Radical trifunctionalization of hexenenitrile by remote cyano migration

2022 ◽  
Author(s):  
Chenyang Chang ◽  
Huihui Zhang ◽  
Xinxin Wu ◽  
Chen Zhu
Keyword(s):  
Functional Group ◽  
Group Migration

A novel radical-mediated trifunctionalization of hexenenitriles by the strategy of remote functional group migration is disclosed. A portfolio of functionalized hexenenitriles are employed as substrates. After difunctionalization of the unactivated...

Functional group migration in benzaldoxime-O-n-propyl ether radical cation

2002 ◽  
Vol 217 (1-3) ◽  
pp. 153-168 ◽  
Author(s):  
Matthias C Letzel ◽  
Hans-Friedrich Grützmacher ◽  
Thomas Fürst ◽  
Klaus K Mayer ◽  
Wolfgang Wiegrebe
Keyword(s):  
Radical Cation ◽  
Functional Group ◽  
Group Migration

Functional Group Migration in Ionized Long-Chain Compounds

1994 ◽  
Vol 116 (13) ◽  
pp. 5865-5872 ◽  
Author(s):  
Ilan Vidavsky ◽  
Russell A. Chorush ◽  
Pierre Longevialle ◽  
Fred W. McLafferty
Keyword(s):  
Functional Group ◽  
Chain Compounds ◽  
Group Migration ◽  
Long Chain

Distal Functional Group Migration for Visible-light Induced Carbo-difluoroalkylation/monofluoroalkylation of Unactivated Alkenes

2017 ◽  
Vol 360 (4) ◽  
pp. 744-750 ◽  
Author(s):  
Jiajia Yu ◽  
Dongping Wang ◽  
Yan Xu ◽  
Zhen Wu ◽  
Chen Zhu
Keyword(s):  
Visible Light ◽  
Functional Group ◽  
Group Migration

Functional Group Migration in Reactions of 1,2-Diferrocenyl-3-(methylthio)cyclopropenylium Iodide with CH Acids

2006 ◽  
Vol 2006 (20) ◽  
pp. 4755-4760 ◽  
Author(s):  
Elena I. Klimova ◽  
Marcos Martínez García ◽  
Tatiana Klimova Berestneva ◽  
Cecilio Alvarez Toledano ◽  
Ruben Alfredo Toscano ◽  
...  
Keyword(s):  
Functional Group ◽  
Ch Acids ◽  
Group Migration

Radical-Mediated Remote Functional Group Migration

2020 ◽  
Vol 53 (8) ◽  
pp. 1620-1636 ◽  
Author(s):  
Xinxin Wu ◽  
Chen Zhu
Keyword(s):  
Functional Group ◽  
Group Migration

scholarly journals Advances in Trifluoromethylation-Promoted Functional Group Migration of Alkenes

2021 ◽  
pp. 1821
Author(s):  
Yunliang Qiu ◽  
Fengjiao Wei ◽  
Liu Ye ◽  
Minyue Zhao
Keyword(s):  
Functional Group ◽  
Group Migration

Difunctionalization of Unactivated Alkenes through SCF3 Radical-triggered Distal Functional Group Migration

2018 ◽  
Vol 76 (12) ◽  
pp. 951 ◽  
Author(s):  
Dong Chen ◽  
Meishan Ji ◽  
Yingming Yao ◽  
Chen Zhu
Keyword(s):  
Functional Group ◽  
Group Migration

Recent advances in 1,4-functional group migration-mediated radical fluoroalkylation of alkenes and alkynes

2020 ◽  
Vol 18 (44) ◽  
pp. 8975-8993
Author(s):  
Ya-Jing Chen ◽  
Ya-Li Qu ◽  
Xiang Li ◽  
Chuan-Chuan Wang
Keyword(s):  
Functional Group ◽  
Recent Advances ◽  
Group Migration

In this article, some representative reactions of 1,4-functional group migration-mediated radical fluoroalkylation of alkenes and alkynes have been discussed and reviewed based on the types of substrates.

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