Rapid synthesis of Cu2O hollow spheres at low temperature and their catalytic performance for the decomposition of ammonium perchlorate

CrystEngComm ◽  
2021 ◽  
Author(s):  
Tao-Tao Lv ◽  
Huai-Zhong Xing ◽  
Hong-Mei Yang ◽  
Hui-Xiang Wang ◽  
Jing Shi ◽  
...  

A simple and efficient strategy for synthesizing high-performance crystalline catalyst Cu2O hollow spheres with a large specific surface area was demonstrated.

2019 ◽  
Vol 6 (3) ◽  
pp. 715-722 ◽  
Author(s):  
Kun Zhao ◽  
Haitao Li ◽  
Shouqin Tian ◽  
Wenjuan Yang ◽  
Xiaoxia Wang ◽  
...  

Sub-micro hierarchical porous Co3O4 dodecahedra with a large specific surface area (106.11 m2 g−1) were synthesized by the thermolysis of ZIF-67 at a low temperature of 268 °C assisted by ammonium perchlorate (AP).


2021 ◽  
Vol 14 (02) ◽  
pp. 2151011
Author(s):  
Jingwen Jia ◽  
Longfu Wei ◽  
Ziting Guo ◽  
Fang Li ◽  
Changlin Yu ◽  
...  

Metal–organic frameworks (MOFs) are the electrocatalytic materials with large specific surface area, high porosity, controllable structure and monodisperse active center, which is a promising candidate for the application of electrochemical energy conversion. However, the electrocatalytic performance of pure MOFs is seriously limited its poor conductivity and stability. In this work, high-performance electrocatalyst was fabricated through combining NiFe/MOF on nickel foam (NF) via in-situ growth strategy. Through rational control of the time and ratio in reaction precursors, we realized the effective manipulation of the growth behavior, and further investigated the electrocatalytic performance in water splitting. The catalyst presented excellent electrocatalytic performance for water splitting, with low overpotential of 260 mV in alkaline condition at a current density of 50 mA[Formula: see text], which is benefited from the large specific surface area and active sites. This study demonstrates that the rational design of NiFe MOF/NF plays a significant role in high-performance electrocatalyst.


Author(s):  
Lei Zhao ◽  
Ziwei Lan ◽  
Junyu Su ◽  
Huazhu Liang ◽  
Jiayu Yao ◽  
...  

Compared with precious metal catalysts, non-platinum catalysts have the advantages of low cost and high performance. Among them, the activated carbon (AC) with a large specific surface area (SSA) can be used as a carrier or as a carbon source of nonprecious metal/carbon system catalyst at the same time. Therefore, this paper uses cheap pine peel bio-based materials to prepare large surface area activated carbon and then compound with cobalt phthalocyanine (CoPc) to obtain a high-performance cobalt/nitrogen/carbon catalyst. The merits include AC@CoPc composite catalysts are prepared by precisely controlling the composite proportion of AC and CoPc, the atomically dispersed Co nanoparticles form and synergistically with N promote the exposure of CoNx active sites, and the Eonset of the catalyst treated with a composite proportion of AC and CoPc of 1 to 2 at 800 °C (AC@CoPc-800-1-2) is 1.01 V, which is higher than Pt/C (20 wt%) catalyst. Apart from this, the stability is 87.8% in 0.1 M KOH after 20000 s testing in compared with other AC@CoPc series catalysts and Pt/C (20 wt%) catalyst. Considering from the performance and price of the catalyst in practical application, these composite catalysts combine biomass carbon materials with phthalocyanine series, which will be widely used in the area of nonprecious metal catalysts.


2018 ◽  
Vol 54 (53) ◽  
pp. 7346-7349 ◽  
Author(s):  
Jianbiao Wang ◽  
Zhenwei Liu ◽  
Wenjuan Yang ◽  
Lijing Han ◽  
Mingdeng Wei

V2O3@C hollow spheres with a large specific surface area exhibited high reversible capacity for LIBs.


2013 ◽  
Vol 42 (2) ◽  
pp. 432-440 ◽  
Author(s):  
Nicole Zink ◽  
Franziska Emmerling ◽  
Tobias Häger ◽  
Martin Panthöfer ◽  
Muhammad Nawaz Tahir ◽  
...  

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