal gravimetric (TG) and differential thermal analyses (DTA). Compound 1 exhibits photoluminescence with an emission maximum at ca. 430 nm upon excitation at 350 nm.

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