Ni(II) based one dimensional coordination polymers for environmental remediation: Design, topology, magnetism and selective adsorption of cationic dyes

CrystEngComm ◽  
2021 ◽  
Author(s):  
M. Shahwaz Ahmad ◽  
Mohd Khalid ◽  
M. Shahnawaz Khan ◽  
M. Shahid ◽  
Musheer Ahmad
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Environmental Remediation ◽  
Selective Adsorption ◽  
Cationic Dyes ◽  
Solvothermal Reaction ◽  
One Dimensional ◽  
Remediation Design

Herein, two Ni(II)-based one-dimensional (1D) coordination polymers (CPs), namely, [Ni(Hpdc)(H2O)(H2O)]]n (CP-1) and [Ni(pyc)2(H2O)]n (CP-2), where H3pdc = 3,5-pyrazoledicarboxylic acid and Hpyc = pyraziene-2-carboxylic acid were successfully synthesized under solvothermal reaction...

scholarly journals Synthesis, Crystal Structure and Magnetic Behaviour of Novel 4f-2s Heterometalic One-Dimensional Coordination Polymers on the Base of 2-Furan-Carboxylic Acid

2009 ◽  
Vol 4 (2) ◽  
pp. 60-67
Author(s):  
Silvia Melnic ◽  
Denis Prodius ◽  
Sergiu Shova ◽  
Helen Stoeckli-Evans ◽  
Yurii Simonov ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Carboxylic Acid ◽  
Ir Spectra ◽  
Single Crystal ◽  
General Formula ◽  
Coordination Polymers ◽  
Magnetic Behaviour ◽  
One Dimensional ◽  
X Ray

Nine new complexes with the general formula {[Ln2Ba(α-Fur)8(H2O)4]}n, where Ln = Nd3+, Sm3+, Eu3+, Pr3+, Gd3+, Tb3+, Ho3+, Er3+ and La3+; α-Fur ≡ C4H3OCOO, were synthesized and characterized by IR spectra, magnetism, X-ray single crystal and powder diffractions.

Sodium and lithium one-dimensional coordination polymers with 1H-indazole-3-carboxylic acid: Crystal structures, vibrational spectra and DFT calculations

Polyhedron ◽  
2020 ◽  
Vol 187 ◽  
pp. 114661
Author(s):  
Ksenia Szmigiel-Bakalarz ◽  
Markus Nentwig ◽  
Daniel Günther ◽  
Oliver Oeckler ◽  
Magdalena Malik-Gajewska ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Dft Calculations ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Vibrational Spectra ◽  
One Dimensional ◽  
Acid Crystal

A new set of Cd(ii)-coordination polymers with mixed ligands of dicarboxylate and pyridyl substituted diaminotriazine: selective sorption towards CO2and cationic dyes

2017 ◽  
Vol 46 (30) ◽  
pp. 9901-9911 ◽  
Author(s):  
Santanu Chand ◽  
Syed Meheboob Elahi ◽  
Arun Pal ◽  
Madhab C. Das
Keyword(s):  
Coordination Polymers ◽  
Selective Adsorption ◽  
Cationic Dyes ◽  
Cationic Dye ◽  
Selective Sorption ◽  
Separation Selectivity ◽  
Mixed Ligands

Pyridyl substituted diaminotriazine based three new Cd(ii)-CPs have been synthesized. CP3showed its potential for CO2/N2and CO2/CH4separation selectivity and its ability for selective adsorption to a cationic dye.

Structural tuning of Zn(ii)-MOFs based on pyrazole functionalized carboxylic acid ligands for organic dye adsorption

CrystEngComm ◽  
2020 ◽  
Vol 22 (36) ◽  
pp. 5941-5945 ◽  
Author(s):  
Xiao-Ting Liu ◽  
Si-Si Chen ◽  
Si-Miao Li ◽  
Hong-Xiang Nie ◽  
Yao-Qing Feng ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Selective Adsorption ◽  
Dye Adsorption ◽  
Organic Dye ◽  
Cationic Dyes

Two Zn(ii)-MOFs based on pyrazole functionalized carboxylic ligands have been constructed, which exhibit favorable selective adsorption of organic cationic dyes.

Anion and solvent controlled growth of crystalline and amorphous zinc(II) coordination polymers and a molecular complex

2021 ◽  
Author(s):  
Claire Deville ◽  
Henrik Særkjær Jeppesen ◽  
Vickie McKee ◽  
Nina Lock
Keyword(s):  
Coordination Polymers ◽  
Molecular Complex ◽  
Research Field ◽  
Metal Coordination ◽  
Controlled Growth ◽  
Bottom Up ◽  
One Dimensional

Controlled bottom-up synthesis of amorphous coordination polymers with tailored metal coordination is a research field in its infancy. In this study, synthesis control was achieved to selectively prepare one-dimensional (1D)...

On-Surface Synthesis of One-Dimensional Coordination Polymers with Tailored Magnetic Anisotropy

2021 ◽  
Author(s):  
Benjamin Mallada ◽  
Piotr Błoński ◽  
Rostislav Langer ◽  
Pavel Jelínek ◽  
Michal Otyepka ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Coordination Polymers ◽  
One Dimensional

scholarly journals Photoluminescent Coordination Polymers Based on Group 12 Metals and 1H-Indazole-6-Carboxylic Acid

Inorganics ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 20
Author(s):  
Antonio A. García-Valdivia ◽  
Estitxu Echenique-Errandonea ◽  
Gloria B. Ramírez-Rodríguez ◽  
José M. Delgado-López ◽  
Belén Fernández ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Density Functional ◽  
Free Ligand ◽  
Emission Spectra ◽  
Point Of View ◽  
Theoretical Point ◽  
Fourier Transformed Infrared Spectroscopy ◽  
3D Network ◽  
The Stability

Two new coordination polymers (CPs) based on Zn(II) and Cd(II) and 1H-indazole-6-carboxylic acid (H2L) of general formulae [Zn(L)(H2O)]n (1) and [Cd2(HL)4]n (2) have been synthesized and fully characterized by elemental analyses, Fourier transformed infrared spectroscopy and single crystal X-ray diffraction. The results indicate that compound 1 possesses double chains in its structure whereas 2 exhibits a 3D network. The intermolecular interactions, including hydrogen bonds, C–H···π and π···π stacking interactions, stabilize both crystal structures. Photoluminescence (PL) properties have shown that compounds 1 and 2 present similar emission spectra compared to the free-ligand. The emission spectra are also studied from the theoretical point of view by means of time-dependent density-functional theory (TD-DFT) calculations to confirm that ligand-centred π-π* electronic transitions govern emission of compound 1 and 2. Finally, the PL properties are also studied in aqueous solution to explore the stability and emission capacity of the compounds.

1D Mn(III) Coordination Polymers Exhibiting Chiral Symmetry Breaking and Weak Ferromagnetism

2021 ◽  
Author(s):  
Aoi Hara ◽  
Sotaro Kusumoto ◽  
Yoshihiro Sekine ◽  
Jack Harrowfield ◽  
Yang Kim ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Chiral Symmetry ◽  
Coordination Polymers ◽  
Chiral Symmetry Breaking ◽  
Weak Ferromagnetism ◽  
Chiral Ligands ◽  
One Dimensional

Mn(III) complexes with the non-chiral ligands, (E)-N-(2-((2-aminobenzylidene)amino)-2-methylpropyl)-5-X-2-hydroxybenzamide (HLX, X = H, Cl, Br, and I), crystallise as chiral conglomerates containing amide oxygen-bridged one-dimensional coordination polymers that exhibit weak ferromagnetism. The...

Carboxylic Acid-Doped SBA-15 Silica as a Host for Metallo-supramolecular Coordination Polymers†

2008 ◽  
Vol 112 (46) ◽  
pp. 14637-14647 ◽  
Author(s):  
D. Akcakayiran ◽  
D. Mauder ◽  
C. Hess ◽  
T. K. Sievers ◽  
D. G. Kurth ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Coordination Polymers ◽  
Supramolecular Coordination
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