scholarly journals Reversed Crystal Growth of Metal Organic Framework MIL-68(In)

CrystEngComm ◽  
2021 ◽  
Author(s):  
Kirsty McRoberts ◽  
Wuzong Zhou
Keyword(s):  
Crystal Growth ◽  
Growth Mechanism ◽  
Metal Organic Framework ◽  
Crystal Growth Mechanism ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

An investigation of the crystal growth of metal organic framework MIL-68(In) under solvothermal conditions revealed a non-classical reversed crystal growth mechanism via a route of nanorods – orientated aggregation into...

scholarly journals Unveiling the mechanism of lattice-mismatched crystal growth of a core–shell metal–organic framework

2019 ◽  
Vol 10 (41) ◽  
pp. 9571-9575 ◽  
Author(s):  
Fajar I. Pambudi ◽  
Michael W. Anderson ◽  
Martin P. Attfield
Keyword(s):  
Crystal Growth ◽  
Epitaxial Growth ◽  
Real Time ◽  
Growth Mechanism ◽  
Metal Organic Framework ◽  
Core Shell ◽  
Metal Organic ◽  
Organic Framework

Real time microscopy reveals the nanoscopic epitaxial growth mechanism and form of a severely lattice-mismatched shell MOF in a core–shell MOF.

scholarly journals Crystal growth of the core and rotated epitaxial shell of a heterometallic metal-organic framework revealed with atomic force microscopy

2021 ◽  
Author(s):  
Fajar Inggit Pambudi ◽  
Michael William Anderson ◽  
Martin Attfield
Keyword(s):  
Atomic Force Microscopy ◽  
Crystal Growth ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Force Microscopy ◽  
The Core ◽  
Atomic Force ◽  
Metal Organic ◽  
Surface Crystal ◽  
Organic Framework

Atomic force microscopy has been used to determine the surface crystal growth of two isostructural metal-organic frameworks, [Zn2(ndc)2(dabco)] (ndc = 1,4-naphthalene dicarboxylate, dabco = 4-diazabicyclo[2.2.2]octane) (1) and [Cu2(ndc)2(dabco)] (2) from...

Li-based MOF-derived multifunctional PEO polymer solid-state electrolyte for lithium energy storage

2022 ◽  
Author(s):  
Xiang Han ◽  
Tiantian Wu ◽  
Lanhui Gu ◽  
Dian Tian
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Isophthalic Acid ◽  
Solid State Electrolyte ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework containing Li-oxygen clusters, namely {[Li2(IPA)]·DMF}n (1) (H2IPA = isophthalic acid), has been constructed under solvothermal conditions. The Li-based MOF can be applied to lithium energy...

Eu-MOF and its mixed-matrix membranes as fluorescent sensor for quantitative ratiometric pH and folic acid detection, and visible fingerprint identifying

2021 ◽  
Author(s):  
Yansong Jiang ◽  
Yating Huang ◽  
Xiangxiang Shi ◽  
Zijing Lu ◽  
Jiamo Ren ◽  
...  
Keyword(s):  
Folic Acid ◽  
Fluorescent Sensor ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Mixed Matrix Membranes ◽  
Tetracarboxylic Acid ◽  
Mixed Matrix ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

Here, we demonstrate the assembly of a new stable lanthanide-based metal-organic framework (MOF), Eu(HDPB)(phen) (1) (HDPB = (1,1ʹ:3ʹ,1ʹʹ-terphenyl)-3,3ʹʹ,5,5ʹʹ-tetracarboxylic acid, phen = 1,10-phenanthroline), with a three-dimensional framework under solvothermal conditions. 1...

Crystal growth of cyclodextrin-based metal-organic framework with inclusion of ferulic acid

2015 ◽  
Vol 50 (7) ◽  
pp. 556-559 ◽  
Author(s):  
Wataru Michida ◽  
Masato Ezaki ◽  
Mina Sakuragi ◽  
Guoqing Guan ◽  
Katsuki Kusakabe
Keyword(s):  
Crystal Growth ◽  
Ferulic Acid ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Novel Cerium Bisphosphinate Coordination Polymer and Unconventional Metal–Organic Framework

Crystals ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 303 ◽  
Author(s):  
Jan Rohlíček ◽  
Daniel Bůžek ◽  
Petr Brázda ◽  
Libor Kobera ◽  
Jan Hynek ◽  
...  
Keyword(s):  
Inorganic Chemistry ◽  
Crystal Structure ◽  
Electron Diffraction ◽  
Coordination Polymer ◽  
Specific Surface ◽  
Metal Organic Framework ◽  
Diffraction Tomography ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

The first Ce(III)-based coordination polymer ICR-9 (ICR stands for Inorganic Chemistry Řež), with the formula Ce2(C8H10P2O4)3, containing ditopic phenylene-1,4-bis(methylphosphinic acid) linker, was synthetized under solvothermal conditions. The crystal structure, solved using electron diffraction tomography (EDT), revealed 2D layers of octahedrally coordinated cerium atoms attached together through O-P-O bridges. The structure is nonporous, however, the modification of synthetic conditions led to unconventional metal–organic framework (or defective amorphous phase) with a specific surface area up to approximately 400 m2 g-1.

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