Proton-Accelerated Lewis Acid Catalysis for Stereo- and Regioselective Isomerization of Epoxides to Allylic Alcohols

2021 ◽  
Author(s):  
Masahiro Noji ◽  
Misako Baba ◽  
Rina Hirabe ◽  
Satoshi Hayashi ◽  
Toshikatsu Takanami
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Catalytic Cycle ◽  
Allylic Alcohols ◽  
Lewis Acid Catalysis ◽  
Proton Source

The isomerization of epoxides to allylic alcohols was developed via proton-accelerated Lewis acid catalysis. The addition of tBuOH as a proton source is the key to the efficient catalytic cycle....

scholarly journals Dual nickel and Lewis acid catalysis for cross-electrophile coupling: the allylation of aryl halides with allylic alcohols

2018 ◽  
Vol 9 (3) ◽  
pp. 640-645 ◽  
Author(s):  
Xue-Gong Jia ◽  
Peng Guo ◽  
Jicheng Duan ◽  
Xing-Zhong Shu
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Coupling Reaction ◽  
Aryl Halides ◽  
Allylic Alcohols ◽  
Lewis Acid Catalysis

Dual nickel and Lewis acid catalysis has been developed for the coupling reaction between reactive and unreactive electrophiles.

Chiral Lewis Acid Catalysis in Nitrile Oxide Cycloadditions

2004 ◽  
Vol 126 (17) ◽  
pp. 5366-5367 ◽  
Author(s):  
Mukund P. Sibi ◽  
Kennosuke Itoh ◽  
Craig P. Jasperse
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Nitrile Oxide ◽  
Lewis Acid Catalysis ◽  
Chiral Lewis Acid

Lewis Acid Catalysis with Cationic Dinuclear Gold(II,II) and Gold(III,III) Phosphorus Ylide Complexes

2016 ◽  
Vol 35 (17) ◽  
pp. 2830-2835 ◽  
Author(s):  
Benjamin R. Reiner ◽  
Mark W. Bezpalko ◽  
Bruce M. Foxman ◽  
Casey R. Wade
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Lewis Acid Catalysis ◽  
Phosphorus Ylide ◽  
Ylide Complexes

Radical Changes in Lewis Acid Catalysis: Matching Metal and Substrate

2016 ◽  
Vol 55 (27) ◽  
pp. 7852-7856 ◽  
Author(s):  
Tim Bleith ◽  
Qing-Hai Deng ◽  
Hubert Wadepohl ◽  
Lutz H. Gade
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Lewis Acid Catalysis

Boosting Lewis Acid Catalysis in Water-in-Oil Metallomicroemulsions

ChemCatChem ◽  
2012 ◽  
Vol 4 (12) ◽  
pp. 1979-1986 ◽  
Author(s):  
María Méndez-Pérez ◽  
Luis García-Río ◽  
Moisés Pérez-Lorenzo
Keyword(s):  
Lewis Acid ◽  
Acid Catalysis ◽  
Lewis Acid Catalysis
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