Ozonolysis of α-angelica lactone: a renewable route to malonates

2021 ◽  
Author(s):  
Andrea Dell'Acqua ◽  
Lukas Wille ◽  
Bernhard Michael Stadler ◽  
Sergey Tin ◽  
Johannes G. de Vries
Keyword(s):  
Malonic Acid ◽  
Levulinic Acid ◽  
Platform Chemical ◽  
Angelica Lactone

Industrially relevant intermediates such as malonic acid, malonates and 3-oxopropionates can be easily accessed by ozonolysis of α-angelica lactone, derived from the platform chemical levulinic acid. The roles of the...

scholarly journals Scalable synthesis and polymerisation of a β-angelica lactone derived monomer

2020 ◽  
Vol 22 (16) ◽  
pp. 5267-5273
Author(s):  
Andrea Dell'Acqua ◽  
Bernhard M. Stadler ◽  
Sarah Kirchhecker ◽  
Sergey Tin ◽  
Johannes G. de Vries
Keyword(s):  
Levulinic Acid ◽  
Platform Chemical ◽  
New Material ◽  
Scalable Synthesis ◽  
Angelica Lactone

A new bio-based norbornene polymer was prepared starting from β-angelica lactone, prepared in a sustainable and scalable manner from the platform chemical levulinic acid. The new material displays transparency comparable to petrochemical-derived polynorbornene.

γ-Valerolactone synthesis from α-angelica lactone and levulinic acid over biobased multifunctional nanohybrid catalysts

2021 ◽  
Author(s):  
Margarida M. Antunes ◽  
Andreia F. Silva ◽  
Auguste Fernandes ◽  
Anabela A. Valente
Keyword(s):  
Levulinic Acid ◽  
Angelica Lactone

Production of levulinic acid and use as a platform chemical for derived products

2000 ◽  
Vol 28 (3-4) ◽  
pp. 227-239 ◽  
Author(s):  
Joseph J Bozell ◽  
L Moens ◽  
D.C Elliott ◽  
Y Wang ◽  
G.G Neuenscwander ◽  
...  
Keyword(s):  
Levulinic Acid ◽  
Platform Chemical

Levulinic acid: a sustainable platform chemical for novel polymer architectures

2020 ◽  
Vol 11 (25) ◽  
pp. 4068-4077 ◽  
Author(s):  
Graham C. Hayes ◽  
C. Remzi Becer
Keyword(s):  
Levulinic Acid ◽  
Platform Chemical ◽  
Polymer Architectures

Levulinic acid is a multipurpose platform chemical that is currently used in a wide variety of applications.

Obtaining a high value branched bio-alkane from biomass-derived levulinic acid using RANEY® as hydrodeoxygenation catalyst

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 93956-93962 ◽  
Author(s):  
Boqiong Lu ◽  
Jinlong Li ◽  
Guangqiang Lv ◽  
Yongqin Qi ◽  
Yingxiong Wang ◽  
...  
Keyword(s):  
Levulinic Acid ◽  
Angelica Lactone

A high value branched angelica lactone bio-alkane from biomass-derived levulinic acid gives nearly 90% hydrodeoxygenation yield under 483 K and 5 MPa H2 and the C10 branched alkane product, 3-ethyl-4-methyl heptane, accounts for 75% of the same.

Optimal Process Conditions for Levulinic Acid Synthesis from Glucose Using ZSM-5 Supported SO42-/ZrO2 Catalysts

2012 ◽  
Vol 538-541 ◽  
pp. 2256-2259 ◽  
Author(s):  
Jun Ping Zhuang ◽  
Xue Ping Li ◽  
Ying Liu
Keyword(s):  
Levulinic Acid ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Acid Synthesis ◽  
Process Conditions ◽  
Optimal Process ◽  
Acid Yield ◽  
Platform Chemical

Levulinic acid has been identified as a promising green, biomass derived platform chemical. Since the availability of fossil resources diminishes, the conversion of carbohydrates to Levulinic acid has become increasingly important. ZSM-5 supported SO42-/ZrO2 solid acid catalyst have been applied for the dehydration of glucose to Levulinic acid. With ZSM-5 supported SO42-/ZrO2 solid acid as the catalyst, an optimized Levulinic acid yield was obtained at 180 °C for 2.5 h with 3 g ZSM-5 supported SO42-/ZrO2 catalyst solid acid catalys and the highest Levulinic acid yield was 55.035%.

scholarly journals Catalytic upgrading of α-angelica lactone to levulinic acid esters under mild conditions over heterogeneous catalysts

2015 ◽  
Vol 5 (12) ◽  
pp. 5168-5173 ◽  
Author(s):  
Mohammad G. Al-Shaal ◽  
Wirawan Ciptonugroho ◽  
Fabian J. Holzhäuser ◽  
Joel B. Mensah ◽  
Peter J. C. Hausoul ◽  
...  
Keyword(s):  
Levulinic Acid ◽  
Heterogeneous Catalysts ◽  
Catalytic Upgrading ◽  
Mild Conditions ◽  
Angelica Lactone ◽  
Acid Esters

α-Angelica lactone was identified as a better candidate than levulinic acid for the heterogeneously catalysed preparation of levulinic acid esters.

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