A {Na2Fe10} isobutyrate cluster, interlinked into 1D chains

CrystEngComm ◽  
2021 ◽  
Author(s):  
Daniel Podgornii ◽  
Jan van Leusen ◽  
Victor Ch. Kravtsov ◽  
Paul Kögerler ◽  
Svetlana G Baca
Keyword(s):  
1D Chains

Charge-neutral [Na2Fe10O6(OH)4(isobutyrate)14(MeO)2(MeCN)2] coordination clusters, comprising a hollow ‘Chinese lantern’-like shell of six condensed planar triangular {FeIII3(μ3-O)} motifs, form upon ultrasonication of trinuclear Fe(III) isobutyrate units in acetonitrile in the presence...

scholarly journals Hierarchical Spin‐Crossover Cooperativity in Hybrid 1D Chains of Fe II ‐1,2,4‐Triazole Trimers Linked by [Au(CN) 2 ] − Bridges

2021 ◽  
Vol 27 (16) ◽  
pp. 5136-5141
Author(s):  
Lida Ezzedinloo ◽  
Katrina A. Zenere ◽  
Zixi Xie ◽  
Manan Ahmed ◽  
SynØve Scottwell ◽  
...  
Keyword(s):  
Spin Crossover ◽  
1D Chains

Holmium, thulium and lutetium-octamolybdate [Mo8O28]8− 1D chains: luminescence investigation of europium doped lutetium-octamolybdate

2019 ◽  
Vol 48 (23) ◽  
pp. 8186-8192 ◽  
Author(s):  
Anna M. Kaczmarek ◽  
Rik Van Deun ◽  
Kristof Van Hecke
Keyword(s):  
Lanthanide Ions ◽  
Inorganic Polymer ◽  
Luminescence Investigation ◽  
1D Chains

A purely inorganic polymer built from [Mo8O28]8− units alternately linked by lanthanide ions (Ho3+, Tm3+ and Lu3+) is reported.

Quasi-1D chains of dinickel lantern complexes and their magnetic properties

2017 ◽  
Vol 46 (17) ◽  
pp. 5546-5557 ◽  
Author(s):  
Arunpatcha Nimthong-Roldán ◽  
Jesse L. Guillet ◽  
James McNeely ◽  
Tarik J. Ozumerzifon ◽  
Matthew P. Shores ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Bridging Ligands ◽  
Chain Complexes ◽  
1D Chains

Four new quasi-1D Ni2lantern chain complexes of the form [Ni2(SOCR)4(L)]∞were prepared withN,N′-donor bridging ligands pyrazine and DABCO.

A Novel Coordination Polymer Containing Both Interdigitated 1D Chains and Interpenetrated 2D Grids

2002 ◽  
Vol 41 (13) ◽  
pp. 3328-3330 ◽  
Author(s):  
Ponnaiyan Ayyappan ◽  
Owen R. Evans ◽  
Wenbin Lin
Keyword(s):  
Coordination Polymer ◽  
1D Chains

A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand

2013 ◽  
Vol 275-277 ◽  
pp. 2367-2370
Author(s):  
Qing Yu Ma ◽  
Rui Fang Guan ◽  
Guo Zhong Li ◽  
Deng Xu Wang
Keyword(s):  
Single Crystal ◽  
Metal Organic Framework ◽  
Diffusion Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Slow Diffusion ◽  
Sheet Structure ◽  
Metal Organic ◽  
1D Chains ◽  
Organic Framework

A novel metal-organic framework, MnCl2(BIPS)2•2CH3OH•2H2O (1) were synthesized from MnCl2 and a tetrahedral silicon-cored ligand, Me2Si(p-C6H4-imdazol-1-yl)2 (BIPS) under the slow diffusion method. The structure was determined by single-crystal X-ray diffraction. Complex 1 is a 2D sheet structure constructed from 1D chains with 34-atom metallamacrocycles.

New 1D chains self-assembled by girdle-like Mo18 polyanions

2005 ◽  
Vol 751 (1-3) ◽  
pp. 29-32 ◽  
Author(s):  
Qi Li ◽  
Guang Liu ◽  
Shi-Wei Zhang
Keyword(s):  
Self Assembled ◽  
1D Chains

scholarly journals Threefold Spiral Structure Constructed by 1D Chains of [[M(NCS)2(bpa)2]·biphenyl]n (M = Fe, Co; bpa = 1,2-bis(4-pyridyl)ethane)

Crystals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 97 ◽  
Author(s):  
Satoshi Tokinobu ◽  
Haruka Dote ◽  
Satoru Nakashima
Keyword(s):  
Spin Crossover ◽  
Spiral Structure ◽  
Diffusion Method ◽  
Central Metal ◽  
X Ray ◽  
Pyridine Complex ◽  
1D Chain ◽  
One Step ◽  
Spiral Structures ◽  
1D Chains

Assembled complexes [[M(NCS)2(bpa)2]·biphenyl]n (M = Fe, Co; bpa = 1,2-bis(4-pyridyl)ethane) have been synthesized because [Fe(NCBH3)2(bpa)2·biphenyl]n has a novel threefold spiral structure and shows stepwise spin-crossover phenomenon. We attempted to obtain spiral structures for [[Fe(NCS)2(bpa)2]·biphenyl]n and [[Co(NCS)2(bpa)2]·biphenyl]n using a one-step diffusion method, while the reported spiral structure of [[Fe(NCBH3)2(bpa)2]·biphenyl]n was obtained by diffusion method after synthesizing Fe(II)-pyridine complex. X-ray structural analysis revealed that [[Fe(NCS)2(bpa)2]·biphenyl]n and [[Co(NCS)2(bpa)2]·biphenyl]n had a chiral propeller structure of pyridines around the central metal, and they had a novel spiral structure and chiral space group P3121 without the presence of chiral auxiliaries. It was shown that the host 1D chain, having a chiral propeller structure of pyridines around the central metal along with its concerted interaction with an atropisomer of biphenyl, made a threefold spiral structure.

Assembly of Iron(II)-Triazole Polymers from 1D Chains to 3D Interpenetrated Frameworks: Syntheses, Structures, and Magnetic Properties

2008 ◽  
Vol 8 (4) ◽  
pp. 1306-1312 ◽  
Author(s):  
Zhi-Guo Gu ◽  
Yi-Fan Xu ◽  
Xin-Hui Zhou ◽  
Jing-Lin Zuo ◽  
Xiao-Zeng You
Keyword(s):  
Magnetic Properties ◽  
1D Chains

A series of divalent metal coordination polymers based on isomeric tetracarboxylic acids: synthesis, structures and magnetic properties

2014 ◽  
Vol 43 (46) ◽  
pp. 17519-17527 ◽  
Author(s):  
Min-Le Han ◽  
Ya-Ping Duan ◽  
Dong-Sheng Li ◽  
Guo-Wang Xu ◽  
Ya-Pan Wu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Divalent Metal ◽  
Metal Coordination ◽  
3D Network ◽  
Supramolecular Networks ◽  
Metal Coordination Polymers ◽  
1D Chains

A series of M(ii) coordination polymers has been synthesized. 1–3 contain 1D infinite chains, and these 1D chains are further linked by hydrogen bonding to form 3D supramolecular networks. While 4 and 5 show tetra- or penta-nodal 3D network, respectively.

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