Molecular structures and magnetic properties of endohedral metallofullerenes

2021 ◽  
Vol 57 (80) ◽  
pp. 10317-10326
Author(s):  
Wang Li ◽  
Chunru Wang ◽  
Taishan Wang
Keyword(s):  
Magnetic Properties ◽  
Recent Progress ◽  
Molecular Structures ◽  
Feature Article ◽  
Endohedral Metallofullerenes

Endohedral metallofullerenes are fascinating materials. Recent progress on molecular structures and magnetic properties of metallofullerenes is summarized in this feature article.

Molecular structures and magnetic properties of .mu.-phenolato binuclear copper(II) complexes incorporating chloro, hydroxo, and azido exogenous bridging ligands

1988 ◽  
Vol 27 (21) ◽  
pp. 3710-3716 ◽  
Author(s):  
Azdine Benzekri ◽  
Patrick Dubourdeaux ◽  
Jean Marc Latour ◽  
Jean Laugier ◽  
Paul Rey
Keyword(s):  
Magnetic Properties ◽  
Molecular Structures ◽  
Binuclear Copper ◽  
Bridging Ligands

Structures, physicochemical properties, and applications of T–HgII–T, C–AgI–C, and other metallo-base-pairs

2015 ◽  
Vol 51 (98) ◽  
pp. 17343-17360 ◽  
Author(s):  
Yoshiyuki Tanaka ◽  
Jiro Kondo ◽  
Vladimír Sychrovský ◽  
Jakub Šebera ◽  
Takenori Dairaku ◽  
...  
Keyword(s):  
Physicochemical Properties ◽  
Recent Progress ◽  
Future Perspectives ◽  
Base Pairs ◽  
Feature Article

In this feature article, recent progress and future perspectives of metal-mediated base-pairs such as T–Hg(ii)–T and C–Ag(i)–C are presented.

Recent progress in the chemistry of endohedral metallofullerenes

2014 ◽  
Vol 50 (94) ◽  
pp. 14701-14715 ◽  
Author(s):  
Xing Lu ◽  
Lipiao Bao ◽  
Takeshi Akasaka ◽  
Shigeru Nagase
Keyword(s):  
Recent Progress ◽  
Endohedral Metallofullerenes

Tuning magnetism at the two-dimensional limit: A theoretical perspective

Nanoscale ◽  
2021 ◽  
Author(s):  
Dongzhe Li ◽  
Shuo Li ◽  
Chengyong Zhong ◽  
Junjie He
Keyword(s):  
Magnetic Properties ◽  
Magnetic Materials ◽  
Recent Progress ◽  
Theoretical Perspective ◽  
Two Dimensional

The discovery of two-dimensional (2D) magnetic materials provides an ideal testbed for manipulating the magnetic properties at the atomically thin and the 2D limit. This review gives recent progress on...

scholarly journals Thermodynamically stable [4 + 2] cycloadducts of lanthanum-encapsulated endohedral metallofullerenes

2014 ◽  
Vol 10 ◽  
pp. 714-721 ◽  
Author(s):  
Yuta Takano ◽  
Yuki Nagashima ◽  
M Ángeles Herranz ◽  
Nazario Martín ◽  
Takeshi Akasaka
Keyword(s):  
Thermal Stability ◽  
Material Science ◽  
Molecular Structures ◽  
Spectroscopic Methods ◽  
Dynamic Nmr ◽  
The Novel ◽  
Endohedral Metallofullerenes ◽  
Derivatives Of ◽  
Paramagnetic Properties

The [4 + 2] cycloaddition of o-quinodimethanes, generated in situ from the sultine 4,5-benzo-3,6-dihydro-1,2-oxathiin 2-oxide and its derivative, to La metal-encapsulated fullerenes, La2@C80 or La@C82, afforded the novel derivatives of endohedral metallofullerenes (3a,b, 4a,b and 5b). Molecular structures of the resulting compounds were elucidated using spectroscopic methods such as MALDI–TOF mass, optical absorption, and NMR spectroscopy. The [4 + 2] adducts of La2@C80 (3a,b, and 4a,b) and La@C82 (5b), respectively, retain diamagnetic and paramagnetic properties, as confirmed by EPR spectroscopy. Dynamic NMR measurements of 4a at various temperatures demonstrated the boat-to-boat inversions of the addend. In addition, 5b revealed remarkable thermal stability in comparison with the reported [4 + 2] cycloadduct of pentamethylcyclopentadiene and La@C82 (6). These findings demonstrate the utility of sultines to afford thermodynamically stable endohedral metallofullerene derivatives for the use in material science.

ChemInform Abstract: Recent Progress in Chemistry of Endohedral Metallofullerenes

ChemInform ◽  
2011 ◽  
Vol 43 (2) ◽  
pp. no-no
Author(s):  
Takahiro Tsuchiya ◽  
Takeshi Akasaka ◽  
Shigeru Nagase
Keyword(s):  
Recent Progress ◽  
Endohedral Metallofullerenes

Metal carbonyl cluster-based coordination polymers: diverse syntheses, versatile network structures, and special properties

CrystEngComm ◽  
2019 ◽  
Vol 21 (48) ◽  
pp. 7341-7364 ◽  
Author(s):  
Minghuey Shieh ◽  
Yu-Hsin Liu ◽  
Yu-Huei Li ◽  
Ru Yan Lin
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Recent Progress ◽  
Metal Carbonyl ◽  
Structural Transformations ◽  
Network Structures ◽  
Carbonyl Cluster ◽  
Metal Carbonyl Cluster

This highlight surveys recent progress in groups 6–10 metal carbonyl cluster-based coordination polymers, focusing on diverse synthetic strategies, versatile structures, structural transformations, and semiconducting as well as magnetic properties.

Magnetic properties of atomic clusters and endohedral metallofullerenes

2015 ◽  
Vol 289-290 ◽  
pp. 315-340 ◽  
Author(s):  
Jijun Zhao ◽  
Xiaoming Huang ◽  
Peng Jin ◽  
Zhongfang Chen
Keyword(s):  
Magnetic Properties ◽  
Atomic Clusters ◽  
Endohedral Metallofullerenes
Sign in / Sign up

Export Citation Format

Share Document