Frustrated Lewis pair catalyzed hydrodehalogenation of benzyl-halides

2022 ◽  
Author(s):  
Tongtong Wang ◽  
Maotong Xu ◽  
Andy jupp ◽  
Shi-Ming Chen ◽  
Zheng-wang Qu ◽  
...  
Keyword(s):  
Frustrated Lewis Pair ◽  
Benzyl Halides

10 mol% B(o-C6F2H3)3 in the presence of excess tetramethylpiperidine (TMP) and H2 (or D2) is shown to catalyze the hydrogenative dehalogenation of benzyl-halides to give corresponding toluene derivatives. These reactions...

scholarly journals Hydrogenation of secondary amides using phosphane oxide and frustrated Lewis pair catalysis

2021 ◽  
Author(s):  
Laura Köring ◽  
Nikolai A. Sitte ◽  
Markus Bursch ◽  
Stefan Grimme ◽  
Jan Henry Hakan Paradies
Keyword(s):  
Frustrated Lewis Pair ◽  
Secondary Amides

Bis(perchlorocatecholato)silane and Heteroleptic Bidonors: Hidden Frustrated Lewis Pairs by Ring Strain

2021 ◽  
Author(s):  
Deborah Hartmann ◽  
Sven Braner ◽  
Lutz Greb
Keyword(s):  
Ammonia Borane ◽  
Frustrated Lewis Pairs ◽  
Ring Strain ◽  
Frustrated Lewis Pair ◽  
Lewis Pairs

Bis(perchlorocatecholato)silane and bidentate N,N- or N,P-heteroleptic donors form hexacoordinated complexes. Depending on the ring strain and hemilability in the adducts, Frustrated Lewis pair reactivity with aldehydes and catalytic ammonia borane...

Phosphine-Catalyzed Cross-Coupling of Benzyl Halides and Fumarates

2021 ◽  
Author(s):  
Tingting Yan ◽  
Kaki Raveendra Babu ◽  
Yong Wu ◽  
Yang Li ◽  
Yuhai Tang ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Benzyl Halides

ChemInform Abstract: Coupling of Benzyl Halides with Aryl Grignard Reagents Catalyzed by Iron(III) Amine-bis(phenolate) Complexes.

ChemInform ◽  
2013 ◽  
Vol 44 (45) ◽  
pp. no-no
Author(s):  
Elliott F. Chard ◽  
Louise N. Dawe ◽  
Christopher M. Kozak
Keyword(s):  
Grignard Reagents ◽  
Benzyl Halides

scholarly journals A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes

2013 ◽  
Vol 5 (8) ◽  
pp. 718-723 ◽  
Author(s):  
Konstantin Chernichenko ◽  
Ádám Madarász ◽  
Imre Pápai ◽  
Martin Nieger ◽  
Markku Leskelä ◽  
...  
Keyword(s):  
Catalytic Reduction ◽  
Frustrated Lewis Pair
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