Size-tunable fluorescent dendrimersomes via aggregation-induced emission

2022 ◽  
Author(s):  
Marilyne Bélanger-Bouliga ◽  
Brandon Andrade-Gagnon ◽  
Diep Thi Hong Nguyen ◽  
Nazemi Ali

Tetraphenylethylene-functionalized amphiphilic Janus dendrimers of up to third generation are synthesized. Their self-assembly has been studied under kinetic and thermodynamic control. By varying the dendrimer generation number and the self-assembly...

2008 ◽  
Vol 86 (6) ◽  
pp. 540-547 ◽  
Author(s):  
Tatiana Vassilieff ◽  
Ashok Kakkar

We report on the synthesis and detailed characterization of dendrimers that evolve symmetrically from a linear core of 2-butyne-1,4-diol with 3,5-dihydroxybenzyl alcohol based dendron arms. The divergent layer-by-layer build-up of the dumbbell-shaped dendrimers is based on simple acid–base hydrolytic chemistry of bis(dimethylamino)dimethylsilane with OH-terminated molecules. The self-assembly of these dendrimers in THF and water is significantly influenced by their generation number, the backbone structure, and the solvent.Key words: dendrimers, divergent synthesis, macromolecules, self-assembly


2016 ◽  
Vol 14 (24) ◽  
pp. 5574-5579 ◽  
Author(s):  
Hendrik Frisch ◽  
Daniel Spitzer ◽  
Mathias Haase ◽  
Thomas Basché ◽  
Jens Voskuhl ◽  
...  

The synthesis and self-assembly of a new C2-symmetric oligohistidine amphiphile equipped with an aggregation induced emission luminophore is reported.


2016 ◽  
Vol 4 (27) ◽  
pp. 6546-6561 ◽  
Author(s):  
Suraj Kumar Pathak ◽  
Balaram Pradhan ◽  
Ravindra Kumar Gupta ◽  
Monika Gupta ◽  
Santanu Kumar Pal ◽  
...  

Effect of the number of flexible peripheral tails on the self-assembly of star-shaped molecules.


2013 ◽  
Vol 135 (47) ◽  
pp. 17723-17726 ◽  
Author(s):  
Amber M. Johnson ◽  
Michael C. Young ◽  
Xing Zhang ◽  
Ryan R. Julian ◽  
Richard J. Hooley

2020 ◽  
Vol 11 (29) ◽  
pp. 4706-4713 ◽  
Author(s):  
Siyu Wang ◽  
Bixin Jin ◽  
Gangfeng Chen ◽  
Yunjun Luo ◽  
Xiaoyu Li

Aggregation-induced emission (AIE) was triggered via the spatial confinement in the coronal chains in block copolymers upon micellization, even with very low content of AIE groups attached, and this could be used to monitor the self-assembly process.


Soft Matter ◽  
2018 ◽  
Vol 14 (30) ◽  
pp. 6166-6170 ◽  
Author(s):  
Marlen Externbrink ◽  
Steffen Riebe ◽  
Carsten Schmuck ◽  
Jens Voskuhl

A novel organogelator with aggregation-induced emission properties responds to several external stimuli such as pH value, temperature and mechanical stress by the self-assembly of guanidiniocarbonyl pyrrole carboxylate zwitterions.


2019 ◽  
Vol 55 (3) ◽  
pp. 322-325 ◽  
Author(s):  
Krishnendu T. Prakash ◽  
Namrata Singh ◽  
V. Venkatesh

We demonstrate a novel strategy to synthesize highly stable and luminescent mercaptoimidazole-capped copper nanoclusters (CuNCs). Simple modification of substituents on the mercaptoimidazole ligand dictates the self-assembly and photophysical properties of the clusters.


2015 ◽  
Vol 51 (5) ◽  
pp. 952-955 ◽  
Author(s):  
Sung Ho Jung ◽  
Ki-Young Kwon ◽  
Jong Hwa Jung

The self-assembly of the terpyridine-based ligand exhibited strong emission in the presence of Zn2+ due to the formation of coordination bonds between the terpyridine moieties and the Zn2+ by the aggregation-induced emission effect.


2017 ◽  
Vol 5 (26) ◽  
pp. 5120-5127 ◽  
Author(s):  
Yuanyuan Huang ◽  
Hui Feng ◽  
Weidong Liu ◽  
Shasha Zhang ◽  
Cong Tang ◽  
...  

The self-assembly of CuNCs was driven by aluminum cations and they had a sensing application in the monitoring of β-galactosidase activity.


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