Luminescent Lanthanide-Macrocycle Supramolecular Assembly

2021 ◽  
Author(s):  
Wei-Lei Zhou ◽  
Yong Chen ◽  
Wenjing Lin ◽  
Yu Liu
Keyword(s):  
Crown Ether ◽  
Supramolecular Assembly ◽  
Macrocyclic Compounds ◽  
Guest Molecules ◽  
Non Covalent Interactions ◽  
Covalent Interactions

a series of macrocyclic compounds, including crown ether, cyclodextrin, cucurbituril and pillararene, bound with various specific organic/inorganic/biological guest molecules and ions through various non-covalent interactions, can not only make a...

Self-assembly mode and supramolecular framework of cyclopentanocucurbit[6]uril and aromatic amines

2021 ◽  
Vol 25 ◽  
Author(s):  
Jun Zheng ◽  
Yan Mei Jin ◽  
Xi Nan Yang ◽  
Lin Zhang ◽  
Dao Fa Jiang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Functional Materials ◽  
Supramolecular Interactions ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
Characterization Methods ◽  
Potential Applications ◽  
Non Covalent Interactions ◽  
Multi Level ◽  
Covalent Interactions

: Single-crystal X-ray diffraction analysis, nuclear magnetic resonance (NMR), and other characterization methods are used to characterize the complexes formed by cyclopentano-cucurbit[6]uril (abbreviated as CyP6Q[6]) as a host interacting with p-aminobenzenesulfonamide (G1), 4,4'-diaminobiphenyl (G2), and (E)-4,4'-diamino-1,2-diphenylethene (G3) as guests, respectively. The experimental results show that these three aromatic amine molecules have the same interaction mode with CyP6Q[6], interacting with its negatively electric potential portals. The supramolecular interactions include non-covalent interactions of hydrogen bonding and ion-dipole between host and guest molecules. CdCl2 acts as a structureinducing agent to form self-assemblies of multi-dimensional and multi-level supramolecular frameworks that may have potential applications in various functional materials.

scholarly journals A combined experimental and computational study on supramolecular assemblies in hetero-tetranuclear nickel(ii)–cadmium(ii) complexes with N2O4-donor compartmental Schiff bases

2016 ◽  
Vol 45 (38) ◽  
pp. 15048-15059 ◽  
Author(s):  
Sourav Roy ◽  
Anik Bhattacharyya ◽  
Sourav Purkait ◽  
Antonio Bauzá ◽  
Antonio Frontera ◽  
...  
Keyword(s):  
Schiff Bases ◽  
Computational Study ◽  
Supramolecular Assembly ◽  
Supramolecular Assemblies ◽  
Non Covalent Interactions ◽  
Covalent Interactions

The contribution of various non-covalent interactions in the supramolecular assembly of two new hetero-polynuclear nickel(ii)–cadmium(ii) complexes with salicylidine Schiff bases were estimated.

Complexation and Chiral Recognition of Chiral Binaphthyl Derivatives and β-Cyclodextrins in Solution Probed by Triplet Excited State Relaxation

2015 ◽  
Vol 229 (10-12) ◽  
Author(s):  
Yasser M. Riyad ◽  
Christian Laube ◽  
Sergej Naumov ◽  
Ralf Hermann ◽  
Bernd Abel
Keyword(s):  
Excited State ◽  
Triplet State ◽  
Supramolecular Chemistry ◽  
Chiral Recognition ◽  
Triplet Excited State ◽  
Guest Molecules ◽  
Excited Triplet ◽  
Non Covalent Interactions ◽  
Covalent Interactions ◽  
Recognition Capability

AbstractIt is well known in supramolecular chemistry that cyclodextrin host molecules (CDs) are capable of including and binding guest molecules in their hydrophobic cavities via non-covalent interactions. The unique recognition capability of CDs depends on their inherent asymmetric cavities. We explored here the impacts of the chiral recognition of excited triplet state of guest 1,1′–Binaphthyl–2,2′–diylhydrogenphosphate (BNP) enantiomers by host native

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