Stereoselective total synthesis of (±)-vindeburnol and (±)-16-epi-vindeburnol

2021 ◽  
Author(s):  
Xiangtao Chen ◽  
Lei Yu ◽  
huijing Wang ◽  
Wen Zhang ◽  
Pei Tang ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Different Types ◽  
Synthetic Work ◽  
Villiger Oxidation

A concise stereoselective total synthesis of (±)-vindeburnol and its epimer (±)-16-epi-vindeburnol is presented. This synthetic work features the utilization of Baeyer-Villiger oxidation to install different types of lactone substrate, and...

Alkaloids from alkaloids: total synthesis of (±)-7a-epi-hyacinthacine A1 from Z-protected tropenone via Baeyer–Villiger oxidation

Tetrahedron ◽  
2009 ◽  
Vol 65 (33) ◽  
pp. 6626-6634 ◽  
Author(s):  
Olena Affolter ◽  
Angelika Baro ◽  
Wolfgang Frey ◽  
Sabine Laschat
Keyword(s):  
Total Synthesis ◽  
Villiger Oxidation

ChemInform Abstract: Total Synthesis of a Monocyclofarnesane Norsesquiterpenoid Isolated from Mushroom Ingested by Beetle: Utility of Solid State Baeyer-Villiger Oxidation.

ChemInform ◽  
2010 ◽  
Vol 30 (30) ◽  
pp. no-no
Author(s):  
Hisahiro Hagiwara ◽  
Hidenori Nagatomo ◽  
Shin-ichi Kazayama ◽  
Hitoshi Sakai ◽  
Takashi Hoshi ◽  
...  
Keyword(s):  
Solid State ◽  
Total Synthesis ◽  
Villiger Oxidation

A selective baeyer-villiger oxidation: A total synthesis of (−)-Acetomycin

1993 ◽  
Vol 34 (48) ◽  
pp. 7669-7672 ◽  
Author(s):  
Frederick E. Ziegler ◽  
Hakwon Kim
Keyword(s):  
Total Synthesis ◽  
Villiger Oxidation

scholarly journals Stereocontrolled Total Synthesis of Tetrodotoxin from myo-Inositol and D-Glucose by Three Routes: Aspects for Constructing Complex Multi-Functionalized Cyclitols with Branched-Chain Structures

2013 ◽  
Vol 8 (7) ◽  
pp. 1934578X1300800
Author(s):  
Ken-ichi Sato ◽  
Shoji Akai ◽  
Juji Yoshimura
Keyword(s):  
Molecular Weight ◽  
Total Synthesis ◽  
Chemical Properties ◽  
Synthetic Method ◽  
Small Molecular Weight ◽  
Different Types ◽  
Branched Chain ◽  
Branched Chains ◽  
Selection Of ◽  
And Chemical Properties

This report describes the stereocontrolled total synthesis of the multi-functionalized cyclitol derivative tetrodotoxin containing eight asymmetric carbons and different types of branched-chains from myo-inositol and D-glucose using three different methods. The tetrodotoxin derivatives possess a relatively small molecular weight but unique structural and chemical properties. Selection of the appropriate synthetic method may be useful not only for compounds related to TTX (including related derivatives) but also for other highly complex multi-functionalized cyclitols containing branched-chains.

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