The Cis/Trans Conformation Approach for Tuning the Magnetic Coupling in a Diradical: Isolation of Pure Pyridine-Based Diradical Dianions
Two-electron reductions of 3,3'-bis(2,6-dimesitylpyridin-4-yl)-1,1'-biphenyl 1 with elemental potassium in the absence and presence of 18-c-6 afforded the diradical dianion salts [K+]2•[trans-1]••2– and [K(18-c-6)]+2•[cis-1]••2–, which exhibits trans and cis configurations respectively....
1993 ◽
Vol 51
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pp. 1038-1039
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1993 ◽
Vol 51
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pp. 1032-1033
1997 ◽
Vol 7
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pp. C2-389-C2-395
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2015 ◽
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pp. 776-784
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2017 ◽
Vol 137
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pp. 326-333
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Vol 137
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pp. 518-525
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